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In
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
, charge conjugation is a transformation that switches all
particle In the physical sciences, a particle (or corpuscle in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from s ...
s with their corresponding
antiparticle In particle physics, every type of particle of "ordinary" matter (as opposed to antimatter) is associated with an antiparticle with the same mass but with opposite physical charges (such as electric charge). For example, the antiparticle of the ...
s, thus changing the sign of all charges: not only
electric charge Electric charge (symbol ''q'', sometimes ''Q'') is a physical property of matter that causes it to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative''. Like charges repel each other and ...
but also the charges relevant to other forces. The term C-symmetry is an abbreviation of the phrase "charge conjugation symmetry", and is used in discussions of the symmetry of physical laws under charge-conjugation. Other important discrete symmetries are
P-symmetry In physics, a parity transformation (also called parity inversion) is the flip in the sign of ''one'' Three-dimensional space, spatial coordinate. In three dimensions, it can also refer to the simultaneous flip in the sign of all three spatial co ...
(parity) and
T-symmetry T-symmetry or time reversal symmetry is the theoretical symmetry of physical laws under the transformation of time reversal, : T: t \mapsto -t. Since the second law of thermodynamics states that entropy increases as time flows toward the futur ...
(time reversal). These discrete symmetries, C, P and T, are symmetries of the equations that describe the known fundamental forces of nature:
electromagnetism In physics, electromagnetism is an interaction that occurs between particles with electric charge via electromagnetic fields. The electromagnetic force is one of the four fundamental forces of nature. It is the dominant force in the interacti ...
,
gravity In physics, gravity (), also known as gravitation or a gravitational interaction, is a fundamental interaction, a mutual attraction between all massive particles. On Earth, gravity takes a slightly different meaning: the observed force b ...
, the strong and the
weak interaction In nuclear physics and particle physics, the weak interaction, weak force or the weak nuclear force, is one of the four known fundamental interactions, with the others being electromagnetism, the strong interaction, and gravitation. It is th ...
s. Verifying whether some given mathematical equation correctly models
nature Nature is an inherent character or constitution, particularly of the Ecosphere (planetary), ecosphere or the universe as a whole. In this general sense nature refers to the Scientific law, laws, elements and phenomenon, phenomena of the physic ...
requires giving physical interpretation not only to continuous symmetries, such as
motion In physics, motion is when an object changes its position with respect to a reference point in a given time. Motion is mathematically described in terms of displacement, distance, velocity, acceleration, speed, and frame of reference to an o ...
in time, but also to its discrete symmetries, and then determining whether nature adheres to these symmetries. Unlike the continuous symmetries, the interpretation of the discrete symmetries is a bit more intellectually demanding and confusing. An early surprise appeared in the 1950s, when Chien Shiung Wu demonstrated that the weak interaction violated P-symmetry. For several decades, it appeared that the combined symmetry CP was preserved, until CP-violating interactions were discovered. Both discoveries led to
Nobel Prize The Nobel Prizes ( ; ; ) are awards administered by the Nobel Foundation and granted in accordance with the principle of "for the greatest benefit to humankind". The prizes were first awarded in 1901, marking the fifth anniversary of Alfred N ...
s. The C-symmetry is particularly troublesome, physically, as the universe is primarily filled with
matter In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic pa ...
, not anti-matter, whereas the naive C-symmetry of the physical laws suggests that there should be equal amounts of both. It is currently believed that CP-violation during the early universe can account for the "excess" matter, although the debate is not settled. Earlier textbooks on
cosmology Cosmology () is a branch of physics and metaphysics dealing with the nature of the universe, the cosmos. The term ''cosmology'' was first used in English in 1656 in Thomas Blount's ''Glossographia'', with the meaning of "a speaking of the wo ...
, predating the 1970s, routinely suggested that perhaps distant galaxies were made entirely of anti-matter, thus maintaining a net balance of zero in the universe. This article focuses on exposing and articulating the C-symmetry of various important equations and theoretical systems, including the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin-1/2 massive particles, called "Dirac ...
and the structure of
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct phy ...
. The various fundamental particles can be classified according to behavior under charge conjugation; this is described in the article on
C-parity In physics, the C parity or charge parity is a multiplicative quantum number of some particles that describes their behavior under the symmetry operation of charge conjugation. Charge conjugation changes the sign of all quantum charges (that is, ...
.


