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The Bethe–Salpeter equation (BSE, named after
Hans Bethe Hans Albrecht Eduard Bethe (; ; July 2, 1906 – March 6, 2005) was a German-American physicist who made major contributions to nuclear physics, astrophysics, quantum electrodynamics and solid-state physics, and received the Nobel Prize in Physi ...
and Edwin Salpeter) is an
integral equation In mathematical analysis, integral equations are equations in which an unknown function appears under an integral sign. In mathematical notation, integral equations may thus be expressed as being of the form: f(x_1,x_2,x_3,\ldots,x_n ; u(x_1,x_2 ...
, the solution of which describes the structure of a relativistic two-body (particles)
bound state A bound state is a composite of two or more fundamental building blocks, such as particles, atoms, or bodies, that behaves as a single object and in which energy is required to split them. In quantum physics, a bound state is a quantum state of a ...
in a covariant formalism
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct phy ...
(QFT). The equation was first published in 1950 at the end of a paper by
Yoichiro Nambu was a Japanese-American physicist and professor at the University of Chicago. Known for his groundbreaking contributions to theoretical physics, Nambu was the originator of the theory of spontaneous symmetry breaking, a concept that revoluti ...
, but without derivation. Due to its common application in several branches of theoretical physics, the Bethe–Salpeter equation appears in many forms. One form often used in
high energy physics Particle physics or high-energy physics is the study of fundamental particles and forces that constitute matter and radiation. The field also studies combinations of elementary particles up to the scale of protons and neutrons, while the stu ...
is : \Gamma(P,p) =\int\!\frac \; K(P,p,k)\, S(k-\tfrac) \,\Gamma(P,k)\, S(k+\tfrac) where \Gamma is the Bethe–Salpeter amplitude (BSA), K the Green's function representing the interaction and S the dressed
propagator In quantum mechanics and quantum field theory, the propagator is a function that specifies the probability amplitude for a particle to travel from one place to another in a given period of time, or to travel with a certain energy and momentum. I ...
s of the two constituent particles. In quantum theory, bound states are composite physical systems with lifetime significantly longer than the time scale of the interaction breaking their structure (otherwise the physical systems under consideration are called
resonances Resonance is a phenomenon that occurs when an object or system is subjected to an external force or vibration whose frequency matches a resonant frequency (or resonance frequency) of the system, defined as a frequency that generates a maximu ...
), thus allowing ample time for constituents to interact. By accounting all possible interactions that can occur between the two constituents, the BSE is a tool to calculate properties of deep-bound states. The BSA as Its solution encodes the structure of the bound state under consideration. As it can be derived via identifying bound-states with poles in the
S-matrix In physics, the ''S''-matrix or scattering matrix is a Matrix (mathematics), matrix that relates the initial state and the final state of a physical system undergoing a scattering, scattering process. It is used in quantum mechanics, scattering ...
of the 4-point function involving the constituent particles, the equation is related to the quantum-field description of scattering processes applying
Green's functions In mathematics, a Green's function (or Green function) is the impulse response of an inhomogeneous linear differential operator defined on a domain with specified initial conditions or boundary conditions. This means that if L is a linear diff ...
. As a general-purpose tool the applications of the BSE can be found in most quantum field theories. Examples include
positronium Positronium (Ps) is a system consisting of an electron and its antimatter, anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two part ...
(bound state of an
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
positron The positron or antielectron is the particle with an electric charge of +1''elementary charge, e'', a Spin (physics), spin of 1/2 (the same as the electron), and the same Electron rest mass, mass as an electron. It is the antiparticle (antimatt ...
pair),
exciton An exciton is a bound state of an electron and an electron hole which are attracted to each other by the electrostatic Coulomb's law, Coulomb force resulting from their opposite charges. It is an electrically neutral quasiparticle regarded as ...
s (bound states of an
electron–hole pair In solid-state physics of semiconductors, carrier generation and carrier recombination are processes by which mobile charge carriers (electrons and electron holes) are created and eliminated. Carrier generation and recombination processes are fund ...
s), and
meson In particle physics, a meson () is a type of hadronic subatomic particle composed of an equal number of quarks and antiquarks, usually one of each, bound together by the strong interaction. Because mesons are composed of quark subparticles, the ...
s (as
quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nucleus, atomic nuclei ...
-antiquark bound states). Even for simple systems such as the
positronium Positronium (Ps) is a system consisting of an electron and its antimatter, anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two part ...
, the equation cannot be solved exactly under
quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the Theory of relativity, relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quant ...
(QED), despite its exact formulation. A reduction of the equation can be achieved without the exact solution. In the case where particle-pair production can be ignored, if one of the two fermion constituent is significantly more
mass Mass is an Intrinsic and extrinsic properties, intrinsic property of a physical body, body. It was traditionally believed to be related to the physical quantity, quantity of matter in a body, until the discovery of the atom and particle physi ...
ive than the other, the system is simplified into the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin-1/2 massive particles, called "Dirac ...
for the light particle under the external
potential Potential generally refers to a currently unrealized ability. The term is used in a wide variety of fields, from physics to the social sciences to indicate things that are in a state where they are able to change in ways ranging from the simple r ...
of the heavy one.


