Breathing gas
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A breathing gas is a mixture of gaseous chemical elements and compounds used for respiration.
Air An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
is the most common and only natural breathing gas, but other mixtures of gases, or pure oxygen, are also used in breathing equipment and enclosed habitats. Oxygen is the essential component for any breathing gas. Breathing gases for hyperbaric use have been developed to improve on the performance of ordinary air by reducing the risk of
decompression sickness Decompression sickness (DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from Solution (chemistry), solution as bubbles inside the body tissues during D ...
, reducing the duration of decompression, reducing nitrogen narcosis or reducing work of breathing and allowing safer deep diving.


Description

A breathing gas is a mixture of gaseous chemical elements and compounds used for respiration.
Air An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
is the most common and only natural breathing gas. Other mixtures of gases, or pure
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, are also used in breathing equipment and enclosed habitats such as scuba equipment, surface supplied diving equipment,
recompression chamber A diving chamber is a vessel for human occupation, which may have an entrance that can be sealed to hold an internal pressure significantly higher than ambient pressure, a pressurised gas system to control the internal pressure, and a supply of ...
s, high-altitude mountaineering, high-flying
aircraft An aircraft ( aircraft) is a vehicle that is able to flight, fly by gaining support from the Atmosphere of Earth, air. It counters the force of gravity by using either Buoyancy, static lift or the Lift (force), dynamic lift of an airfoil, or, i ...
,
submarine A submarine (often shortened to sub) is a watercraft capable of independent operation underwater. (It differs from a submersible, which has more limited underwater capability.) The term "submarine" is also sometimes used historically or infor ...
s, space suits,
spacecraft A spacecraft is a vehicle that is designed spaceflight, to fly and operate in outer space. Spacecraft are used for a variety of purposes, including Telecommunications, communications, Earth observation satellite, Earth observation, Weather s ...
, medical life support and first aid equipment, and anaesthetic machines.


Contents

Oxygen is the essential component for any breathing gas, at a
partial pressure In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal g ...
of between roughly 0.16 and 1.60 bar at the
ambient pressure The ambient pressure on an object is the pressure of the surrounding medium, such as a gas or liquid, in contact with the object. Atmosphere Within the atmosphere, the ambient pressure decreases as elevation increases. By measuring ambient atmosp ...
, occasionally lower for high altitude mountaineering, or higher for hyperbaric oxygen treatment. The oxygen is usually the only metabolically active component unless the gas is an anaesthetic mixture. Some of the oxygen in the breathing gas is consumed by the metabolic processes, and the inert components are unchanged, and serve mainly to dilute the oxygen to an appropriate concentration, and are therefore also known as diluent gases. Most breathing gases therefore are a mixture of
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
and one or more metabolically
inert gas An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent u ...
es. Breathing gases for hyperbaric use have been developed to improve on the performance of ordinary air by reducing the risk of
decompression sickness Decompression sickness (DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from Solution (chemistry), solution as bubbles inside the body tissues during D ...
, reducing the duration of decompression, reducing nitrogen narcosis or allowing safer deep diving. The techniques used to fill diving cylinders with gases other than air or pure oxygen are called gas blending. Breathing gases for use at ambient pressures below normal atmospheric pressure are usually pure oxygen or air enriched with oxygen to provide sufficient oxygen to maintain life and consciousness, or to allow higher levels of exertion than would be possible using air. It is common to provide the additional oxygen as a pure gas added to the breathing air at inhalation, or though a life-support system.


