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Blueschist (), also called glaucophane schist, is a
metavolcanic rock Metavolcanic rock is volcanic rock that shows signs of having experienced metamorphism. In other words, the rock was originally produced by a volcano, either as lava or tephra. The rock was then subjected to high pressure, high temperature or both ...
that forms by the
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
of
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
and rocks with similar composition at high
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...
s and low
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temp ...
s (), approximately corresponding to a depth of . The blue color of the rock comes from the presence of the predominant minerals
glaucophane Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2. Glaucophane crystallizes in the monoclinic system. Name G ...
and
lawsonite Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to transluc ...
. Blueschists are
schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes ...
s typically found within
orogenic belts Orogeny is a mountain building process. An orogeny is an event that takes place at a convergent plate margin when plate motion compresses the margin. An ''orogenic belt'' or ''orogen'' develops as the compressed plate crumples and is uplifted t ...
as
terrane In geology, a terrane (; in full, a tectonostratigraphic terrane) is a crust (geology), crust fragment formed on a tectonic plate (or broken off from it) and Accretion (geology), accreted or "Suture (geology), sutured" to crust lying on another pla ...
s of lithology in faulted contact with
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite ...
or rarely
eclogite Eclogite () is a metamorphic rock containing garnet (almandine- pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, ...
facies rocks.


Petrology

Blueschist, as a rock type, is defined by the presence of the minerals
glaucophane Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2. Glaucophane crystallizes in the monoclinic system. Name G ...
+ (
lawsonite Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to transluc ...
or
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in hab ...
) +/- jadeite +/-
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
or chlorite +/-
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...
+/-
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
in a rock of roughly basaltic composition.
Blueschist often has a lepidoblastic, nematoblastic or
schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes ...
ose
rock microstructure Rock microstructure includes the texture and small-scale structures of a rock. The words ''texture'' and ''microstructure'' are interchangeable, with the latter preferred in modern geological literature. However, ''texture'' is still acceptable ...
defined primarily by chlorite, phengitic white mica, glaucophane, and other minerals with an elongate or platy shape. Grain size is rarely coarse, as mineral growth is retarded by the swiftness of the rock's metamorphic trajectory and perhaps more importantly, the low temperatures of metamorphism and in many cases the anhydrous state of the basalts. However, porphyritic varieties do occur. Blueschists may appear blue, black, gray, or blue-green in outcrop.