Derivation

The starting point for the derivation of the Bethe–Salpeter equation is the two-particle (or four point) Dyson equation : G = S_1\,S_2 + S_1\,S_2\, K_\, G in momentum space, where "G" is the two-particle Green function \langle\Omega, \phi_1 \,\phi_2\, \phi_3\, \phi_4 , \Omega\rangle , "S" are the free
propagator In quantum mechanics and quantum field theory, the propagator is a function that specifies the probability amplitude for a particle to travel from one place to another in a given period of time, or to travel with a certain energy and momentum. I ...
s and "K" is an interaction kernel, which contains all possible interactions between the two particles. The crucial step is now, to assume that bound states appear as poles in the Green function. One assumes, that two particles come together and form a bound state with mass "M", this bound state propagates freely, and then the bound state splits in its two constituents again. Therefore, one introduces the Bethe–Salpeter wave function \Psi = \langle\Omega, \phi_1 \,\phi_2, \psi\rangle , which is a transition amplitude of two constituents \phi_i into a bound state \psi, and then makes an Ansatz for the Green function in the vicinity of the pole as : G \approx \frac, where ''P'' is the total momentum of the system. One sees, that if for this momentum the equation P^2 = M^2 holds, which is exactly the Einstein energy-momentum relation (with the
Four-momentum In special relativity, four-momentum (also called momentum–energy or momenergy) is the generalization of the classical three-dimensional momentum to four-dimensional spacetime. Momentum is a vector in three dimensions; similarly four-momentum i ...
P_\mu = \left(E/c,\vec p \right) and P^2 = P_\mu\,P^\mu ), the four-point Green function contains a pole. If one plugs that Ansatz into the Dyson equation above, and sets the total momentum "P" such that the energy-momentum relation holds, on both sides of the term a pole appears. : \frac = S_1\,S_2 +S_1\,S_2\, K_\frac Comparing the residues yields : \Psi=S_1\,S_2\, K_\Psi, \, This is already the Bethe–Salpeter equation, written in terms of the Bethe–Salpeter wave functions. To obtain the above form one introduces the Bethe–Salpeter amplitudes "Γ" : \Psi = S_1\,S_2\,\Gamma and gets finally : \Gamma= K_\,S_1\,S_2\,\Gamma which is written down above, with the explicit momentum dependence.