For diving and other hyperbaric use

A safe breathing gas for
hyperbaric Hyperbaric medicine is medical treatment in which an increase in barometric pressure of typically air or oxygen is used. The immediate effects include reducing the size of gas emboli and raising the partial pressures of the gases present. Initial ...
use has four essential features: * It must contain sufficient oxygen to support life, consciousness and work rate of the breather. * It must not contain harmful contaminants.
Carbon monoxide Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
and
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
are common poisons which may contaminate breathing gases. There are many other possibilities. * It must not become toxic when being breathed at high
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
such as when underwater. Oxygen and
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
are examples of gases that become
toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...
under pressure. * It must not be too dense to breathe. Work of breathing increases with
density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...
and
viscosity Viscosity is a measure of a fluid's rate-dependent drag (physics), resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for e ...
. Maximum ventilation drops by about 50% when density is equivalent to air at 30 msw, and carbon dioxide levels rise unacceptably for moderate exercise with a gas density exceeding 6 g/litre. Breathing gas density of 10 g/litre or more may cause runaway
hypercapnia Hypercapnia (from the Greek ''hyper'', "above" or "too much" and ''kapnos'', "smoke"), also known as hypercarbia and CO2 retention, is a condition of abnormally elevated carbon dioxide (CO2) levels in the blood. Carbon dioxide is a gaseous pro ...
even at very low work levels, with potentially fatal effects. These common diving breathing gases are used: *
Air An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
is a mixture of 21%
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, 78%
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, and approximately 1% other trace gases, primarily
argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
; to simplify calculations this last 1% is usually treated as if it were nitrogen. Being freely available and simple to use, it is the most common diving gas. As its nitrogen component causes nitrogen narcosis, it is considered to have a safe depth limit of about for most divers, although the maximum operating depth (MOD) of air taking an allowable oxygen partial pressure of 1,6 bar is . Breathing air is air meeting specified standards for contaminants. * Pure oxygen is mainly used to speed the shallow decompression stops at the end of a
military A military, also known collectively as armed forces, is a heavily armed, highly organized force primarily intended for warfare. Militaries are typically authorized and maintained by a sovereign state, with their members identifiable by a d ...
,
commercial Commercial may refer to: * (adjective for) commerce, a system of voluntary exchange of products and services ** (adjective for) trade, the trading of something of economic value such as goods, services, information or money * a dose of advertising ...
, or technical dive. Risk of acute oxygen toxicity increases rapidly at pressures greater than 6 metres sea water. It was much used in frogmen's
rebreather A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's exhaled breath to permit the rebreathing (recycling) of the substantial unused oxygen content, and unused inert content when present, of each breath. Oxygen is a ...
s, and is still used by attack swimmers. * are mixtures of two or more gases specifically blended for use as breathing gas for divers. They may be mixed to the composition required before the dive, for open circuit use, or produced in the breathing circuit of a rebreather during the dive. Diving using mixed gases is referred to as mixed gas diving. ** '' Nitrox'' is a mixture of oxygen and nitrogen, either by mixing oxygen with air, or by removing nitrogen from air, and generally refers to mixtures which are more than 21% oxygen. It can be used as a tool to accelerate in-water decompression stops or to decrease the risk of
decompression sickness Decompression sickness (DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from Solution (chemistry), solution as bubbles inside the body tissues during D ...
and thus prolong a dive (a common misconception is that the diver can go deeper, this is not true owing to a shallower maximum operating depth than on conventional air). ** '' Trimix'' is a mixture of oxygen, nitrogen and
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
and is often used at depth in
technical diving Technical diving (also referred to as tec diving or tech diving) is scuba diving that exceeds the List of diver certification organizations, agency-specified limits of recreational diving for non-Professional diver, professional purposes. Technica ...
and commercial diving instead of air to decrease density, reduce nitrogen narcosis and to avoid the dangers of oxygen toxicity. ** '' Heliox'' is a mixture of oxygen and helium and is often used in the deep phase of a commercial deep dive to eliminate nitrogen narcosis and reduce density, to limit work of breathing. Heliox is the standard mixture type for deep offshore saturation diving. ** '' Heliair'' is a form of trimix that is easily blended from helium and air without using pure oxygen. It always has a 21:79 ratio of oxygen to nitrogen; the balance of the mix is helium. ** '' Hydreliox'' is a mixture of oxygen, helium, and
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
and is used for dives below 130 metres in commercial diving. Experimental work using hydreliox is also done in deep technical diving, where the hydrogen is used to reduce HPNS. ** '' Hydrox'', a gas mixture of
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
and
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, is used as a breathing gas in very deep diving. ** ''Neox'' (also called neonox) is a mixture of oxygen and
neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ...
sometimes employed in deep commercial diving. It is rarely used due to its cost. Also, DCS symptoms produced by neon ("neox bends") have a poor reputation, being widely reported to be more severe than those produced by an exactly equivalent dive-table and mix with helium.


Breathing air

Breathing air is atmospheric air with a standard of purity suitable for human breathing in the specified application. For hyperbaric use, the partial pressure of contaminants is increased in proportion to the absolute pressure, and must be limited to a safe composition for the depth or pressure range in which it is to be used.


Classification by oxygen fraction

Breathing gases for diving are classified by oxygen fraction. The boundaries set by authorities may differ slightly, as the effects vary gradually with concentration and between people, and are not accurately predictable. ;: where the oxygen content does not differ greatly from that of air and allows continuous safe use at atmospheric pressure. ;, or : where the oxygen content exceeds atmospheric levels, generally to a level where there is some measurable physiological effect over long term use, and sometimes requiring special procedures for handling due to increased fire hazard. The associated risks are oxygen toxicity at depth and fire, particularly in the breathing apparatus. ;: where the oxygen content is less than that of air, generally to the extent that there is a significant risk of measurable physiological effect over the short term. The immediate risk is usually hypoxic incapacitation at or near the surface.


Individual component gases

Breathing gases for diving are mixed from a small number of component gases which provide special characteristics to the mixture which are not available from atmospheric air.


