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atomic radius The atomic radius of a chemical element is a measure of the size of its atom, usually the mean or typical distance from the center of the nucleus to the outermost isolated electron. Since the boundary is not a well-defined physical entity, there ...
of a
chemical element A chemical element is a species of atoms that have a given number of protons in their atomic nucleus, nuclei, including the pure Chemical substance, substance consisting only of that species. Unlike chemical compounds, chemical elements canno ...
is the distance from the center of the nucleus to the outermost shell of an electron. Since the boundary is not a well-defined physical entity, there are various non-equivalent definitions of atomic radius. Depending on the definition, the term may apply only to isolated atoms, or also to atoms in
condensed matter Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the su ...
, covalently bound in
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and b ...
s, or in
ionized Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule ...
and
excited state In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to ...
s; and its value may be obtained through experimental measurements, or computed from theoretical models. Under some definitions, the value of the radius may depend on the atom's state and context. Atomic radii vary in a predictable and explicable manner across the
periodic table The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ch ...
. For instance, the radii generally decrease rightward along each period (row) of the table, from the
alkali metal The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...
s to the
noble gases The noble gases (historically also the inert gases; sometimes referred to as aerogens) make up a class of chemical elements with similar properties; under standard conditions, they are all odorless, colorless, monatomic gases with very low ch ...
; and increase down each group (column). The radius increases sharply between the noble gas at the end of each period and the alkali metal at the beginning of the next period. These trends of the atomic radii (and of various other chemical and physical properties of the elements) can be explained by the
electron shell In chemistry and atomic physics, an electron shell may be thought of as an orbit followed by electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or ...
theory of the atom; they provided important evidence for the development and confirmation of quantum theory.


Atomic radius

Note: All measurements given are in picometers (pm). For more recent data on covalent radii see
Covalent radius The covalent radius, ''r''cov, is a measure of the size of an atom that forms part of one covalent bond. It is usually measured either in picometres (pm) or angstroms (Å), with 1 Å = 100 pm. In principle, the sum of the two coval ...
. Just as atomic units are given in terms of the atomic mass unit (approximately the proton mass), the physically appropriate unit of length here is the Bohr radius, which is the radius of a hydrogen atom. The Bohr radius is consequently known as the "atomic unit of length". It is often denoted by ''a''0 and is approximately 53 pm. Hence, the values of atomic radii given here in picometers can be converted to atomic units by dividing by 53, to the level of accuracy of the data given in this table.


See also

*
Atomic radius The atomic radius of a chemical element is a measure of the size of its atom, usually the mean or typical distance from the center of the nucleus to the outermost isolated electron. Since the boundary is not a well-defined physical entity, there ...
*
Covalent radius The covalent radius, ''r''cov, is a measure of the size of an atom that forms part of one covalent bond. It is usually measured either in picometres (pm) or angstroms (Å), with 1 Å = 100 pm. In principle, the sum of the two coval ...
(Single-, double- and triple-bond radii, up to the superheavy elements.) *
Ionic radius Ionic radius, ''r''ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the catio ...


Notes

* Difference between empirical and experimental data: Empirical data basically means, "originating in or based on observation or experience" or "relying on experience or observation alone often without due regard for system and theory data". It basically means that you measured it through physical observation, and a lot of experiments generating ''the same results''. Although, note that the values are not calculated by a formula. However, often the empirical results then become an equation of estimation. Experimental data on the other hand are only based on theories. Such theoretical predictions are useful when there are no ways of measuring radii experimentally, if you want to predict the radius of an element that hasn't been discovered yet, or it has too short of a half-life. * The radius of an atom is not a uniquely defined property and depends on the definition. Data derived from other sources with different assumptions cannot be compared. *
† to an accuracy of about 5 pm
*
(b) 12 coordinate
*
(c)
gallium Gallium is a chemical element with the Symbol (chemistry), symbol Ga and atomic number 31. Discovered by France, French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in boron group, group 13 of the periodic table and is similar to ...
has an anomalous crystal structure
*
(d) 10 coordinate
*
(e)
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
,
neptunium Neptunium is a chemical element with the symbol Np and atomic number 93. A radioactive actinide metal, neptunium is the first transuranic element. Its position in the periodic table just after uranium, named after the planet Uranus, led to it bein ...
and
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exh ...
have irregular structures
*Triple bond mean-square deviation 3pm.


References

Data is as quoted at http://www.webelements.com/ from these sources:


Covalent radii (single bond)

* * * * *


Metallic radius

{{DEFAULTSORT:Atomic radii of the elements (data page) Properties of chemical elements Chemical element data pages Atomic radius