Informal overview

Charge conjugation occurs as a symmetry in three different but closely related settings: a symmetry of the (classical, non-quantized) solutions of several notable differential equations, including the Klein–Gordon equation and the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin-1/2 massive particles, called "Dirac ...
, a symmetry of the corresponding quantum fields, and in a general setting, a symmetry in (pseudo-)
Riemannian geometry Riemannian geometry is the branch of differential geometry that studies Riemannian manifolds, defined as manifold, smooth manifolds with a ''Riemannian metric'' (an inner product on the tangent space at each point that varies smooth function, smo ...
. In all three cases, the symmetry is ultimately revealed to be a symmetry under
complex conjugation In mathematics, the complex conjugate of a complex number is the number with an equal real part and an imaginary part equal in magnitude but opposite in sign. That is, if a and b are real numbers, then the complex conjugate of a + bi is a - ...
, although exactly what is being conjugated where can be at times obfuscated, depending on notation, coordinate choices and other factors.


In classical fields

The charge conjugation symmetry is interpreted as that of
electrical charge Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
, because in all three cases (classical, quantum and geometry), one can construct Noether currents that resemble those of classical electrodynamics. This arises because electrodynamics itself, via
Maxwell's equations Maxwell's equations, or Maxwell–Heaviside equations, are a set of coupled partial differential equations that, together with the Lorentz force law, form the foundation of classical electromagnetism, classical optics, Electrical network, electr ...
, can be interpreted as a structure on a
U(1) In mathematics, the circle group, denoted by \mathbb T or , is the multiplicative group of all complex numbers with absolute value 1, that is, the unit circle in the complex plane or simply the unit complex numbers \mathbb T = \. The circle g ...
fiber bundle, the so-called circle bundle. This provides a geometric interpretation of electromagnetism: the electromagnetic potential A_\mu is interpreted as the gauge connection (the Ehresmann connection) on the circle bundle. This geometric interpretation then allows (literally almost) anything possessing a complex-number-valued structure to be coupled to the electromagnetic field, provided that this coupling is done in a gauge-invariant way. Gauge symmetry, in this geometric setting, is a statement that, as one moves around on the circle, the coupled object must also transform in a "circular way", tracking in a corresponding fashion. More formally, one says that the equations must be gauge invariant under a change of local coordinate frames on the circle. For U(1), this is just the statement that the system is invariant under multiplication by a phase factor e^ that depends on the (space-time) coordinate x. In this geometric setting, charge conjugation can be understood as the discrete symmetry z = (x + iy) \mapsto \overline z = (x - iy) that performs complex conjugation, that reverses the sense of direction around the circle.