Oxygen

Oxygen (O2) must be present in every breathing gas. This is because it is essential to the
human body The human body is the entire structure of a Human, human being. It is composed of many different types of Cell (biology), cells that together create Tissue (biology), tissues and subsequently Organ (biology), organs and then Organ system, org ...
's metabolic process, which sustains life. The human body cannot store oxygen for later use as it does with food. If the body is deprived of oxygen for more than a few minutes, unconsciousness and death result. The tissues and organs within the body (notably the heart and brain) are damaged if deprived of oxygen for much longer than four minutes. Filling a diving cylinder with pure oxygen costs around five times more than filling it with compressed air. As oxygen supports combustion and causes rust in diving cylinders, it should be handled with caution when gas blending. Oxygen has historically been obtained by
fractional distillation Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation ...
of
liquid air Liquid Air was the marque of an automobile planned by Liquid Air Power and Automobile Co. of Boston and New York City in 1899. page 1432 A factory location was acquired in Boston, Massachusetts in 1899 and Liquid Air claimed they would constr ...
, but is increasingly obtained by non-cryogenic technologies such as pressure swing adsorption (PSA) and vacuum swing adsorption (VSA) technologies. The fraction of the oxygen component of a breathing gas mixture is sometimes used when naming the mix: * ''hypoxic'' mixes, strictly, contain less than 21% oxygen, although often a boundary of 16% is used, and are designed only to be breathed at depth as a "bottom gas" where the higher pressure increases the
partial pressure In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal g ...
of oxygen to a safe level. Trimix, Heliox and Heliair are gas blends commonly used for hypoxic mixes and are used in professional and
technical diving Technical diving (also referred to as tec diving or tech diving) is scuba diving that exceeds the List of diver certification organizations, agency-specified limits of recreational diving for non-Professional diver, professional purposes. Technica ...
as deep breathing gases. A may be assigned to a hypoxic gas mixture, based on the depth at which the partial pressure is equal to the minimum oxygen partial pressure acceptable to the person or organisation using the gas. * ''normoxic'' mixes have the same proportion of oxygen as air, 21%. The maximum operating depth of a normoxic mix could be as shallow as . Trimix with between 17% and 21% oxygen is often described as normoxic because it contains a high enough proportion of oxygen to be safe to breathe at the surface. * ''hyperoxic'' mixes have more than 21% oxygen. Enriched Air Nitrox (EANx) is a typical hyperoxic breathing gas. Hyperoxic mixtures, when compared to air, cause oxygen toxicity at shallower depths but can be used to shorten
decompression stop To prevent or minimize decompression sickness, divers must properly plan and monitor decompression. Divers follow a decompression model to safely allow the release of excess inert gases dissolved in their body tissues, which accumulated as ...
s by drawing dissolved inert gases out of the body more quickly. The fraction of the oxygen determines the greatest depth at which the mixture can safely be used to avoid oxygen toxicity. This depth is called the maximum operating depth. The concentration of oxygen in a gas mix depends on the fraction and the pressure of the mixture. It is expressed by the
partial pressure In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal g ...
of oxygen (PO2). The partial pressure of any component gas in a mixture is calculated as: :''partial pressure = total absolute pressure × volume fraction of gas component'' For the oxygen component, :PO2 = P × FO2 where: :PO2 = partial pressure of oxygen :P = total pressure :FO2 = volume fraction of oxygen content The minimum safe partial pressure of oxygen in a breathing gas is commonly held to be 16  kPa (0.16 bar). Below this partial pressure the diver may be at risk of unconsciousness and death due to hypoxia, depending on factors including individual physiology and level of exertion. When a hypoxic mix is breathed in shallow water it may not have a high enough PO2 to keep the diver conscious. For this reason normoxic or hyperoxic "travel gases" are used at medium depth between the "bottom" and "decompression" phases of the dive. The maximum safe PO2 in a breathing gas depends on exposure time, the level of exercise and the security of the breathing equipment being used. It is typically between 100 kPa (1 bar) and 160 kPa (1.6 bar); for dives of less than three hours it is commonly considered to be 140 kPa (1.4 bar), although the U.S. Navy has been known to authorize dives with a PO2 of as much as 180 kPa (1.8 bar). At high PO2 or longer exposures, the diver risks oxygen toxicity which may result in a
seizure A seizure is a sudden, brief disruption of brain activity caused by abnormal, excessive, or synchronous neuronal firing. Depending on the regions of the brain involved, seizures can lead to changes in movement, sensation, behavior, awareness, o ...
. Each breathing gas has a maximum operating depth that is determined by its oxygen content. For therapeutic recompression and hyperbaric oxygen therapy partial pressures of 2.8 bar are commonly used in the chamber, but there is no risk of drowning if the occupant loses consciousness. For longer periods such as in saturation diving, 0.4 bar can be tolerated over several weeks. Oxygen analysers are used to measure the oxygen partial pressure in the gas mix. Divox is breathing grade oxygen labelled for diving use. In the
Netherlands , Terminology of the Low Countries, informally Holland, is a country in Northwestern Europe, with Caribbean Netherlands, overseas territories in the Caribbean. It is the largest of the four constituent countries of the Kingdom of the Nether ...
, pure oxygen for breathing purposes is regarded as medicinal as opposed to industrial oxygen, such as that used in
welding Welding is a fabrication (metal), fabrication process that joins materials, usually metals or thermoplastics, primarily by using high temperature to melting, melt the parts together and allow them to cool, causing Fusion welding, fusion. Co ...
, and is only available on
medical prescription A prescription, often abbreviated or Rx, is a formal communication from physicians or other registered healthcare professionals to a pharmacist, authorizing them to dispense a specific prescription drug for a specific patient. Historicall ...
. The diving industry registered Divox as a
trademark A trademark (also written trade mark or trade-mark) is a form of intellectual property that consists of a word, phrase, symbol, design, or a combination that identifies a Good (economics and accounting), product or Service (economics), service f ...
for breathing grade oxygen to circumvent the strict rules concerning medicinal oxygen thus making it easier for (recreational) scuba divers to obtain oxygen for blending their breathing gas. In most countries, there is no difference in purity in medical oxygen and industrial oxygen, as they are produced by exactly the same methods and manufacturers, but labeled and filled differently. The chief difference between them is that the record-keeping trail is much more extensive for medical oxygen, to more easily identify the exact manufacturing trail of a "lot" or batch of oxygen, in case problems with its purity are discovered. Aviation grade oxygen is similar to medical oxygen, but may have a lower moisture content.