Rainbow-ladder approximation

In principle the interaction kernel K contains all possible two-particle-irreducible interactions that can occur between the two constituents. In order to carry out practical calculations one has to model it by choosing a subset of the interactions. As in quantum field theories, interaction is described via the exchange of particles (e.g.
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless particles that can ...
s in QED, or
gluon A gluon ( ) is a type of Massless particle, massless elementary particle that mediates the strong interaction between quarks, acting as the exchange particle for the interaction. Gluons are massless vector bosons, thereby having a Spin (physi ...
s in
quantum chromodynamics In theoretical physics, quantum chromodynamics (QCD) is the study of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type of ...
), other than contact interactions the most simple interaction is modeled by the exchange of only one of these force-carrying particles with a known propagator. As the Bethe–Salpeter equation sums up the interaction infinitely many times from a perturbative view point, the resulting Feynman graph resembles the form of a ladder (or rainbow), hence the name of this approximation. While in QED the ladder approximation caused problems with crossing symmetry and gauge invariance, indicating the inclusion of crossed-ladder terms. In
quantum chromodynamics In theoretical physics, quantum chromodynamics (QCD) is the study of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type of ...
(QCD) this approximation is frequently used phenomenologically to calculate
hadron In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong nuclear force. Pronounced , the name is derived . They are analogous to molecules, which are held together by the electri ...
mass and its structure in terms of Bethe—Salpeter amplitudes and Faddeev amplitudes, a well-known Ansatz of which is proposed by Maris and Tandy. Such an Ansatz for the dressed quark-gluon vertex within the rainbow-ladder truncation respects chiral symmetry and its dynamical breaking, which therefore is an important modeling of the strong nuclear interaction. As an example the structure of
pion In particle physics, a pion (, ) or pi meson, denoted with the Greek alphabet, Greek letter pi (letter), pi (), is any of three subatomic particles: , , and . Each pion consists of a quark and an antiquark and is therefore a meson. Pions are the ...
s can be solved applying the Maris—Tandy Ansatz from the Bethe—Salpeter equation in
Euclidean space Euclidean space is the fundamental space of geometry, intended to represent physical space. Originally, in Euclid's ''Elements'', it was the three-dimensional space of Euclidean geometry, but in modern mathematics there are ''Euclidean spaces ...
.


Normalization

As for solutions of any homogeneous equation, that of the Bethe–Salpeter equation is determined up to a numerical factor. This factor has to be specified by a certain normalization condition. For the Bethe–Salpeter amplitudes this is usually done by demanding probability conservation (similar to the normalization of the quantum mechanical
wave function In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter) ...
), which corresponds to the equation :2 P_\mu = \bar\Gamma \left( \frac \left( S_1 \otimes S_2 \right) - S_1\,S_2\, \left(\frac\,K\right)\, S_1\,S_2\right) \Gamma Normalizations to the charge and energy-momentum tensor of the bound state lead to the same equation. In the rainbow-ladder approximation this Interaction kernel does not depend on the total momentum of the Bethe–Salpeter amplitude, in which case the second term of the normalization condition vanishes. An alternative normalization based on the eigenvalue of the corresponding linear operator was derived by Nakanishi.


Solution in the Minkowski space

The Bethe—Salpeter equation applies to all kinematic region of the Bethe—Salpeter amplitude. Consequently it determines the amplitudes where the functions are not continuous. Such singularities are usually located when the constituent momentum is timelike, which are not directly accessible from Euclidean-space solutions of this equation. Instead one develop methods to solve these types of integral equations directly in the timelike region. In the case of scalar bound states through a scalar-particle exchange in the rainbow-ladder truncation, the Bethe—Salpeter equation in the
Minkowski space In physics, Minkowski space (or Minkowski spacetime) () is the main mathematical description of spacetime in the absence of gravitation. It combines inertial space and time manifolds into a four-dimensional model. The model helps show how a ...
can be solved with the assistance of Nakanishi integral representation.


See also

* ABINIT * Araki–Sucher correction * Breit equation * Lippmann–Schwinger equation * Schwinger–Dyson equation * Two-body Dirac equations * YAMBO code


References


Bibliography

Many modern quantum field theory textbooks and a few articles provide pedagogical accounts for the Bethe–Salpeter equation's context and uses. See: * * Still a good introduction is given by the review article of Nakanishi * For historical aspects, see *


External links to codes where the Bethe-Salpeter equation is coded


Yambo
- plane-wave pseudopotential
BerkeleyGW
– plane-wave pseudopotential
ExC
- plane-wave pseudopotential
Fiesta
- Gaussian all-electron
Abinit
- plane-wave pseudopotential
VASP
- plane-wave pseudopotential For a more comprehensive list of first principles codes see here: List of quantum chemistry and solid-state physics software {{DEFAULTSORT:Bethe-Salpeter Equation Eponymous equations of physics Quantum field theory Quantum mechanics Hans Bethe