In quantum theory

In
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct phy ...
, charge conjugation can be understood as the exchange of
particle In the physical sciences, a particle (or corpuscle in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from s ...
s with anti-particles. To understand this statement, one must have a minimal understanding of what quantum field theory is. In (vastly) simplified terms, it is a technique for performing calculations to obtain solutions for a system of coupled differential equations via
perturbation theory In mathematics and applied mathematics, perturbation theory comprises methods for finding an approximate solution to a problem, by starting from the exact solution of a related, simpler problem. A critical feature of the technique is a middle ...
. A key ingredient to this process is the quantum field, one for each of the (free, uncoupled) differential equations in the system. A quantum field is conventionally written as :\psi(x) = \int d^3p \sum_ e^ a\left(\vec p, \sigma, n\right) u\left(\vec p, \sigma, n\right) + e^ a^\dagger\left(\vec p, \sigma, n\right) v\left(\vec p, \sigma, n\right) where \vec p is the momentum, \sigma is a spin label, n is an auxiliary label for other states in the system. The a and a^\dagger are
creation and annihilation operators Creation operators and annihilation operators are Operator (mathematics), mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. An annihilatio ...
( ladder operators) and u, v are solutions to the (free, non-interacting, uncoupled) differential equation in question. The quantum field plays a central role because, in general, it is not known how to obtain exact solutions to the system of coupled differential questions. However, via perturbation theory, approximate solutions can be constructed as combinations of the free-field solutions. To perform this construction, one has to be able to extract and work with any one given free-field solution, on-demand, when required. The quantum field provides exactly this: it enumerates all possible free-field solutions in a vector space such that any one of them can be singled out at any given time, via the creation and annihilation operators. The creation and annihilation operators obey the canonical commutation relations, in that the one operator "undoes" what the other "creates". This implies that any given solution u\left(\vec p, \sigma, n\right) must be paired with its "anti-solution" v\left(\vec p, \sigma, n\right) so that one undoes or cancels out the other. The pairing is to be performed so that all symmetries are preserved. As one is generally interested in
Lorentz invariance In a relativistic theory of physics, a Lorentz scalar is a scalar expression whose value is invariant under any Lorentz transformation. A Lorentz scalar may be generated from, e.g., the scalar product of vectors, or by contracting tensors. While ...
, the quantum field contains an integral over all possible Lorentz coordinate frames, written above as an integral over all possible momenta (it is an integral over the fiber of the
frame bundle In mathematics, a frame bundle is a principal fiber bundle F(E) associated with any vector bundle ''E''. The fiber of F(E) over a point ''x'' is the set of all ordered bases, or ''frames'', for ''E_x''. The general linear group acts naturally on ...
). The pairing requires that a given u\left(\vec p\right) is associated with a v\left(\vec p\right) of the opposite momentum and energy. The quantum field is also a sum over all possible spin states; the dual pairing again matching opposite spins. Likewise for any other quantum numbers, these are also paired as opposites. There is a technical difficulty in carrying out this dual pairing: one must describe what it means for some given solution u to be "dual to" some other solution v, and to describe it in such a way that it remains consistently dual when integrating over the fiber of the frame bundle, when integrating (summing) over the fiber that describes the spin, and when integrating (summing) over any other fibers that occur in the theory. When the fiber to be integrated over is the U(1) fiber of electromagnetism, the dual pairing is such that the direction (orientation) on the fiber is reversed. When the fiber to be integrated over is the SU(3) fiber of the color charge, the dual pairing again reverses orientation. This "just works" for SU(3) because it has two dual fundamental representations \mathbf and \overline\mathbf which can be naturally paired. This prescription for a quantum field naturally generalizes to any situation where one can enumerate the continuous symmetries of the system, and define duals in a coherent, consistent fashion. The pairing ties together opposite charges in the fully abstract sense. In physics, a charge is associated with a generator of a continuous symmetry. Different charges are associated with different eigenspaces of the Casimir invariants of the universal enveloping algebra for those symmetries. This is the case for ''both'' the Lorentz symmetry of the underlying
spacetime In physics, spacetime, also called the space-time continuum, is a mathematical model that fuses the three dimensions of space and the one dimension of time into a single four-dimensional continuum. Spacetime diagrams are useful in visualiz ...
manifold In mathematics, a manifold is a topological space that locally resembles Euclidean space near each point. More precisely, an n-dimensional manifold, or ''n-manifold'' for short, is a topological space with the property that each point has a N ...
, ''as well as'' the symmetries of any fibers in the fiber bundle posed above the spacetime manifold. Duality replaces the generator of the symmetry with minus the generator. Charge conjugation is thus associated with reflection along the
line bundle In mathematics, a line bundle expresses the concept of a line that varies from point to point of a space. For example, a curve in the plane having a tangent line at each point determines a varying line: the ''tangent bundle'' is a way of organis ...
or determinant bundle of the space of symmetries. The above then is a sketch of the general idea of a quantum field in quantum field theory. The physical interpretation is that solutions u\left(\vec p, \sigma, n\right) correspond to particles, and solutions v\left(\vec p, \sigma, n\right) correspond to antiparticles, and so charge conjugation is a pairing of the two. This sketch also provides enough hints to indicate what charge conjugation might look like in a general geometric setting. There is no particular forced requirement to use perturbation theory, to construct quantum fields that will act as middle-men in a perturbative expansion. Charge conjugation can be given a general setting.