Diluent gases

Gases which have no metabolic function in the breathing gas are used to dilute the gas, and are therefore classed as diluent gases. Some of them have a reversible narcotic effect at high partial pressure, and must therefore be limited to avoid excessive narcotic effects at the maximum pressure at which they are intended to be breathed. Diluent gases also affect the density of the gas mixture and thereby the work of breathing.


= Nitrogen

=
Nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
(N2) is a
diatomic Diatomic molecules () are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen () or oxygen (), then it is said to be homonuclear mol ...
gas and the main component of
air An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
, the cheapest and most common breathing gas used for diving. It causes nitrogen narcosis in the diver, so its use is limited to shallower dives. Nitrogen can cause
decompression sickness Decompression sickness (DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from Solution (chemistry), solution as bubbles inside the body tissues during D ...
. Equivalent air depth is used to estimate the decompression requirements of a nitrox (oxygen/nitrogen) mixture. Equivalent narcotic depth is used to estimate the narcotic potency of trimix (oxygen/helium/nitrogen mixture). Many divers find that the level of narcosis caused by a dive, whilst breathing air, is a comfortable maximum. Nitrogen in a gas mix is almost always obtained by adding air to the mix.


= Helium

=
Helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
(He) is an inert gas that is less narcotic than nitrogen at equivalent pressure (in fact there is no evidence for any narcosis from helium at all), and it has a much lower density, so it is more suitable for deeper dives than nitrogen. Helium is equally able to cause
decompression sickness Decompression sickness (DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from Solution (chemistry), solution as bubbles inside the body tissues during D ...
. At high pressures, helium also causes high-pressure nervous syndrome, which is a central nervous system irritation syndrome which is in some ways opposite to narcosis. Helium mixture fills are considerably more expensive than air fills due to the cost of helium and the cost of mixing and compressing the mix. Helium is not suitable for
dry suit A dry suit or drysuit provides the wearer with environmental protection by way of thermal insulation and exclusion of water, and is worn by underwater diving, divers, boating, boaters, List of water sports, water sports enthusiasts, and others wh ...
inflation owing to its poor
thermal insulation Thermal insulation is the reduction of heat transfer (i.e., the transfer of thermal energy between objects of differing temperature) between objects in thermal contact or in range of radiative influence. Thermal insulation can be achieved with s ...
properties – compared to air, which is regarded as a reasonable insulator, helium has six times the thermal conductivity. Helium's low molecular weight (monatomic MW=4, compared with diatomic nitrogen MW=28) increases the timbre of the breather's voice, which may impede communication. This is because the speed of sound is faster in a lower molecular weight gas, which increases the resonance frequency of the vocal cords. Helium leaks from damaged or faulty
valve A valve is a device or natural object that regulates, directs or controls the flow of a fluid (gases, liquids, fluidized solids, or Slurry, slurries) by opening, closing, or partially obstructing various passageways. Valves are technically Pip ...
s more readily than other gases because atoms of helium are smaller allowing them to pass through smaller gaps in seals. Helium is found in significant amounts only in
natural gas Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium ...
, from which it is extracted at low temperatures by fractional distillation.


= Neon

=
Neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ...
(Ne) is an inert gas sometimes used in deep commercial diving but is very expensive. Like helium, it is less narcotic than nitrogen, but unlike helium, it does not distort the diver's voice. Compared to helium, neon has superior thermal insulating properties. Neon has an atomic and molecular weight of approximately 20, compared to 14 for nitrogen and 4 for helium, but nitrogen gas (N2)has a molecular weight of 28.


