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Metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
s used for architectural purposes include
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
, for water pipes, roofing, and windows;
tin Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
, formed into
tinplate Tinplate consists of sheets of steel coated with a thin layer of tin to impede rusting. Before the advent of cheap milled steel, the backing metal was wrought iron. While once more widely used, the primary use of tinplate now is the manufacture ...
;
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
,
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
and
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
, in a range of applications including roofing and decoration; and
iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
, which has structural and other uses in the form of
cast iron Cast iron is a class of iron– carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured: white cast iron has carbide impur ...
or
wrought iron Wrought iron is an iron alloy with a very low carbon content (less than 0.08%) in contrast to that of cast iron (2.1% to 4%). It is a semi-fused mass of iron with fibrous slag inclusions (up to 2% by weight), which give it a wood-like "grain" ...
, or made into steel. Metal
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductilit ...
s used in building include bronze (mainly copper and tin);
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
(copper and zinc);
monel metal Monel is a group of alloys of nickel (from 52 to 67%) and copper, with small amounts of iron, manganese, carbon, and silicon. Monel is not a cupronickel alloy because it has less than 60% copper. Stronger than pure nickel, Monel alloys are res ...
and
nickel silver Nickel silver, Maillechort, German silver, Argentan, new silver, nickel brass, albata, alpacca, is a copper alloy with nickel and often zinc. The usual formulation is 60% copper, 20% nickel and 20% zinc. Nickel silver does not contain the eleme ...
, mainly consisting of nickel and copper; and stainless steel, with important components of nickel and chromium.


Metal types


Lead

The low
melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depen ...
of lead permitted its use on a wide scale throughout human history. Lead was one of the first to be made into sheet metal for architectural purposes. Water pipes were frequently constructed of lead, until its health hazards were publicised in the late 19th century. Lead is not subject to rust and has been a popular
roofing material Domestic roof construction is the framing and roof covering which is found on most detached houses in cold and temperate climates. Such roofs are built with mostly timber, take a number of different shapes, and are covered with a variety of ma ...
for centuries, being used for roofing, flashing, gutters, downspouts, and conductor heads. Lead was best suited for low-pitched roofs, as steep roofs experienced creep. Lead roofs in regions with large temperature fluctuations, such as the mid-Atlantic states, experienced deterioration from constant expansion and contraction, called fatigue. Beginning in the 19th century, a roofing material called “ terne” or “terneplate” was used, consisting of sheet iron or sheet steel coated with a lead-tin
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductilit ...
. It is frequently confused with
tinplate Tinplate consists of sheets of steel coated with a thin layer of tin to impede rusting. Before the advent of cheap milled steel, the backing metal was wrought iron. While once more widely used, the primary use of tinplate now is the manufacture ...
. Lead
came A came is a divider bar used between small pieces of glass to make a larger glazing panel. There are two kinds of came: the H-shaped sections that hold two pieces together and the U-shaped sections that are used for the borders. Cames are mostl ...
was also frequently used for window panes in skylights and stained glass. It was also used for small pieces of sculpture and garden ornamentation. Lead was frequently added to paint, with red lead used as an anti-corrosive pigment for iron, and white lead used as paint for wooden houses.
Lead-based paint Lead paint or lead-based paint is paint containing lead. As pigment, lead(II) chromate (, "chrome yellow"), lead(II,IV) oxide, (, "red lead"), and lead(II) carbonate (, "white lead") are the most common forms.. Lead is added to paint to acceler ...
was one of the most durable materials developed as a protective exterior coating. The use of lead paint has been restricted on most buildings, due to concerns of lead poisoning.


Tin

Tin Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
is too soft to be used by itself for architectural purposes so it generally falls into two categories: the alloying of tin with other metals such as
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
to form bronze, and the coating of tin on harder metals, such as tinplated iron or steel. Architectural bronzes usually contain about 90% copper and 10% tin, although the content may vary widely. The term “ tin ceiling” is a misnomer and early manufacturers did not use the name. However, persons who worked with sheet metal were called tinsmiths, so the term could have sprung from this title.
Tinplate Tinplate consists of sheets of steel coated with a thin layer of tin to impede rusting. Before the advent of cheap milled steel, the backing metal was wrought iron. While once more widely used, the primary use of tinplate now is the manufacture ...
was a type of architectural material consisting of sheet iron or steel coated with tin. “Tin roofs,” a type of tinplate, was originally used for armor but eventually as a roofing material. Tinplate was also used for decoration, such as ornamental windows, door lintels and stamped ceilings. Ornamental stamped metal made from tinplate was an affordable alternative to plasterwork. Although tinplate is still available today for ceilings, roofing and flashing, it is generally considered expensive since the initial cost is more than that for common modern roofing types such as
asphalt Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term ...
shingles or built-up roofs. A well-maintained tinplate roof or ceiling typically lasts several times longer than modern materials, and is more economical when the longer lifespan is taken into account.


