An anticaking agent is an
additive
Additive may refer to:
Mathematics
* Additive function, a function in number theory
* Additive map, a function that preserves the addition operation
* Additive set-function see Sigma additivity
* Additive category, a preadditive category with fin ...
placed in
powdered or
granulated materials, such as table
salt
In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...
or confectioneries, to prevent the formation of lumps (
caking) and for easing packaging, transport, flowability, and consumption.
Caking mechanisms depend on the nature of the material. Crystalline solids often cake by formation of liquid bridge and subsequent fusion of microcrystals. Amorphous materials can cake by glass transitions and changes in viscosity.
Polymorphic phase transitions can also induce caking.
Some anticaking agents function by
absorbing excess moisture or by coating particles and making them water-repellent.
Calcium silicate
Calcium silicate can refer to several silicates of calcium including:
*CaO·SiO2, wollastonite (CaSiO3)
*2CaO·SiO2, larnite (Ca2SiO4)
*3CaO·SiO2, alite or (Ca3SiO5)
*3CaO·2SiO2, (Ca3Si2O7).
This article focuses on Ca2SiO4, also known as calci ...
(CaSiO
3), a commonly used anti-caking agent, added to e.g. table salt, absorbs both water and
oil.
Anticaking agents are also used in non-food items such as
road salt
Road salt (also known as de-icing salt, rock salt, or snow salt) is a salt used mainly as an anti-slip agent in winter road conditions, but also to prevent dust and snow build-up on roads. Various kinds of salts are used as road salt, but calciu ...
,
fertiliser
A fertilizer or fertiliser is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrition, plant nutrients. Fertilizers may be distinct from Liming (soil), liming materials or other non- ...
s,
cosmetics
Cosmetics are substances that are intended for application to the body for cleansing, beautifying, promoting attractiveness, or altering appearance. They are mixtures of chemical compounds derived from either Natural product, natural source ...
, and
detergent
A detergent is a surfactant or a mixture of surfactants with Cleanliness, cleansing properties when in Concentration, dilute Solution (chemistry), solutions. There are a large variety of detergents. A common family is the alkylbenzene sulfonate ...
s.
Some studies suggest that anticaking agents may have a negative effect on the nutritional content of food; one such study indicated that most anti-caking agents result in the additional degradation of
vitamin C
Vitamin C (also known as ascorbic acid and ascorbate) is a water-soluble vitamin found in citrus and other fruits, berries and vegetables. It is also a generic prescription medication and in some countries is sold as a non-prescription di ...
added to food.
Examples
An anticaking agent in salt is denoted in the
ingredient
In a general sense, an ingredient is a substance which forms part of a mixture. In cooking, recipes specify which ingredients are used to prepare a dish, and the term may also refer to a specific food item in relation to its use in different re ...
s, for example, as "anti-caking agent (554)", which is
sodium aluminosilicate. This product is present in many commercial table salts as well as
dried milk,
egg
An egg is an organic vessel grown by an animal to carry a possibly fertilized egg cell (a zygote) and to incubate from it an embryo within the egg until the embryo has become an animal fetus that can survive on its own, at which point the ...
mixes,
sugar
Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose
Glucose is a sugar with the Chemical formula#Molecular formula, molecul ...
products,
flour
Flour is a powder made by Mill (grinding), grinding raw grains, List of root vegetables, roots, beans, Nut (fruit), nuts, or seeds. Flours are used to make many different foods. Cereal flour, particularly wheat flour, is the main ingredie ...
s and
spices
In the culinary arts, a spice is any seed, fruit, root, Bark (botany), bark, or other plant substance in a form primarily used for flavoring or coloring food. Spices are distinguished from herbs, which are the leaves, flowers, or stems of pl ...
. In Europe,
sodium ferrocyanide (535) and
potassium ferrocyanide
Potassium hexacyanidoferrate(II) is the inorganic compound with formula K4 e(CN)6�3H2O. It is the potassium salt of the coordination complex e(CN)6sup>4−. This salt forms lemon-yellow monoclinic crystals.