= Hydrogen

=
Hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
(H2) has been used in deep diving gas mixes but is very explosive when mixed with more than about 4 to 5% oxygen (such as the oxygen found in breathing gas). This limits use of hydrogen to deep dives and imposes complicated protocols to ensure that excess oxygen is cleared from the breathing equipment before breathing hydrogen starts. Like helium, it raises the timbre of the diver's voice. The hydrogen-oxygen mix when used as a diving gas is sometimes referred to as Hydrox. Mixtures containing both hydrogen and helium as diluents are termed Hydreliox.


Unwelcome components of breathing gases for diving

Many gases are not suitable for use in diving breathing gases. Here is an incomplete list of gases commonly present in a diving environment:


Argon

Argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
(Ar) is an inert gas that is more narcotic than nitrogen, so is ''not'' generally suitable as a diving breathing gas. Argox is used for decompression research. It is sometimes used for
dry suit A dry suit or drysuit provides the wearer with environmental protection by way of thermal insulation and exclusion of water, and is worn by underwater diving, divers, boating, boaters, List of water sports, water sports enthusiasts, and others wh ...
inflation by divers whose primary breathing gas is helium-based, because of argon's good thermal insulation properties. Argon is more expensive than air or oxygen, but considerably less expensive than helium. Argon is a component of natural air, and constitutes 0.934% by volume of the Earth's atmosphere.


Carbon dioxide

Carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
(CO2) is produced by the
metabolism Metabolism (, from ''metabolē'', "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion of the energy in food to energy available to run cellular processes; the co ...
in the
human body The human body is the entire structure of a Human, human being. It is composed of many different types of Cell (biology), cells that together create Tissue (biology), tissues and subsequently Organ (biology), organs and then Organ system, org ...
and can cause carbon dioxide poisoning. When breathing gas is recycled in a
rebreather A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's exhaled breath to permit the rebreathing (recycling) of the substantial unused oxygen content, and unused inert content when present, of each breath. Oxygen is a ...
or life support system, the carbon dioxide is removed by scrubbers before the gas is re-used.


Carbon monoxide

Carbon monoxide Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
(CO) is a highly toxic gas that competes with dioxygen for binding to hemoglobin, thereby preventing the blood from carrying oxygen (see
carbon monoxide poisoning Carbon monoxide poisoning typically occurs from breathing in carbon monoxide (CO) at excessive levels. Symptoms are often described as " flu-like" and commonly include headache, dizziness, weakness, vomiting, chest pain, and confusion. Large ...
). It is typically produced by incomplete
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
. Four common sources are: *
Internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal comb ...
exhaust gas Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends, or coal. According to the type of engine, it is discharged into the atmosphere through ...
containing CO in the air being drawn into a diving air compressor. CO in the intake air cannot be stopped by any filter. The exhausts of all internal combustion engines running on petroleum fuels contain some CO, and this is a particular problem on boats, where the intake of the compressor cannot be arbitrarily moved as far as desired from the engine and compressor exhausts. * Heating of
lubricant A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, ...
s inside the compressor may vaporize them sufficiently to be available to a compressor intake or intake system line. * In some cases hydrocarbon lubricating oil may be drawn into the compressor's cylinder directly through damaged or worn seals, and the oil may (and usually will) then undergo combustion, being ignited by the immense compression ratio and subsequent temperature rise. Since heavy oils don't burn well – especially when not atomized properly – incomplete combustion will result in carbon monoxide production. * A similar process is thought to potentially happen to any particulate material, which contains "organic" (carbon-containing) matter, especially in cylinders which are used for hyperoxic gas mixtures. If the compressor air filter(s) fail, ordinary
dust Dust is made of particle size, fine particles of solid matter. On Earth, it generally consists of particles in the atmosphere that come from various sources such as soil lifted by wind (an aeolian processes, aeolian process), Types of volcan ...
will be introduced to the cylinder, which contains organic matter (since it usually contains
humus In classical soil science, humus is the dark organic matter in soil that is formed by the decomposition of plant and animal matter. It is a kind of soil organic matter. It is rich in nutrients and retains moisture in the soil. Humus is the Lati ...
). A more severe danger is that air particulates on boats and industrial areas, where cylinders are filled, often contain carbon-particulate combustion products (these are what makes a dirt rag black), and these represent a more severe CO danger when introduced into a cylinder. Carbon monoxide is generally avoided as far as is reasonably practicable by positioning of the air intake in uncontaminated air, filtration of particulates from the intake air, use of suitable compressor design and appropriate lubricants, and ensuring that running temperatures are not excessive. Where the residual risk is excessive, a hopcalite catalyst can be used in the high pressure filter to convert carbon monoxide into carbon dioxide, which is far less toxic.