In geometry

For general Riemannian and
pseudo-Riemannian manifold In mathematical physics, a pseudo-Riemannian manifold, also called a semi-Riemannian manifold, is a differentiable manifold with a metric tensor that is everywhere nondegenerate. This is a generalization of a Riemannian manifold in which the ...
s, one has a
tangent bundle A tangent bundle is the collection of all of the tangent spaces for all points on a manifold, structured in a way that it forms a new manifold itself. Formally, in differential geometry, the tangent bundle of a differentiable manifold M is ...
, a cotangent bundle and a metric that ties the two together. There are several interesting things one can do, when presented with this situation. One is that the smooth structure allows differential equations to be posed on the manifold; the
tangent In geometry, the tangent line (or simply tangent) to a plane curve at a given point is, intuitively, the straight line that "just touches" the curve at that point. Leibniz defined it as the line through a pair of infinitely close points o ...
and cotangent spaces provide enough structure to perform calculus on manifolds. Of key interest is the
Laplacian In mathematics, the Laplace operator or Laplacian is a differential operator given by the divergence of the gradient of a scalar function on Euclidean space. It is usually denoted by the symbols \nabla\cdot\nabla, \nabla^2 (where \nabla is th ...
, and, with a constant term, what amounts to the Klein–Gordon operator. Cotangent bundles, by their basic construction, are always
symplectic manifold In differential geometry, a subject of mathematics, a symplectic manifold is a smooth manifold, M , equipped with a closed nondegenerate differential 2-form \omega , called the symplectic form. The study of symplectic manifolds is called sy ...
s. Symplectic manifolds have canonical coordinates x,p interpreted as position and momentum, obeying canonical commutation relations. This provides the core infrastructure to extend duality, and thus charge conjugation, to this general setting. A second interesting thing one can do is to construct a spin structure. Perhaps the most remarkable thing about this is that it is a very recognizable generalization to a (p,q)-dimensional pseudo-Riemannian manifold of the conventional physics concept of spinors living on a (1,3)-dimensional Minkowski spacetime. The construction passes through a complexified
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra with the additional structure of a distinguished subspace. As -algebras, they generalize the real number ...
to build a Clifford bundle and a spin manifold. At the end of this construction, one obtains a system that is remarkably familiar, if one is already acquainted with Dirac spinors and the Dirac equation. Several analogies pass through to this general case. First, the spinors are the Weyl spinors, and they come in complex-conjugate pairs. They are naturally anti-commuting (this follows from the Clifford algebra), which is exactly what one wants to make contact with the Pauli exclusion principle. Another is the existence of a chiral element, analogous to the gamma matrix \gamma_5 which sorts these spinors into left and right-handed subspaces. The complexification is a key ingredient, and it provides "electromagnetism" in this generalized setting. The spinor bundle doesn't "just" transform under the pseudo-orthogonal group SO(p,q), the generalization of the Lorentz group SO(1,3), but under a bigger group, the complexified spin group \mathrm^\mathbb(p,q). It is bigger in that it is a double covering of SO(p,q)\times U(1). The U(1) piece can be identified with electromagnetism in several different ways. One way is that the Dirac operators on the spin manifold, when squared, contain a piece F=dA with A arising from that part of the connection associated with the U(1) piece. This is entirely analogous to what happens when one squares the ordinary Dirac equation in ordinary Minkowski spacetime. A second hint is that this U(1) piece is associated with the determinant bundle of the spin structure, effectively tying together the left and right-handed spinors through complex conjugation. What remains is to work through the discrete symmetries of the above construction. There are several that appear to generalize
P-symmetry In physics, a parity transformation (also called parity inversion) is the flip in the sign of ''one'' Three-dimensional space, spatial coordinate. In three dimensions, it can also refer to the simultaneous flip in the sign of all three spatial co ...
and
T-symmetry T-symmetry or time reversal symmetry is the theoretical symmetry of physical laws under the transformation of time reversal, : T: t \mapsto -t. Since the second law of thermodynamics states that entropy increases as time flows toward the futur ...
. Identifying the p dimensions with time, and the q dimensions with space, one can reverse the tangent vectors in the p dimensional subspace to get time reversal, and flipping the direction of the q dimensions corresponds to parity. The C-symmetry can be identified with the reflection on the line bundle. To tie all of these together into a knot, one finally has the concept of transposition, in that elements of the Clifford algebra can be written in reversed (transposed) order. The net result is that not only do the conventional physics ideas of fields pass over to the general Riemannian setting, but also the ideas of the discrete symmetries. There are two ways to react to this. One is to treat it as an interesting curiosity. The other is to realize that, in low dimensions (in low-dimensional spacetime) there are many "accidental" isomorphisms between various
Lie group In mathematics, a Lie group (pronounced ) is a group (mathematics), group that is also a differentiable manifold, such that group multiplication and taking inverses are both differentiable. A manifold is a space that locally resembles Eucli ...
s and other assorted structures. Being able to examine them in a general setting disentangles these relationships, exposing more clearly "where things come from".


Charge conjugation for Dirac fields

The laws of
electromagnetism In physics, electromagnetism is an interaction that occurs between particles with electric charge via electromagnetic fields. The electromagnetic force is one of the four fundamental forces of nature. It is the dominant force in the interacti ...
(both classical and
quantum In physics, a quantum (: quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a property can be "quantized" is referred to as "the hypothesis of quantization". This me ...
) are invariant under the exchange of electrical charges with their negatives. For the case of
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s and
quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nucleus, atomic nuclei ...
s, both of which are fundamental particle
fermion In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
fields, the single-particle field excitations are described by the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin-1/2 massive particles, called "Dirac ...
:(i - q - m) \psi = 0 One wishes to find a charge-conjugate solution :(i + q - m) \psi^c = 0 A handful of algebraic manipulations are sufficient to obtain the second from the first. Standard expositions of the Dirac equation demonstrate a conjugate field \overline\psi = \psi^\dagger\gamma^0, interpreted as an anti-particle field, satisfying the complex-transposed Dirac equation :\overline\psi(-i - q - m) = 0 Note that some but not all of the signs have flipped. Transposing this back again gives almost the desired form, provided that one can find a 4×4 matrix C that transposes the
gamma matrices In mathematical physics, the gamma matrices, \ \left\\ , also called the Dirac matrices, are a set of conventional matrices with specific anticommutation relations that ensure they generate a matrix representation of the Clifford algebra \ \mathr ...
to insert the required sign-change: :C^\gamma_\mu C = -\gamma_\mu^\textsf The charge conjugate solution is then given by the involution :\psi \mapsto \psi^c=\eta_c\, C\overline\psi^\textsf The 4×4 matrix C, called the charge conjugation matrix, has an explicit form given in the article on
gamma matrices In mathematical physics, the gamma matrices, \ \left\\ , also called the Dirac matrices, are a set of conventional matrices with specific anticommutation relations that ensure they generate a matrix representation of the Clifford algebra \ \mathr ...
. Curiously, this form is not representation-independent, but depends on the specific matrix representation chosen for the gamma group (the subgroup of the
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra with the additional structure of a distinguished subspace. As -algebras, they generalize the real number ...
capturing the algebraic properties of the
gamma matrices In mathematical physics, the gamma matrices, \ \left\\ , also called the Dirac matrices, are a set of conventional matrices with specific anticommutation relations that ensure they generate a matrix representation of the Clifford algebra \ \mathr ...
). This matrix is representation dependent due to a subtle interplay involving the complexification of the spin group describing the Lorentz covariance of charged particles. The
complex number In mathematics, a complex number is an element of a number system that extends the real numbers with a specific element denoted , called the imaginary unit and satisfying the equation i^= -1; every complex number can be expressed in the for ...
\eta_c is an arbitrary phase factor , \eta_c, =1, generally taken to be \eta_c=1.


