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Caesium hexafluorocobaltate(IV) is a
salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...
with the chemical formula . It can be synthesized by the reaction of and
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
. The salt contains rare example of
cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...
(IV)
complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...
, i.e. oF6sup>2-. It has cubic K2PtCl6 structure, with the lattice constant a = 8.91 Å, and the length of Co-F bond is 1.73 Å. The complex is
ferromagnetic Ferromagnetism is a property of certain materials (such as iron) that results in a significant, observable magnetic permeability, and in many cases, a significant magnetic coercivity, allowing the material to form a permanent magnet. Ferromagne ...
and the ground state of Co(IV) is T2g3Eg2.


See also

* Percobaltate


References

{{Inorganic-compound-stub Caesium compounds Cobalt complexes Fluoro complexes Metal halides Fluorometallates Ferromagnetic materials Cobalt compounds