Hydrocarbons

Hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
s (C''x''H''y'') are present in compressor lubricants and
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work (physics), work. The concept was originally applied solely to those materials capable of releasing chem ...
s. They can enter diving cylinders as a result of contamination, leaks, or due to incomplete combustion near the air intake. * They can act as a
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work (physics), work. The concept was originally applied solely to those materials capable of releasing chem ...
in combustion increasing the risk of
explosion An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated ...
, especially in high-oxygen gas mixtures. * Inhaling oil mist can damage the
lung The lungs are the primary Organ (biology), organs of the respiratory system in many animals, including humans. In mammals and most other tetrapods, two lungs are located near the Vertebral column, backbone on either side of the heart. Their ...
s and ultimately cause the lungs to degenerate with severe lipid pneumonia or
emphysema Emphysema is any air-filled enlargement in the body's tissues. Most commonly emphysema refers to the permanent enlargement of air spaces (alveoli) in the lungs, and is also known as pulmonary emphysema. Emphysema is a lower respiratory tract di ...
.


Moisture content

The process of compressing gas into a diving cylinder removes moisture from the gas. This is good for
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
prevention in the cylinder but means that the diver inhales very dry gas. The dry gas extracts moisture from the diver's lungs while underwater contributing to
dehydration In physiology, dehydration is a lack of total body water that disrupts metabolic processes. It occurs when free water loss exceeds intake, often resulting from excessive sweating, health conditions, or inadequate consumption of water. Mild deh ...
, which is also thought to be a predisposing risk factor of
decompression sickness Decompression sickness (DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from Solution (chemistry), solution as bubbles inside the body tissues during D ...
. Evaporation in the lungs causes a significant heat loss. Dry gas is also uncomfortable, causing a dry mouth and throat and making the diver thirsty. This problem is reduced in
rebreather A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's exhaled breath to permit the rebreathing (recycling) of the substantial unused oxygen content, and unused inert content when present, of each breath. Oxygen is a ...
s because the
soda lime Soda lime, a mixture of sodium hydroxide (NaOH) and calcium oxide (CaO), is used in granular form within recirculating breathing environments like general anesthesia and its breathing circuit, submarines, rebreathers, and hyperbaric chambers and u ...
reaction, which removes carbon dioxide, also puts moisture back into the breathing gas, and the relative humidity and temperature of exhaled gas is relatively high and there is a cumulative effect due to rebreathing. In hot climates, open circuit diving can accelerate heat exhaustion because of dehydration. Another concern with regard to moisture content is the tendency of moisture to condense as the gas expands while passing through the regulator; this coupled with the extreme reduction in temperature, also due to the decompression, can cause the moisture to solidify as ice. This icing up in a regulator can cause moving parts to seize and the regulator to fail or free flow. This is one of the reasons that scuba regulators are generally constructed from brass, and chrome plated (for protection). Brass, with its good thermal conductive properties, quickly conducts heat from the surrounding water to the cold, newly decompressed air, helping to prevent icing up.


Gas analysis

Gas mixtures must generally be analysed either in process or after blending for quality control. This is particularly important for breathing gas mixtures where errors can affect the health and safety of the end user. It is difficult to detect most gases that are likely to be present in diving cylinders because they are colourless, odourless and tasteless. Electronic sensors exist for some gases, such as oxygen analysers, helium analyser, carbon monoxide detectors and
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
detectors. Oxygen analysers are commonly found underwater in
rebreather A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's exhaled breath to permit the rebreathing (recycling) of the substantial unused oxygen content, and unused inert content when present, of each breath. Oxygen is a ...
s. Oxygen and helium analysers are often used on the surface during gas blending to determine the percentage of oxygen or helium in a breathing gas mix. Chemical and other types of gas detection methods are not often used in recreational diving, but are used for periodic quality testing of compressed breathing air from diving air compressors.


Breathing gas standards

Standards for breathing gas quality are published by national and international organisations, and may be enforced in terms of legislation. In the UK, the Health and Safety Executive indicate that the requirements for breathing gases for divers are based on the BS EN 12021:2014. The specifications are listed for oxygen compatible air, nitrox mixtures produced by adding oxygen, removing nitrogen, or mixing nitrogen and oxygen, mixtures of helium and oxygen (heliox), mixtures of helium, nitrogen and oxygen (trimix), and pure oxygen, for both open circuit and reclaim systems, and for high pressure and low pressure supply (above and below 40 bar supply). Oxygen content is variable depending on the operating depth, but the tolerance depends on the gas fraction range, being ±0.25% for an oxygen fraction below 10% by volume, ±0.5% for a fraction between 10% and 20%, and ±1% for a fraction over 20%. Water content is limited by risks of icing of control valves, and corrosion of containment surfaces – higher humidity is not a physiological problem – and is generally a factor of
dew point The dew point is the temperature the air needs to be cooled to (at constant pressure) in order to produce a relative humidity of 100%. This temperature depends on the pressure and water content of the air. When the air at a temperature above the ...
. Other specified contaminants are carbon dioxide, carbon monoxide, oil, and volatile hydrocarbons, which are limited by toxic effects. Other possible contaminants should be analysed based on risk assessment, and the required frequency of testing for contaminants is also based on risk assessment. In Australia breathing air quality is specified by Australian Standard 2299.1, Section 3.13 Breathing Gas Quality.