Charge conjugation, chirality, helicity

The interplay between chirality and charge conjugation is a bit subtle, and requires articulation. It is often said that charge conjugation does not alter the
chirality Chirality () is a property of asymmetry important in several branches of science. The word ''chirality'' is derived from the Greek (''kheir''), "hand", a familiar chiral object. An object or a system is ''chiral'' if it is distinguishable fro ...
of particles. This is not the case for ''fields'', the difference arising in the "hole theory" interpretation of particles, where an anti-particle is interpreted as the absence of a particle. This is articulated below. Conventionally, \gamma_5 is used as the chirality operator. Under charge conjugation, it transforms as :C\gamma_5 C^ = \gamma_5^\textsf and whether or not \gamma_5^\textsf equals \gamma_5 depends on the chosen representation for the gamma matrices. In the Dirac and chiral basis, one does have that \gamma_5^\textsf = \gamma_5, while \gamma_5^\textsf = -\gamma_5 is obtained in the Majorana basis. A worked example follows.


Weyl spinors

For the case of massless Dirac spinor fields, chirality is equal to helicity for the positive energy solutions (and minus the helicity for negative energy solutions). One obtains this by writing the massless Dirac equation as :i\partial\!\!\!\big /\psi = 0 Multiplying by \gamma^5\gamma^0 = -i\gamma^1\gamma^2\gamma^3 one obtains :^m\sigma^\partial_m \psi = \gamma_5 \partial_t \psi where \sigma^ = i\left gamma^\mu, \gamma^\nu\right2 is the angular momentum operator and \epsilon_ is the totally antisymmetric tensor. This can be brought to a slightly more recognizable form by defining the 3D spin operator \Sigma^m\equiv ^m\sigma^, taking a plane-wave state \psi(x) = e^\psi(k), applying the on-shell constraint that k \cdot k = 0 and normalizing the momentum to be a 3D unit vector: _i = k_i/k_0 to write :\left(\Sigma \cdot \hat k\right) \psi = \gamma_5 \psi~. Examining the above, one concludes that angular momentum eigenstates ( helicity eigenstates) correspond to eigenstates of the chiral operator. This allows the massless Dirac field to be cleanly split into a pair of Weyl spinors \psi_\text and \psi_\text, each individually satisfying the Weyl equation, but with opposite energy: :\left(-p_0 + \sigma\cdot\vec p\right)\psi_\text = 0 and :\left(p_0 + \sigma\cdot\vec p\right)\psi_\text = 0 Note the freedom one has to equate negative helicity with negative energy, and thus the anti-particle with the particle of opposite helicity. To be clear, the \sigma here are the
Pauli matrices In mathematical physics and mathematics, the Pauli matrices are a set of three complex matrices that are traceless, Hermitian, involutory and unitary. Usually indicated by the Greek letter sigma (), they are occasionally denoted by tau () ...
, and p_\mu = i\partial_\mu is the momentum operator.