Blueschist facies

Blueschist facies is determined by the particular temperature and pressure conditions required to metamorphose basalt to form blueschist. Felsic rocks and
pelitic A pelite (Greek: ''pelos'', "clay") or metapelite is a metamorphosed fine-grained sedimentary rock, i.e. mudstone or siltstone. The term was earlier used by geologists to describe a clay-rich, fine-grained clastic sediment or sedimentary rock ...
sediments which are subjected to blueschist facies conditions will form different mineral assemblages than metamorphosed basalt. Thereby, these rocks do not appear blue overall in color. Blueschist mineralogy varies by rock composition, but the classic equilibrium assemblages of blueschist facies are: * Basalts: ''glaucophane + lawsonite and/or epidote + albite +
titanite Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals ...
+/- garnet +/- quartz'' ''jadeite + quartz'' - diagnostic of pressures ~> 10 kbar *
Ultramafic Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed ...
rocks: ''
serpentinite Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''se ...
/ lizardite +/-
talc Talc, or talcum, is a clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent a ...
+/-
zoisite Zoisite, first known as saualpite, after its type locality, is a calcium aluminium hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2 Al3( Si O4)(Si2O7)O(O H). Zoisite occurs as prismatic, orthorho ...
'' *
Pelite A pelite ( Greek: ''pelos'', "clay") or metapelite is a metamorphosed fine-grained sedimentary rock, i.e. mudstone or siltstone. The term was earlier used by geologists to describe a clay-rich, fine-grained clastic sediment or sedimentary rock, ...
s: ''Fe-Mg-carpholite +/-
chloritoid Chloritoid is a silicate mineral of Metamorphism, metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula . It occurs as greenish grey to black platy micaceous crystals and foliation (geology), foliated masses. ...
+/-
kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks gener ...
+ zoisite +/-
pargasite Pargasite is a complex inosilicate mineral of the amphibole group with formula NaCa2(Mg4Al)(Si6Al2)O22(OH)2. It was first described for an occurrence in Pargas, Finland in 1814 and named for the locality. It occurs in high temperature regional ...
or
phengite Phengite is a series name for dioctahedral micas of composition K(AlMg)2(OH)2(SiAl)4O10 it is common for Mg or Fe2+ to substitute for Al on the Y site and a corresponding increase in Si on the Z site in the mica group formula ''X''2''Y''4–6''Z' ...
+/- albite +/- quartz +/- talc +/- garnet'' *
Granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies under ...
s: ''
kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks gener ...
+/-
paragonite Paragonite is a mineral, related to muscovite. Its empirical formula is . A wide solvus separates muscovite from paragonite, such that there is little solid solution along the vector Na+ K+ and apparent micas of intermediate composition is most ...
+/- chlorite +/- albite +/- quartz +/- pargasite or phengite'' * Calc-silicates: Various *
Limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
s and
marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Marble is typically not foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorphose ...
: calcite transforms to
aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
at high pressure, but typically reverts to calcite when exhumed Blueschist facies generally is considered to form under pressures of >0.6
GPa Grading in education is the process of applying standardized measurements for varying levels of achievements in a course. Grades can be assigned as letters (usually A through F), as a range (for example, 1 to 6), as a percentage, or as a numbe ...
, equivalent to depth of burial in excess of 15–18 km, and at temperatures of between 200 and 500 °C. This is a 'low temperature, high pressure' prograde metamorphic path and is also known as the ''Franciscan facies series'', after the west coast of the United States where these rocks are exposed. Well-exposed blueschists also occur in Greece, Turkey, Japan, New Zealand and New Caledonia. Continued subduction of blueschist facies
oceanic crust Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust, with pillow lavas and a dike complex, and the lower oceanic crust, composed of troctolite, gabbro and ultramafic ...
will produce
eclogite Eclogite () is a metamorphic rock containing garnet (almandine- pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, ...
facies assemblages in metamorphosed basalt (garnet + omphacitic clinopyroxene). Rocks which have been subjected to blueschist conditions during a prograde trajectory will gain heat by conduction with hotter lower crustal rocks if they remain at the 15–18 km depth. Blueschist which heats up to greater than 500 °C via this fashion will enter
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite ...
or
eclogite Eclogite () is a metamorphic rock containing garnet (almandine- pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, ...
facies temperature-pressure conditions, and the mineral assemblages will metamorphose to reflect the new facies conditions. Thus in order for blueschist facies assemblages to be seen at the Earth's surface, the rock must be exhumed swiftly enough to prevent total thermal equilibration of the rocks which are under blueschist facies conditions with the typical
geothermal gradient Geothermal gradient is the rate of temperature change with respect to increasing depth in Earth's interior. As a general rule, the crust temperature rises with depth due to the heat flow from the much hotter mantle; away from tectonic plate bo ...
. Blueschists and other high-pressure subduction zone rocks are thought to be exhumed rapidly by flow and/or faulting in
accretionary wedge An accretionary wedge or accretionary prism forms from sediments accreted onto the non- subducting tectonic plate at a convergent plate boundary. Most of the material in the accretionary wedge consists of marine sediments scraped off from the d ...
s or the upper parts of subducted crust, or may return to the Earth's surface in part owing to buoyancy if the metabasaltic rocks are associated with low-density continental crust (marble, metapelite, and other rocks of continental margins). It has been held that the absence of blueschist dating to before the Neoproterozoic Era indicates that currently exhumed rocks never reached blueschist facies at subduction zones before 1,000 million years ago. This assertion is arguably wrong because the earliest
oceanic crust Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust, with pillow lavas and a dike complex, and the lower oceanic crust, composed of troctolite, gabbro and ultramafic ...
would have contained more
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
than today's crust and, therefore, would have formed greenschist-like rocks at blueschist facies.


History and etymology

In
Minoan Crete The Minoan civilization was a Bronze Age Aegean civilization on the island of Crete and other Aegean Islands, whose earliest beginnings were from 3500BC, with the complex urban civilization beginning around 2000BC, and then declining from 1450B ...
blueschist and
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite ...
were used to pave streets and
courtyard A courtyard or court is a circumscribed area, often surrounded by a building or complex, that is open to the sky. Courtyards are common elements in both Western and Eastern building patterns and have been used by both ancient and contemporary ...
s between 1650 and 1600 BC. These rocks were likely quarried in
Agia Pelagia Agia Pelagia ( el, Αγία Πελαγία, " Saint Pelagia") is a popular seaside resort 23 km northwest of Crete's capital city of Heraklion. In former times, Agia Pelagia was a tiny fishing village and a place for the residents of nearby Ach ...
on the north coast of central Crete. In 1962, Edgar Bailey of the
U.S. Geological Survey The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, and ...
, introduced the concept of "blueschist" into the subject of metamorphic
geology Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Ea ...
. His carefully constructed definition established the pressure and temperature conditions which produce this type of metamorphism.


See also

*
Metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
* List of rock types *
List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ...


References


External links


Blueschist facies - Rock Library Glossary, Imperial College London
{{Metamorphic Facies Schist Metamorphic petrology Volcanic rocks he:צפחה#צפחות כחולות