Zinc

Pure
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
was used for roofing in Belgium, France and Germany, where it replaced more expensive copper and lead in roofing. Starting in the 1820s, Belgian sheet zinc was imported in America, used by builders in New York City and elsewhere. Pure zinc is subject to creep at ordinary temperatures. Zinc-coated metals were first
patented A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an enabling disclosure of the invention."A p ...
in 1837, separately by M. Sorel in France and H. W. Crawford in England. The methods employed a “hot dipping” process to coat sheet iron with zinc. By 1839 “galvanized” sheet iron roofing was being used in New York City. The Merchant's Exchange in Manhattan was one of the first buildings to have both a galvanized roof and galvanized gutters. Some galvanized sheet roofing was pressed with designs, a popular technique in the Victorian era. Zinc was also cast for sculptures and decorative elements in Germany and Austria as early as 1832. Decorative architectural elements were frequently cast in zinc, since it molded readily, was inexpensive compared to stone, and could be painted to imitate more expensive metals. Stamped swags, rosettes,
fleur-de-lis The fleur-de-lis, also spelled fleur-de-lys (plural ''fleurs-de-lis'' or ''fleurs-de-lys''), is a lily (in French, and mean 'flower' and 'lily' respectively) that is used as a decorative design or symbol. The fleur-de-lis has been used in the ...
and acanthus leaves provided popular decorative ornamentation of both exteriors and interiors by the late 19th century.
Zinc oxide Zinc oxide is an inorganic compound with the formula . It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cement ...
paints were nontoxic and resistant to
pollution Pollution is the introduction of contaminants into the natural environment that cause adverse change. Pollution can take the form of any substance (solid, liquid, or gas) or energy (such as radioactivity, heat, sound, or light). Pollutants, the ...
. They became commercially successful and readily available in America in about 1850 and used widely starting around the 1870s. They had the added benefit of being good rust inhibitors on iron and steel. During the early decades of the 20th century, the use of pure zinc roofing and ornament decreased in use in the US. It is now gaining popularity in its pure form (99.95%)for building materials. Typically, architectural grade zinc is 99.995 percent pure zinc with trace amounts of titanium, to reduce coefficient of thermal expansion and improve tensile strength and hardness, and copper to improve workability. Exact alloy composition is subject to manufacturer and is a color determinant in zinc's final patina. Over time, zinc develops its distinctive patina, transforming from a shiny silver to a matte bluish-grey. Pre patinated finishes are available from certain manufacturers to expedite the natural patination process. Zinc is still used in alloys such as
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
and
nickel silver Nickel silver, Maillechort, German silver, Argentan, new silver, nickel brass, albata, alpacca, is a copper alloy with nickel and often zinc. The usual formulation is 60% copper, 20% nickel and 20% zinc. Nickel silver does not contain the eleme ...
, and in the electroplating of steel as well. Today, galvanized steel and pure zinc material, usually Double Locked Standing Seam panels, are used for roofing a variety of buildings. Creep has been reduced by the introduction of
titanium Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...
in most architectural zinc available in North America. Galvanized nails and sheet metal ducts are also common. Architectural grade zinc is 90 to 95% recycled. Replacement costs are negligible with a long lifetime of 80 to 100 years for zinc roofing and 200 to 300 years for wall systems. This long-life durability is a key component in durability. At the end of its service life, zinc building products can be recycled indefinitely without loss to chemical or physical properties. The use of architectural grade zinc can help building qualify for LEED certification due to its high recycled content and sustainability.