Synthesis
In 1752, the French chemi ...
(536) are more common anticaking agents in table salt. "Natural" anticaking agents used in more expensive table salt include
calcium carbonate
Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
and the
magnesium carbonate.
Diatomaceous earth
Diatomaceous earth ( ), also known as diatomite ( ), celite, or kieselguhr, is a naturally occurring, soft, siliceous rock, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging fr ...
, mostly consisting of
silicon dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundan ...
(SiO
2), may also be used as an anticaking agent in animal foods, typically mixed at 2% rate of a product dry weight
.
List of anticaking agents
The most widely used anticaking agents include the
stearates of calcium and magnesium, silica and various silicates, talc, as well as flour and starch. Ferrocyanides are used for table salt.
[
The following anticaking agents are listed in order by their ]number
A number is a mathematical object used to count, measure, and label. The most basic examples are the natural numbers 1, 2, 3, 4, and so forth. Numbers can be represented in language with number words. More universally, individual numbers can ...
in the Codex Alimentarius
The is a collection of internationally recognized standards, codes of practice, guidelines, and other recommendations published by the Food and Agriculture Organization (FAO) and World Health Organization (WHO) of the United Nations relating to f ...
by the Food and Agriculture Organization
The Food and Agriculture Organization of the United Nations; . (FAO) is a specialized agency of the United Nations that leads international efforts to defeat hunger and improve nutrition and food security. Its Latin motto, , translates ...
of the UN.
* 341 tricalcium phosphate
* 460(ii) powdered cellulose
Cellulose is an organic compound with the chemical formula, formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of glycosidic bond, β(1→4) linked glucose, D-glucose units. Cellulose is an important s ...
* 470b magnesium stearate
* 500 sodium bicarbonate
Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda (or simply “bicarb” especially in the UK) is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cat ...
* 535 sodium ferrocyanide
* 536 potassium ferrocyanide
Potassium hexacyanidoferrate(II) is the inorganic compound with formula K4 e(CN)6�3H2O. It is the potassium salt of the coordination complex e(CN)6sup>4−. This salt forms lemon-yellow monoclinic crystals.
Synthesis
In 1752, the French chemi ...
* 538 calcium ferrocyanide
* 542 calcium phosphate
* 550 sodium silicate
* 551 silicon dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundan ...
* 552 calcium silicate
Calcium silicate can refer to several silicates of calcium including:
*CaO·SiO2, wollastonite (CaSiO3)
*2CaO·SiO2, larnite (Ca2SiO4)
*3CaO·SiO2, alite or (Ca3SiO5)
*3CaO·2SiO2, (Ca3Si2O7).
This article focuses on Ca2SiO4, also known as calci ...
* 553a magnesium trisilicate
* 553b talcum powder
* 554 sodium aluminosilicate
* 555 potassium aluminium silicate
* 556 calcium aluminosilicate
* 558 bentonite
Bentonite ( ) is an Absorption (chemistry), absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelli ...
* 559 aluminium silicate
Aluminum silicate (or aluminium silicate) is a name commonly applied to chemical compounds which are derived from aluminium oxide, Al2O3 and silicon dioxide, SiO2 which may be anhydrous or hydrated, naturally occurring as minerals or synthetic. ...
* 570 stearic acid
Stearic acid ( , ) is a saturated fatty acid with an 18-carbon chain. The IUPAC name is octadecanoic acid. It is a soft waxy solid with the formula . The triglyceride derived from three molecules of stearic acid is called stearin. Stearic acid ...
* 900 polydimethylsiloxane
Polydimethylsiloxane (PDMS), also known as dimethylpolysiloxane or dimethicone, is a silicone polymer with a wide variety of uses, from cosmetics to industrial lubrication and passive daytime radiative cooling.
PDMS is particularly known for its ...
References
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Food additives