Charge conjugation in the chiral basis

Taking the Weyl representation of the gamma matrices, one may write a (now taken to be massive) Dirac spinor as :\psi = \begin \psi_\text\\ \psi_\text \end The corresponding dual (anti-particle) field is :\overline^\textsf = \left( \psi^\dagger \gamma^0 \right)^\textsf = \begin 0 & I \\ I & 0\end \begin \psi_\text^* \\ \psi_\text^* \end = \begin \psi_\text^* \\ \psi_\text^* \end The charge-conjugate spinors are :\psi^c = \begin \psi_\text^c\\ \psi_\text^c \end = \eta_c C \overline\psi^\textsf = \eta_c \begin -i\sigma^2 & 0 \\ 0 & i\sigma^2\end \begin \psi_\text^* \\ \psi_\text^* \end = \eta_c \begin -i\sigma^2\psi_\text^* \\ i\sigma^2\psi_\text^* \end where, as before, \eta_c is a phase factor that can be taken to be \eta_c=1. Note that the left and right states are inter-changed. This can be restored with a parity transformation. Under parity, the Dirac spinor transforms as :\psi\left(t, \vec x\right) \mapsto \psi^p\left(t, \vec x\right) = \gamma^0 \psi\left(t, -\vec x\right) Under combined charge and parity, one then has :\psi\left(t, \vec x\right) \mapsto \psi^\left(t, \vec x\right) = \begin \psi_\text^ \left(t, \vec x\right)\\ \psi_\text^\left(t,\vec x\right) \end = \eta_c \begin -i\sigma^2\psi_\text^*\left(t, -\vec x\right) \\ i\sigma^2\psi_\text^*\left(t, -\vec x\right) \end Conventionally, one takes \eta_c = 1 globally. See however, the note below.


Majorana condition

The Majorana condition imposes a constraint between the field and its charge conjugate, namely that they must be equal: \psi = \psi^c. This is perhaps best stated as the requirement that the Majorana spinor must be an eigenstate of the charge conjugation involution. Doing so requires some notational care. In many texts discussing charge conjugation, the involution \psi\mapsto\psi^c is not given an explicit symbolic name, when applied to ''single-particle solutions'' of the Dirac equation. This is in contrast to the case when the ''quantized field'' is discussed, where a unitary operator \mathcal is defined (as done in a later section, below). For the present section, let the involution be named as \mathsf:\psi\mapsto\psi^c so that \mathsf\psi = \psi^c. Taking this to be a linear operator, one may consider its eigenstates. The Majorana condition singles out one such: \mathsf\psi = \psi. There are, however, two such eigenstates: \mathsf\psi^ = \pm \psi^. Continuing in the Weyl basis, as above, these eigenstates are :\psi^ = \begin \psi_\text\\ i\sigma^2\psi_\text^* \end and :\psi^ = \begin i\sigma^2\psi_\text^*\\ \psi_\text \end The Majorana spinor is conventionally taken as just the positive eigenstate, namely \psi^. The chiral operator \gamma_5 exchanges these two, in that :\gamma_5\mathsf = - \mathsf\gamma_5 This is readily verified by direct substitution. Bear in mind that \mathsf ''does not have'' a 4×4 matrix representation! More precisely, there is no complex 4×4 matrix that can take a complex number to its complex conjugate; this inversion would require an 8×8 real matrix. The physical interpretation of complex conjugation as charge conjugation becomes clear when considering the complex conjugation of scalar fields, described in a subsequent section below. The projectors onto the chiral eigenstates can be written as P_\text = \left(1 - \gamma_5\right)/2 and P_\text = \left(1 + \gamma_5\right)/2, and so the above translates to :P_\text\mathsf = \mathsfP_\text~. This directly demonstrates that charge conjugation, applied to single-particle complex-number-valued solutions of the Dirac equation flips the chirality of the solution. The projectors onto the charge conjugation eigenspaces are P^ = (1 + \mathsf)P_\text and P^ = (1 - \mathsf)P_\text.


Geometric interpretation

The phase factor \ \eta_c\ can be given a geometric interpretation. It has been noted that, for massive Dirac spinors, the "arbitrary" phase factor \ \eta_c\ may depend on both the momentum, and the helicity (but not the chirality). This can be interpreted as saying that this phase may vary along the fiber of the spinor bundle, depending on the local choice of a coordinate frame. Put another way, a spinor field is a local section of the spinor bundle, and Lorentz boosts and rotations correspond to movements along the fibers of the corresponding
frame bundle In mathematics, a frame bundle is a principal fiber bundle F(E) associated with any vector bundle ''E''. The fiber of F(E) over a point ''x'' is the set of all ordered bases, or ''frames'', for ''E_x''. The general linear group acts naturally on ...
(again, just a choice of local coordinate frame). Examined in this way, this extra phase freedom can be interpreted as the phase arising from the electromagnetic field. For the Majorana spinors, the phase would be constrained to not vary under boosts and rotations.


Charge conjugation for quantized fields

The above describes charge conjugation for the single-particle solutions only. When the Dirac field is second-quantized, as in
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct phy ...
, the spinor and electromagnetic fields are described by operators. The charge conjugation involution then manifests as a unitary operator \mathcal (in calligraphic font) acting on the particle fields, expressed as # \psi \mapsto \psi^c = \mathcal\ \psi\ \mathcal^\dagger = \eta_c\ C\ \overline\psi^\textsf # \overline\psi \mapsto \overline\psi^c = \mathcal\ \overline\psi\ \mathcal^\dagger = \eta^*_c\ \psi^\textsf\ C^ # A_\mu \mapsto A^c_\mu = \mathcal\ A_\mu\ \mathcal^\dagger = -A_\mu\ where the non-calligraphic \ C\ is the same 4×4 matrix given before.