Copper and its alloys

Copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
is a very durable metal, withstanding
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
when forming a bluish-green patina that variably consists of copper
carbonates A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
,
sulfates The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many a ...
, sulfides, and
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride sa ...
s. Sheet copper used as roofing is lighter than wooden shingles and much lighter than slate, tile, or lead. Roofing copper can be folded readily into waterproof seams, or shaped over curved frameworks for
cupolas In architecture, a cupola () is a relatively small, most often dome-like, tall structure on top of a building. Often used to provide a lookout or to admit light and air, it usually crowns a larger roof or dome. The word derives, via Italian, fro ...
and domes. The initial cost of copper was traditionally high, but its length of service more than compensated for the price. Copper could also be shaped to the bends and angles around chimneys and at roof edges and dormers. All nails, screws, bolts, and cleats used with sheet copper must be made of copper or a copper alloy, otherwise galvanic action between the dissimilar metals would occur, causing deterioration. Copper was also used for decorative purposes, including architectural ornaments, siding, ceilings or sculptures. One famous example is the Statue of Liberty. Copper alloys used in architecture include bronze, an alloy of copper and tin, and
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
, an alloy of copper and zinc.


Nickel and its alloys

Although somewhat rare,
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow ...
has been used for plating architectural details. Nickel is most frequently used for building components in the form of alloys:
nickel silver Nickel silver, Maillechort, German silver, Argentan, new silver, nickel brass, albata, alpacca, is a copper alloy with nickel and often zinc. The usual formulation is 60% copper, 20% nickel and 20% zinc. Nickel silver does not contain the eleme ...
,
Monel metal Monel is a group of alloys of nickel (from 52 to 67%) and copper, with small amounts of iron, manganese, carbon, and silicon. Monel is not a cupronickel alloy because it has less than 60% copper. Stronger than pure nickel, Monel alloys are res ...
, and stainless steel. Nickel silver was originally called “German Silver,” until World War I. It has been called “white brass” but probably should be termed “nickel brass,” because it generally contains 75% copper, 20% nickel, and 5% zinc. Different percentages result in a range of colors, including silvery-white, yellow, slight blue, green or pink. Nickel silver hardware was popular in the US during the
Art Deco Art Deco, short for the French ''Arts Décoratifs'', and sometimes just called Deco, is a style of visual arts, architecture, and product design, that first appeared in France in the 1910s (just before World War I), and flourished in the Unite ...
and Depression Modern periods. Architects and designers preferred nickel silver because it could take and retain appropriate finishes, and it resisted corrosion. Monel metal is an alloy of approximately two-thirds nickel and one-third copper. It is similar to platinum in color. Monel pioneered many of the present uses of stainless steel. The first architectural use of Monel was for roofing the Pennsylvania Railroad Terminal in New York City in 1909. In 1936, the copper roof on the New York City Public Library at Fifth Avenue and 42nd Street was replaced with a Monel metal roof. Its advantages as a roofing material included its ability to be brazed, welded, or soldered in place to provide a watertight, continuous cover. Monel was popular during the Art Deco periods. During World War II large quantities of nickel and copper were diverted to the war effort, and the supply of Monel was greatly reduced. Following the war, stainless steel and aluminium replaced Monel because of lower production costs.