Diving gas blending

Gas blending (or gas mixing) of breathing gases for diving is the filling of
gas cylinder A gas cylinder is a pressure vessel for storage and containment of gases at above atmospheric pressure. Gas storage cylinders may also be called ''bottles''. Inside the cylinder the stored contents may be in a state of compressed gas, vapor ov ...
s with non-
air An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
breathing gas mixtures. Filling cylinders with a mixture of gases has dangers for both the filler and the diver. During filling there is a risk of fire due to use of oxygen and a risk of explosion due to the use of high-pressure gases. The composition of the mix must be safe for the depth and duration of the planned dive. If the concentration of oxygen is too lean the diver may lose consciousness due to hypoxia and if it is too rich the diver may develop oxygen toxicity. The concentration of inert gases, such as nitrogen and helium, are planned and checked to avoid nitrogen narcosis and decompression sickness. Methods used include batch mixing by partial pressure or by mass fraction, and continuous blending processes. Completed blends are analysed for composition for the safety of the user. Gas blenders may be required by legislation to prove competence if filling for other persons.


Density

Excessive density of a breathing gas can raise the work of breathing to intolerable levels, and can cause carbon dioxide retention at lower densities. Helium is used as a component to reduce density as well as to reduce narcosis at depth. Like partial pressure, density of a mixture of gases is in proportion to the volumetric fraction of the component gases, and absolute pressure. The ideal gas laws are adequately precise for gases at respirable pressures. The density of a gas mixture at a given temperature and pressure can be calculated as: :ρm = (ρ1 V1 + ρ2 V2 + .. + ρn Vn) / (V1 + V2 + ... + Vn) where :ρm = density of the gas mixture :ρ1 ... ρn = density of each of the components :V1 ... Vn = partial volume of each of the component gases Since gas fraction Fi (volumetric fraction) of each gas can be expressed as Vi / (V1 + V2 + ... + Vn ) by substitution, :ρm = (ρ1 F1 + ρ2 F2 + .. + ρn Fn)


Hypobaric breathing gases

Breathing gases for use at reduced ambient pressure are used for high altitude flight in unpressurised
aircraft An aircraft ( aircraft) is a vehicle that is able to flight, fly by gaining support from the Atmosphere of Earth, air. It counters the force of gravity by using either Buoyancy, static lift or the Lift (force), dynamic lift of an airfoil, or, i ...
, in
space flight Spaceflight (or space flight) is an application of astronautics to fly objects, usually spacecraft, into or through outer space, either with or without humans on board. Most spaceflight is uncrewed and conducted mainly with spacecraft such a ...
, particularly in space suits, and for high altitude
mountaineering Mountaineering, mountain climbing, or alpinism is a set of outdoor activities that involves ascending mountains. Mountaineering-related activities include traditional outdoor climbing, skiing, and traversing via ferratas that have become mounta ...
. In all these cases, the primary consideration is providing an adequate
partial pressure In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal g ...
of oxygen. In some cases the breathing gas has oxygen added to make up a sufficient concentration, and in other cases the breathing gas may be pure or nearly pure oxygen. Closed circuit systems may be used to conserve the breathing gas, which may be in limited supply – in the case of mountaineering the user must carry the supplemental oxygen, and in space flight the cost of lifting mass into orbit is very high.


Medical breathing gases

Medical use of breathing gases other than air include oxygen therapy and anesthesia applications.


