The Allam Cycle or Allam-Fetvedt Cycle is a process for converting carbonaceous fuels into thermal energy, while capturing the generated
carbon dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
and water.
The inventors are English engineer
Rodney John Allam, American engineer Jeremy Eron Fetvedt, American scientist Dr. Miles R Palmer, and American businessperson and innovator G. William Brown, Jr.
The Allam-Fetvedt Cycle was recognized by
MIT Technology Review
''MIT Technology Review'' is a bimonthly magazine wholly owned by the Massachusetts Institute of Technology. It was founded in 1899 as ''The Technology Review'', and was re-launched without "''The''" in its name on April 23, 1998, under then pu ...
on the 2018 list of 10 Breakthrough Technologies.
This cycle was validated at a 50 MWth natural gas fed
test facility in La Porte, Texas in May 2018.
Description
The Allam-Fetvedt Cycle is a recuperated, high-pressure,
Brayton cycle
The Brayton cycle, also known as the Joule cycle, is a thermodynamic cycle that describes the operation of certain heat engines that have air or some other gas as their working fluid.
It is characterized by isentropic process, isentropic compre ...
employing a
transcritical working fluid with an
oxy-fuel combustion regime. This cycle begins by burning a gaseous fuel with oxygen and a hot, high-pressure, recycled
supercritical working fluid in a combustor. The recycled stream serves the dual purpose of lowering the combustion flame temperature to a manageable level and diluting the combustion products such that the cycle working fluid is predominantly . The pressure in the combustor can be as high as approximately 30 MPa. The combustion feedstock consists of approximately 95% recycled by mass.
The combustor provides high-pressure exhaust that can be supplied to a turbine expander operating at a pressure ratio between 6 and 12. The expander discharge leaves as a subcritical mixture predominantly commingled with combustion derived water. This fluid enters an economizer heat exchanger, which cools the expander discharge to below 65 °C against the stream of that is recycled to the combustor. Upon exiting the economizer heat exchanger, the expander exhaust is further cooled to near ambient temperature by a central cooling system, enabling liquid water to be removed from the working fluid and recycled for beneficial use.
The remaining working fluid of nearly pure then enters a compression and pumping stage. The compression system consists of a conventional inter-cooled centrifugal compressor with an inlet pressure below the critical pressure. The working fluid is compressed and then cooled to near ambient temperature in the compressor after-cooler. At this point, the combination of compressing and cooling the working fluid permits it to achieve a density in excess of 500 kg/m3. In this condition, the stream can be pumped to the high combustion pressure required using a multi-stage centrifugal pump. Finally, the high-pressure working fluid is sent back through the economizer heat exchanger to be reheated and returned to the combustor.
The net product derived from the addition of fuel and oxygen in the combustor is removed from the high-pressure stream; at this point, the product is high-pressure and high purity, ready for sequestration or utilization without requiring further compression.
In order for the system to achieve high
thermal efficiency
In thermodynamics, the thermal efficiency (\eta_) is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, steam turbine, steam engine, boiler, furnace, refrigerator, ACs etc.
For ...
, a close temperature approach is needed on the high-temperature side of the primary heat exchanger. Due to the cooling process employed at the compression and pumping stage, a large energy imbalance would typically exist in the cycle between the cooling expander exhaust flow and the reheating recycle flow.
The Allam-Fetvedt Cycle corrects this imbalance through the incorporation of low-grade heat at the low-temperature end of the recuperative heat exchanger. Due to the low temperatures at the cool end of the cycle, this low-grade heat only needs to be in the range of 100 °C to 400 °C. A convenient source of this heat is the Air Separation Unit (ASU) required for the oxy-fuel combustion regime.
When burning natural gas as a fuel, this basic configuration has been modeled to achieve an efficiency up to 60% (LHV) as a power cycle net of all parasitic loads, including the energy-intensive ASU. Despite its novelty, the components required by this cycle are commercially available, with the exception of the combustion turbine package. The turbine relies on proven technologies and approaches used by existing gas and steam turbine design tools.
Applications
Construction began in March 2016 in
La Porte, Texas on a 50 MWth industrial test facility to showcase the Allam-Fetvedt Cycle, finishing in 2017. In 2018, the Allam-Fetvedt Cycle and supporting technologies were validated, allowing OEMs to certify components for use with future production plants.
On November 15, 2021, at approximately 7:40 pm EST the
test facility successfully synchronized to the ERCOT grid proving that the Allam Fetvedt Cycle was capable of generating power at 60 Hz.
This
test facility is owned and operated by NET Power, which is owned by
Constellation Energy Corporation,
Occidental Petroleum (Oxy) Low Carbon Ventures,
Baker Hughes
Baker Hughes Company is an American global energy technology company co-headquartered in Houston, Texas and London, UK. As one of the world's largest oil field services, industrial and energy technology companies, it provides products and serv ...
and 8 Rivers Capital (the inventor of the technology).
NET Power was awarded the 2018 International Excellence in Energy Breakthrough Technological Project of the Year at the Abu Dhabi International Petroleum Exhibition and Conference (ADIPEC).
Patent history
See also
*
Oxy-fuel combustion process
References
{{Reflist, 30em
External links
Process diagram for natural gas
Energy conversion
Thermodynamic cycles
English inventions
Power station technology
Carbon capture and storage