The carbonate compensation depth (CCD) is the depth, in the oceans, at which the rate of supply of

calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...

s matches the rate of

solvation Solvations describes the interaction of a solvent with dissolved molecules. Both ionized and uncharged molecules interact strongly with a solvent, and the strength and nature of this interaction influence many properties of the solute, includi ...

. That is, solvation 'compensates' supply. Below the CCD solvation is faster, so that carbonate particles dissolve and the carbonate shells ( tests) of animals are not preserved. Carbonate particles cannot accumulate in the sediments where the sea floor is below this depth.

Calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

is the least soluble of these carbonates, so the CCD is normally the compensation depth for calcite. The aragonite compensation depth (ACD) is the compensation depth for aragonitic carbonates. Aragonite is more soluble than calcite, and the aragonite compensation depth is generally shallower than both the calcite compensation depth and the CCD.

Overview

As shown in the diagram, biogenic

(CaCO₃) tests are produced in the

photic zone The photic zone (or euphotic zone, epipelagic zone, or sunlight zone) is the uppermost layer of a body of water that receives sunlight, allowing phytoplankton to perform photosynthesis. It undergoes a series of physical, chemical, and biological ...

of the oceans (green circles). Upon death, those tests escaping dissolution near the surface settle, along with clay materials. In seawater, a dissolution boundary is formed as a result of temperature, pressure, and depth, and is known as the ''saturation horizon''. Above this horizon, waters are supersaturated and CaCO₃ tests are largely preserved. Below it, waters are undersaturated, because of both the increasing solubility with depth and the release of CO₂ from organic matter decay, and CaCO₃ will dissolve. The sinking velocity of debris is rapid (broad pale arrows), so dissolution occurs primarily at the sediment surface. At the carbonate compensation depth, the rate of dissolution exactly matches the rate of supply of CaCO₃ from above. At steady state this depth, the CCD, is similar to the snowline (the first depth where carbonate-poor sediments occur). The lysocline is the depth interval between the saturation and carbonate compensation depths.

Solubility of carbonate

Calcium carbonate is essentially insoluble in sea surface waters today. Shells of dead calcareous

plankton Plankton are the diverse collection of organisms that drift in Hydrosphere, water (or atmosphere, air) but are unable to actively propel themselves against ocean current, currents (or wind). The individual organisms constituting plankton are ca ...

sinking to deeper waters are practically unaltered until reaching the lysocline, the point about 3.5 km deep past which the

solubility In chemistry, solubility is the ability of a chemical substance, substance, the solute, to form a solution (chemistry), solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form su ...

increases dramatically with depth and pressure. By the time the CCD is reached all

has dissolved according to this equation: :CaCO3 + CO2 + H2O <=> Ca^2+ (aq) + 2HCO_3^- (aq) Calcareous plankton and

sediment Sediment is a solid material that is transported to a new location where it is deposited. It occurs naturally and, through the processes of weathering and erosion, is broken down and subsequently sediment transport, transported by the action of ...

particles can be found in the water column above the CCD. If the sea bed is above the CCD, bottom

s can consist of calcareous sediments called calcareous ooze, which is essentially a type of

limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...

chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Ch ...

. If the exposed sea bed is below the CCD tiny

shell Shell may refer to: Architecture and design * Shell (structure), a thin structure ** Concrete shell, a thin shell of concrete, usually with no interior columns or exterior buttresses Science Biology * Seashell, a hard outer layer of a marine ani ...

s of CaCO₃ will dissolve before reaching this level, preventing deposition of carbonate sediment. As the sea floor spreads,

thermal subsidence In geology and geophysics, thermal subsidence is a mechanism of subsidence in which conductive cooling of the mantle thickens the lithosphere and causes it to decrease in elevation. This is because of thermal expansion: as mantle material cools ...

of the plate, which has the effect of increasing depth, may bring the carbonate layer below the CCD; the carbonate layer may be prevented from chemically interacting with the sea water by overlying sediments such as a layer of siliceous ooze or abyssal clay deposited on top of the carbonate layer.

Variations in value of the CCD

The exact value of the CCD depends on the solubility of calcium carbonate which is determined by

temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...

pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...

and the chemical composition of the water – in particular the amount of dissolved in the water. Calcium carbonate is more soluble at lower temperatures and at higher pressures. It is also more soluble if the concentration of dissolved is higher. Adding a reactant to the above chemical equation pushes the equilibrium towards the right producing more products: Ca²⁺ and HCO₃⁻, and consuming more reactants and

according to Le Chatelier's principle. At the present time the CCD in the

Pacific Ocean The Pacific Ocean is the largest and deepest of Earth's five Borders of the oceans, oceanic divisions. It extends from the Arctic Ocean in the north to the Southern Ocean, or, depending on the definition, to Antarctica in the south, and is ...

