Caesium hydride or cesium hydride is an
inorganic compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''.
Inorgan ...
of
caesium
Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only f ...
and
hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
with the
chemical formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ...
. It is an
alkali metal hydride.
It was the first substance to be created by light-induced particle formation in metal vapor, and showed promise in early studies of an
ion propulsion system using caesium. It is the most reactive stable
alkaline metal hydride of all. It is a powerful
superbase and reacts with water extremely vigorously.
The caesium nucleus in CsH can be hyperpolarized through interactions with an
optically pumped caesium vapor in a process known as
spin-exchange optical pumping (SEOP). SEOP can increase the
nuclear magnetic resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a ...
(NMR) signal of caesium nucleus by an order of magnitude.
It is very difficult to make caesium hydride in a pure form. Caesium hydride can be produced by heating
caesium carbonate and metallic
magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
in
hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
at 580 to 620
°C.
Crystal structure
At room temperature and atmospheric pressure, CsH has the same structure as
NaCl
Sodium chloride , commonly known as edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral hali ...
.
References
Caesium compounds
Metal hydrides
Superbases
Rock salt crystal structure
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