Charge reversal in electroweak theory

Charge conjugation does not alter the
chirality Chirality () is a property of asymmetry important in several branches of science. The word ''chirality'' is derived from the Greek (''kheir''), "hand", a familiar chiral object. An object or a system is ''chiral'' if it is distinguishable fro ...
of particles. A left-handed
neutrino A neutrino ( ; denoted by the Greek letter ) is an elementary particle that interacts via the weak interaction and gravity. The neutrino is so named because it is electrically neutral and because its rest mass is so small ('' -ino'') that i ...
would be taken by charge conjugation into a left-handed antineutrino, which does not interact in the Standard Model. This property is what is meant by the "maximal violation" of C-symmetry in the weak interaction. Some postulated extensions of the
Standard Model The Standard Model of particle physics is the Scientific theory, theory describing three of the four known fundamental forces (electromagnetism, electromagnetic, weak interaction, weak and strong interactions – excluding gravity) in the unive ...
, like left-right models, restore this C-symmetry.


Scalar fields

The Dirac field has a "hidden" U(1) gauge freedom, allowing it to couple directly to the electromagnetic field without any further modifications to the Dirac equation or the field itself. This is not the case for
scalar field In mathematics and physics, a scalar field is a function associating a single number to each point in a region of space – possibly physical space. The scalar may either be a pure mathematical number ( dimensionless) or a scalar physical ...
s, which must be explicitly "complexified" to couple to electromagnetism. This is done by "tensoring in" an additional factor of the
complex plane In mathematics, the complex plane is the plane (geometry), plane formed by the complex numbers, with a Cartesian coordinate system such that the horizontal -axis, called the real axis, is formed by the real numbers, and the vertical -axis, call ...
\mathbb into the field, or constructing a
Cartesian product In mathematics, specifically set theory, the Cartesian product of two sets and , denoted , is the set of all ordered pairs where is an element of and is an element of . In terms of set-builder notation, that is A\times B = \. A table c ...
with U(1). One very conventional technique is simply to start with two real scalar fields, \phi and \chi and create a linear combination :\psi \mathrel\stackrel The charge conjugation involution is then the mapping \mathsf:i\mapsto -i since this is sufficient to reverse the sign on the electromagnetic potential (since this complex number is being used to couple to it). For real scalar fields, charge conjugation is just the identity map: \mathsf:\phi\mapsto \phi and \mathsf:\chi\mapsto \chi and so, for the complexified field, charge conjugation is just \mathsf:\psi\mapsto \psi^*. The "mapsto" arrow \mapsto is convenient for tracking "what goes where"; the equivalent older notation is simply to write \mathsf\phi=\phi and \mathsf\chi = \chi and \mathsf\psi = \psi^*. The above describes the conventional construction of a charged scalar field. It is also possible to introduce additional algebraic structure into the fields in other ways. In particular, one may define a "real" field behaving as \mathsf:\phi\mapsto -\phi. As it is real, it cannot couple to electromagnetism by itself, but, when complexified, would result in a charged field that transforms as \mathsf:\psi\mapsto -\psi^*. Because C-symmetry is a discrete symmetry, one has some freedom to play these kinds of algebraic games in the search for a theory that correctly models some given physical reality. In physics literature, a transformation such as \mathsf:\phi \mapsto \phi^c = -\phi might be written without any further explanation. The formal mathematical interpretation of this is that the field \phi is an element of \mathbb\times\mathbb_2 where \mathbb_2 = \. Thus, properly speaking, the field should be written as \phi = (r, c) which behaves under charge conjugation as \mathsf: (r, c) \mapsto (r, -c). It is very tempting, but not quite formally correct to just multiply these out, to move around the location of this minus sign; this mostly "just works", but a failure to track it properly will lead to confusion.


Combination of charge and parity reversal

It was believed for some time that C-symmetry could be combined with the parity-inversion transformation (see
P-symmetry In physics, a parity transformation (also called parity inversion) is the flip in the sign of ''one'' Three-dimensional space, spatial coordinate. In three dimensions, it can also refer to the simultaneous flip in the sign of all three spatial co ...
) to preserve a combined
CP-symmetry In particle physics, CP violation is a violation of CP-symmetry (or charge conjugation parity symmetry): the combination of C-symmetry (Charge (physics), charge conjugation symmetry) and Parity (physics), P-symmetry (Parity (physics), parity sym ...
. However, violations of this symmetry have been identified in the weak interactions (particularly in the kaons and B
meson In particle physics, a meson () is a type of hadronic subatomic particle composed of an equal number of quarks and antiquarks, usually one of each, bound together by the strong interaction. Because mesons are composed of quark subparticles, the ...
s). In the Standard Model, this CP violation is due to a single phase in the CKM matrix. If CP is combined with time reversal (
T-symmetry T-symmetry or time reversal symmetry is the theoretical symmetry of physical laws under the transformation of time reversal, : T: t \mapsto -t. Since the second law of thermodynamics states that entropy increases as time flows toward the futur ...
), the resulting CPT-symmetry can be shown using only the Wightman axioms to be universally obeyed.