is about 4200–4500 metres except beneath the equatorial

upwelling Upwelling is an physical oceanography, oceanographic phenomenon that involves wind-driven motion of dense, cooler, and usually nutrient-rich water from deep water towards the ocean surface. It replaces the warmer and usually nutrient-depleted sur ...

zone, where the CCD is about 5000 m. In the

temperate In geography, the temperate climates of Earth occur in the middle latitudes (approximately 23.5° to 66.5° N/S of the Equator), which span between the tropics and the polar regions of Earth. These zones generally have wider temperature ran ...

and

tropical The tropics are the regions of Earth surrounding the equator, where the sun may shine directly overhead. This contrasts with the temperate or polar regions of Earth, where the Sun can never be directly overhead. This is because of Earth's ax ...

Atlantic Ocean The Atlantic Ocean is the second largest of the world's five borders of the oceans, oceanic divisions, with an area of about . It covers approximately 17% of Earth#Surface, Earth's surface and about 24% of its water surface area. During the ...

the CCD is at approximately 5000 m. In the

Indian Ocean The Indian Ocean is the third-largest of the world's five oceanic divisions, covering or approximately 20% of the water area of Earth#Surface, Earth's surface. It is bounded by Asia to the north, Africa to the west and Australia (continent), ...

it is intermediate between the Atlantic and the Pacific at approximately 4300 meters. The variation in the depth of the CCD largely results from the length of time since the bottom water has been exposed to the surface; this is called the "age" of the water mass. Thermohaline circulation determines the relative ages of the water in these basins. Because organic material, such as fecal pellets from copepods, sink from the surface waters into deeper water, deep water masses tend to accumulate dissolved carbon dioxide as they age. The oldest water masses have the highest concentrations of and therefore the shallowest CCD. The CCD is relatively shallow in high

latitude In geography, latitude is a geographic coordinate system, geographic coordinate that specifies the north-south position of a point on the surface of the Earth or another celestial body. Latitude is given as an angle that ranges from −90° at t ...

s with the exception of the

North Atlantic The Atlantic Ocean is the second largest of the world's five oceanic divisions, with an area of about . It covers approximately 17% of Earth's surface and about 24% of its water surface area. During the Age of Discovery, it was known for ...

and regions of

Southern Ocean The Southern Ocean, also known as the Antarctic Ocean, comprises the southernmost waters of the world ocean, generally taken to be south of 60th parallel south, 60° S latitude and encircling Antarctica. With a size of , it is the seco ...

where downwelling occurs. This downwelling brings young, surface water with relatively low concentrations of carbon dioxide into the deep ocean, depressing the CCD. In the geological past the depth of the CCD has shown significant variation. In the

Cretaceous The Cretaceous ( ) is a geological period that lasted from about 143.1 to 66 mya (unit), million years ago (Mya). It is the third and final period of the Mesozoic Era (geology), Era, as well as the longest. At around 77.1 million years, it is the ...

through to the

Eocene The Eocene ( ) is a geological epoch (geology), epoch that lasted from about 56 to 33.9 million years ago (Ma). It is the second epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), Era. The name ''Eocene'' comes ...

the CCD was much shallower globally than it is today; due to intense volcanic activity during this period atmospheric concentrations were much higher. Higher concentrations of resulted in a higher

partial pressure In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal g ...

of over the ocean. This greater pressure of atmospheric leads to increased dissolved in the ocean mixed surface layer. This effect was somewhat moderated by the deep oceans' elevated temperatures during this period. In the late Eocene the transition from a greenhouse to an icehouse Earth coincided with a deepened CCD. John Murray investigated and experimented on the dissolution of calcium carbonate and was first to identify the carbonate compensation depth in oceans.

Climate change impacts

Increasing atmospheric concentration of from combustion of

fossil fuels A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geologica ...

are causing the CCD to rise, with zones of downwelling first being affected.

Ocean acidification Ocean acidification is the ongoing decrease in the pH of the Earth's ocean. Between 1950 and 2020, the average pH of the ocean surface fell from approximately 8.15 to 8.05. Carbon dioxide emissions from human activities are the primary cause of ...

, which is also caused by increasing carbon dioxide concentrations in the atmosphere, will increase such dissolution and shallow the carbonate compensation depth on timescales of tens to hundreds of years.

Sedimentary ooze

On the sea floors above the carbonate compensation depth, the most commonly found ooze is calcareous ooze; on the sea floors below the carbonate compensation depth, the most commonly found ooze is siliceous ooze. While calcareous ooze mostly consists of Rhizaria, siliceous ooze mostly consists of Radiolaria and

diatom A diatom (Neo-Latin ''diatoma'') is any member of a large group comprising several Genus, genera of algae, specifically microalgae, found in the oceans, waterways and soils of the world. Living diatoms make up a significant portion of Earth's B ...

References