Oxygen therapy

upA person wearing a simple face mask for oxygen therapy Oxygen is required by people for normal cell metabolism. Air is typically 21% oxygen by volume. This is normally sufficient, but in some circumstances the oxygen supply to tissues is compromised.
Oxygen therapy Oxygen therapy, also referred to as supplemental oxygen, is the use of oxygen as medical treatment. Supplemental oxygen can also refer to the use of oxygen enriched air at altitude. Acute indications for therapy include hypoxemia (low blood o ...
, also known as supplemental oxygen, is the use of
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
as a medical treatment. This can include for low blood oxygen, carbon monoxide toxicity,
cluster headache Cluster headache is a neurological disorder characterized by recurrent severe headaches on one side of the head, typically around the eye, eye(s). There is often accompanying eye watering, nasal congestion, or swelling around the eye on the aff ...
s, and to maintain enough oxygen while
inhaled anesthetics An inhalational anesthetic is a chemical compound possessing general anesthetic properties that is delivered via inhalation. They are administered through a face mask, laryngeal mask airway or tracheal tube connected to an anesthetic vaporise ...
are given. Long term oxygen is often useful in people with chronically low oxygen such as from severe
COPD Chronic obstructive pulmonary disease (COPD) is a type of progressive lung disease characterized by chronic respiratory symptoms and airflow limitation. GOLD defines COPD as a heterogeneous lung condition characterized by chronic respiratory s ...
or
cystic fibrosis Cystic fibrosis (CF) is a genetic disorder inherited in an autosomal recessive manner that impairs the normal clearance of Sputum, mucus from the lungs, which facilitates the colonization and infection of the lungs by bacteria, notably ''Staphy ...
. Oxygen can be given in a number of ways including
nasal cannula The nasal cannula (NC) is a device used to deliver supplemental oxygen or increased airflow to a patient or person in need of respiratory help. This device consists of a lightweight tube which on one end splits into two prongs which are place ...
, face mask, and inside a
hyperbaric chamber A diving chamber is a vessel for human occupation, which may have an entrance that can be sealed to hold an internal pressure significantly higher than ambient pressure, a pressurised gas system to control the internal pressure, and a supply of ...
. High concentrations of oxygen can cause oxygen toxicity such as lung damage or result in
respiratory failure Respiratory failure results from inadequate gas exchange by the respiratory system, meaning that the arterial oxygen, carbon dioxide, or both cannot be kept at normal levels. A drop in the oxygen carried in the blood is known as hypoxemia; a r ...
in those who are predisposed. It can also dry out the nose and increase the risk of fires in those who
smoke Smoke is an aerosol (a suspension of airborne particulates and gases) emitted when a material undergoes combustion or pyrolysis, together with the quantity of air that is entrained or otherwise mixed into the mass. It is commonly an unwante ...
. The target
oxygen saturation Oxygen saturation (symbol SO2) is a relative measure of the concentration of oxygen that is Dissolution (chemistry), dissolved or carried in a given medium as a proportion of the maximal concentration that can be dissolved in that medium at the g ...
recommended depends on the condition being treated. In most conditions a saturation of 94-98% is recommended, while in those at risk of carbon dioxide retention saturations of 88-92% are preferred, and in those with carbon monoxide toxicity or
cardiac arrest Cardiac arrest (also known as sudden cardiac arrest [SCA]) is when the heart suddenly and unexpectedly stops beating. When the heart stops beating, blood cannot properly Circulatory system, circulate around the body and the blood flow to the ...
the saturation should be as high as possible. The use of oxygen in medicine become common around 1917. It is on the WHO Model List of Essential Medicines, World Health Organization's List of Essential Medicines. The cost of home oxygen is about US$150 a month in Brazil and US$400 a month in the United States. Home oxygen can be provided either by oxygen tanks or an oxygen concentrator. Oxygen is believed to be the most common treatment given in hospitals in the developed world.


Anaesthetic gases

image:Maquet Flow-I anesthesia machine.jpg, upAn anaesthetic machine. The most common approach to general anaesthesia is through the use of inhaled general anesthetics. Each has its own potency which is correlated to its solubility in oil. This relationship exists because the drugs bind directly to cavities in proteins of the central nervous system, although several theories of general anaesthetic action have been described. Inhalational anesthetics are thought to exact their effects on different parts of the central nervous system. For instance, the paralysis, immobilizing effect of inhaled anesthetics results from an effect on the spinal cord whereas sedation, hypnosis and amnesia involve sites in the brain. An inhalational anaesthetic is a chemical compound possessing general anaesthetic properties that can be delivered via inhalation. Agents of significant contemporary clinical interest include Volatility (chemistry), volatile anaesthetic agents such as isoflurane, sevoflurane and desflurane, and anaesthetic gases such as nitrous oxide and xenon.


Administration

Anaesthetic gases are administered by anaesthetists (a term which includes anesthesiologist, anaesthesiologists, nurse anesthetist, nurse anaesthetists, and Anesthesia#Anesthesiologist assistants, anaesthesiologist assistants) through an anaesthesia mask, laryngeal mask airway or tracheal tube connected to an anaesthetic vaporiser and an anaesthetic machine, anaesthetic delivery system. The anaesthetic machine (UK English) or anesthesia machine (US English) or Boyle's machine is used to support the administration of Anesthesia, anaesthesia. The most common type of anaesthetic machine in use in the developed world is the continuous-flow anaesthetic machine, which is designed to provide an accurate and continuous supply of medical gases (such as
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
and nitrous oxide), mixed with an accurate concentration of anaesthetic vapour (such as isoflurane), and deliver this to the patient at a safe
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
and flow. Modern machines incorporate a ventilator, Suction (medicine), suction unit, and Monitoring (medicine), patient monitoring devices. Exhaled gas is passed through a scrubber to remove carbon dioxide, and the anaesthetic vapour and oxygen are replenished as required before the mixture is returned to the patient.


See also

* * * * *


References


External links

* * * * {{DEFAULTSORT:Breathing Gas Breathing gases, Industrial gases Breathing apparatus components