In general settings

The analog of charge conjugation can be defined for
higher-dimensional gamma matrices In mathematical physics, higher-dimensional gamma matrices generalize to arbitrary dimension the four-dimensional Gamma matrices of Paul Dirac, Dirac, which are a mainstay of relativistic quantum mechanics. They are utilized in relativistically i ...
, with an explicit construction for Weyl spinors given in the article on Weyl–Brauer matrices. Note, however, spinors as defined abstractly in the representation theory of
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra with the additional structure of a distinguished subspace. As -algebras, they generalize the real number ...
s are not fields; rather, they should be thought of as existing on a zero-dimensional spacetime. The analog of
T-symmetry T-symmetry or time reversal symmetry is the theoretical symmetry of physical laws under the transformation of time reversal, : T: t \mapsto -t. Since the second law of thermodynamics states that entropy increases as time flows toward the futur ...
follows from \gamma^1\gamma^3 as the T-conjugation operator for Dirac spinors. Spinors also have an inherent
P-symmetry In physics, a parity transformation (also called parity inversion) is the flip in the sign of ''one'' Three-dimensional space, spatial coordinate. In three dimensions, it can also refer to the simultaneous flip in the sign of all three spatial co ...
, obtained by reversing the direction of all of the basis vectors of the
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra with the additional structure of a distinguished subspace. As -algebras, they generalize the real number ...
from which the spinors are constructed. The relationship to the P and T symmetries for a fermion field on a spacetime manifold are a bit subtle, but can be roughly characterized as follows. When a spinor is constructed via a Clifford algebra, the construction requires a vector space on which to build. By convention, this vector space is the tangent space of the spacetime manifold at a given, fixed spacetime point (a single fiber in the tangent manifold). P and T operations applied to the spacetime manifold can then be understood as also flipping the coordinates of the tangent space as well; thus, the two are glued together. Flipping the parity or the direction of time in one also flips it in the other. This is a convention. One can become unglued by failing to propagate this connection. This is done by taking the tangent space as a
vector space In mathematics and physics, a vector space (also called a linear space) is a set (mathematics), set whose elements, often called vector (mathematics and physics), ''vectors'', can be added together and multiplied ("scaled") by numbers called sc ...
, extending it to a
tensor algebra In mathematics, the tensor algebra of a vector space ''V'', denoted ''T''(''V'') or ''T''(''V''), is the algebra over a field, algebra of tensors on ''V'' (of any rank) with multiplication being the tensor product. It is the free algebra on ''V'', ...
, and then using an
inner product In mathematics, an inner product space (or, rarely, a Hausdorff pre-Hilbert space) is a real vector space or a complex vector space with an operation called an inner product. The inner product of two vectors in the space is a scalar, ofte ...
on the vector space to define a
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra with the additional structure of a distinguished subspace. As -algebras, they generalize the real number ...
. Treating each such algebra as a fiber, one obtains a fiber bundle called the Clifford bundle. Under a change of basis of the tangent space, elements of the Clifford algebra transform according to the spin group. Building a principle fiber bundle with the spin group as the fiber results in a spin structure. All that is missing in the above paragraphs are the spinors themselves. These require the "complexification" of the tangent manifold: tensoring it with the complex plane. Once this is done, the Weyl spinors can be constructed. These have the form :w_j = \frac\left(e_ - ie_\right) where the e_j are the basis vectors for the vector space V=T_pM, the tangent space at point p\in M in the spacetime manifold M. The Weyl spinors, together with their complex conjugates span the tangent space, in the sense that :V \otimes \mathbb = W\oplus \overline W The alternating algebra \wedge W is called the spinor space, it is where the spinors live, as well as products of spinors (thus, objects with higher spin values, including vectors and tensors).


See also

* C parity *
G-parity In particle physics, G-parity is a multiplicative quantum number that results from the generalization of C-parity to multiplets of particles. ''C''-parity applies only to neutral systems; in the pion triplet, only π0 has ''C''-parity. On the ot ...
* Anti-particle *
Antimatter In modern physics, antimatter is defined as matter composed of the antiparticles (or "partners") of the corresponding subatomic particle, particles in "ordinary" matter, and can be thought of as matter with reversed charge and parity, or go ...
* Truly neutral particle


Notes


References

* {{C, P and T Quantum field theory Symmetry Antimatter