Saponite is a trioctahedral

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...

of the

smectite A smectite (; ; ) is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secon ...

group. Its chemical formula is . It is soluble in

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...

. It was first described in 1840 by Svanberg. Varieties of saponite are griffithite, bowlingite and sobotkite. It is soft, massive, and plastic, and exists in veins and cavities in

serpentinite Serpentinite is a metamorphic rock composed predominantly of serpentine group minerals formed by serpentinization of mafic or ultramafic rocks. The ancient origin of the name is uncertain; it may be from the similarity of its texture or color ...

and

basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...

. The name is derived from the

Greek Greek may refer to: Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group *Greek language, a branch of the Indo-European language family **Proto-Greek language, the assumed last common ancestor of all kno ...

''sapo'',

soap Soap is a salt (chemistry), salt of a fatty acid (sometimes other carboxylic acids) used for cleaning and lubricating products as well as other applications. In a domestic setting, soaps, specifically "toilet soaps", are surfactants usually u ...

. Other names include bowlingite; mountain soap; piotine;

soapstone Soapstone (also known as steatite or soaprock) is a talc-schist, which is a type of metamorphic rock. It is composed largely of the magnesium-rich mineral talc. It is produced by dynamothermal metamorphism and metasomatism, which occur in sub ...

Occurrence

Saponite was first described in 1840 for an occurrence in Lizard Point, Landewednack,

Cornwall Cornwall (; or ) is a Ceremonial counties of England, ceremonial county in South West England. It is also one of the Celtic nations and the homeland of the Cornish people. The county is bordered by the Atlantic Ocean to the north and west, ...

, England. It occurs in

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

veins Veins () are blood vessels in the circulatory system of humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are those of the pulmonary and fetal c ...

, in

vesicles,

skarn Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, ...

amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose ...

and

. Associated minerals include

celadonite Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula . It crystallizes in the monoclinic system and usually forms massive aggregates of prismatic crystallites or, ...

chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...

native copper Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native coppe ...

epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ha ...

orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles ...

, dolomite,

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

and

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

. Saponite is found in

Ząbkowice Śląskie Ząbkowice Śląskie ( ; ) is a town in Lower Silesian Voivodeship, in south-western Poland. It is the seat of Ząbkowice Śląskie County and of a local municipality called Gmina Ząbkowice Śląskie. The town lies approximately south of the ...

Silesia Silesia (see names #Etymology, below) is a historical region of Central Europe that lies mostly within Poland, with small parts in the Czech Silesia, Czech Republic and Germany. Its area is approximately , and the population is estimated at 8, ...

, Svärdsjö in Dalarna,

Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...

and in Cornwall, UK. The soapstone of Cornwall is used in the porcelain factory. Saponite is also found in the "dark rims" of chondrules in

carbonaceous chondrites Carbonaceous chondrites or C chondrites are a class of chondritic meteorites comprising at least 8 known groups and many ungrouped meteorites. They include some of the most primitive known meteorites. The C chondrites represent only a small propor ...

and seen as a sign of

aqueous An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in wat ...

alteration. Europe's largest primary diamond deposit, Lomonosov, in the Primorsky District of

Arkhangelsk Oblast Arkhangelsk Oblast ( rus, Архангельская область, p=ɐrˈxanɡʲɪlʲskəjə ˈobɫəsʲtʲ) is a federal subjects of Russia, federal subject of Russia (an oblast). It includes the Arctic Ocean, Arctic archipelagos of Franz ...

is an area of intensive accumulation and storage of saponite at the tailings.

Application

The forecasted mass of saponite to be discharged into the tailings of diamond ore processing makes up millions of tons. Worryingly, when macro- and micro-components are found in non-hazardous concentrations, fewer efforts are put into the environmental management of the tailings, though technogenic sediments offer prospects for reuse and valorization beyond their traditional disposal. Saponite is a demonstrative example of the tailings constituent that is often left unfairly mistreated. Electrochemical separation helps to obtain modified saponite-containing products with high smectite-group minerals concentrations, lower mineral particles size, more compact structure, and greater surface area. These characteristics open possibilities for the manufacture of high-quality ceramics and heavy-metal sorbents from saponite-containing products. Furthermore, tail grinding occurs during the preparation of the raw material for ceramics; this waste reprocessing is of high importance for the use of clay pulp as a neutralizing agent, as fine particles are required for the reaction. Experiments on the

Histosol In both the World Reference Base for Soil Resources (WRB) and the USDA soil taxonomy, a Histosol is a soil consisting primarily of organic materials. They are defined as having or more of organic soil material starting within 40 cm from the so ...

deacidification with the alkaline clay slurry demonstrated that neutralization with the average pH level of 7.1 is reached at 30% of the pulp added and an experimental site with perennial grasses proved the efficacy of the technique. Moreover, the reclamation of disturbed lands is an integral part of the social and environmental responsibility of the mining company and this scenario addresses the community necessities at both local and regional levels. Synthetic saponites have defined chemical composition and reactive surface and serve as a substitute for zeolites. In contrast to the pores in zeolites, saponites have a larger layer spacing and can also be used as catalysts for larger organic molecules, e.g. in polymerization, isomerization and cracking.

References

''This article contains material from the U.S. Bureau of Mines Dictionary of Mining, Mineral, and Related Terms.'' {{Clay minerals Clay minerals group Smectite group Calcium minerals Iron minerals Magnesium minerals Aluminium minerals Monoclinic minerals Minerals in space group 12

Occurrence

Application

See also

References