Iron and its alloys

Iron has become an important architectural building component. It has been used in four common forms: wrought iron, cast iron, sheet iron, and steel.
Wrought iron Wrought iron is an iron alloy with a very low carbon content (less than 0.08%) in contrast to that of cast iron (2.1% to 4%). It is a semi-fused mass of iron with fibrous slag inclusions (up to 2% by weight), which give it a wood-like "grain" ...
was used for minor structural and decorative elements starting in the 18th century. Until the mid-19th century, the use of wrought iron in buildings was generally limited to small items such as tie rods, straps, nails, and hardware, or to decorative ironwork in balconies, railings fences and gates. Around 1850 its structural use became more widespread as iron mills began to roll rails, bulb-tees, and eventually I-beams. It was also used for decorative purposes, such as ornamental balconies or hardware. Since wrought iron is handmade, no two pieces are identical.
Cast iron Cast iron is a class of iron– carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured: white cast iron has carbide impur ...
was a major 19th century building material of the
Industrial Revolution The Industrial Revolution was the transition to new manufacturing processes in Great Britain, continental Europe, and the United States, that occurred during the period from around 1760 to about 1820–1840. This transition included going f ...
. Although brittle, it is remarkably strong in compression. It was frequently used for structural purposes, such as columns, building fronts, domes and light courts. Decorative uses have included stairs, elevators, lintels, grilles, verandas, balconies, railings, fences, streetlights, and tombs. The Bradbury Building is an example of extensive decorative cast iron. Today, cast iron is used for plumbing fixtures and piping in new construction, and its structural and decorative use is used occasionally through historic preservation practices. Sheet iron can be subject to rapid corrosion, forming rust. Sheet iron was used throughout the 19th century, although it is not clear how widespread sheet iron roofs became. Pressed decorative sheet iron used for ceilings was frequently called a “ tin ceiling,” which was actually sheets of iron dipped in molten tin to prevent them from rusting. Steel was introduced to the construction industry at the end of the 19th century. The development of structural steel in the mid-19th century allowed construction of tall buildings. Builders and manufacturers turned to steel, which was stronger than cast iron in compression and wrought iron in tension. When the
Bessemer process The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is removal of impurities from the iron by oxidation ...
was developed in England in 1856, and the open-hearth process was invented, steel was produced in a quantity that allowed it to be economical. Bridges, railroad companies, and skyscrapers were among the first large-scale uses of structural steel. Although iron and steel are not combustible, they lose strength in a fire if they are not protected from the heat. Almost all structural steel must be “fireproofed” in some manner, utilizing a cladding of
terra-cotta Terracotta, terra cotta, or terra-cotta (; ; ), in its material sense as an earthenware substrate, is a clay-based unglazed or glazed ceramic where the fired body is porous. In applied art, craft, construction, and architecture, terracotta ...
, tile, plaster-poured concrete, sprayed concrete, or sprayed insulation. Ferro concrete, also called reinforced concrete, was developed in the late 19th century when steel wire was added to concrete. Decorative steels used in buildings include: * Stainless steel, a chromium-nickel steel, developed between 1903 and 1912. Its most important property is its resistance to corrosion. It contains about 18% chromium and 8-12% nickel. Stainless steel is expensive, so it was used primarily as a nonstructural metal or where there is a high potential for corrosion. One of the most extensive early uses of stainless steel was in the
Chrysler Building The Chrysler Building is an Art Deco skyscraper on the East Side of Manhattan in New York City, at the intersection of 42nd Street and Lexington Avenue in Midtown Manhattan. At , it is the tallest brick building in the world with a steel fra ...
. * Copper-bearing steels, containing from .15% to .25% copper, develop increased resistance to atmospheric corrosion, when compared to ordinary steel, by forming a protective oxide coating, having a uniform deep brown color and texture.
Eero Saarinen Eero Saarinen (, ; August 20, 1910 – September 1, 1961) was a Finnish-American architect and industrial designer noted for his wide-ranging array of designs for buildings and monuments. Saarinen is best known for designing the General Motors ...
experimented with the material in the Deere and Company building in 1964.


Aluminium

Much like copper,
Aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
is highly resistant to
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
. It also has the added benefit of being a third lighter than steel with comparable strength. Aluminium can also be easily and repeatedly recycled. It has been estimated that of the estimated 900 million tonnes of aluminium produced since 1880, three quarters is still in productive use, 35% of which is in building construction.
Aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
was unavailable at reasonable cost or in sufficient quantities for general architectural use until after the beginning of the 20th century. Architectural use of aluminum increased in the 1920s, mainly for decorative detailing. It was used for roofing, flashing, gutters, downspouts, wall panels, and spandrels. Art Deco designs frequently used aluminum for ornamental features. The first extensive use of aluminum in construction was the Empire State Building, where the entire tower portion is aluminum, as well as many decorative features, such as the entrances, elevator doors, ornamental trim, and some 6,000 window spandrels. Today, aluminum is used frequently in construction except major structural members.Gayle & Waite (1980), pp 84-88.


See also

*
Building materials Building material is material used for construction. Many naturally occurring substances, such as clay, rocks, sand, wood, and even twigs and leaves, have been used to construct buildings. Apart from naturally occurring materials, many man- ...


References

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Sources

* Gayle, Margot and Waite, John G. (1980), ''Metals in America's Historic Buildings: Uses and Preservation Treatments'', Washington: U.S. Dept. of the Interior, Heritage Conservation and Recreation. Architectural history Building materials Construction Metalworking Sculpture materials