Aerosil
   HOME

TheInfoList



OR:

Fumed silica ( CAS number 7631-86-9, also 112945-52-5), also known as pyrogenic silica because it is produced in a flame, consists of microscopic droplets of amorphous
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
fused into branched, chainlike, three-dimensional secondary particles which then agglomerate into tertiary particles. The resulting powder has an extremely low bulk density and high surface area. Its three-dimensional structure results in viscosity-increasing,
thixotropic Thixotropy is a time-dependent shear thinning property. Certain gels or fluids that are thick or viscous under static conditions will flow (become thinner, less viscous) over time when shaken, agitated, shear-stressed, or otherwise stressed ...
behavior when used as a thickener or reinforcing filler.


Properties

Fumed silica has a very strong thickening effect. Primary particle size is 5–50 nm. The particles are non-porous and have a surface area of 50–600 m2/g. The density is 160–190 kg/m3.


Production

Fumed silica is made from flame
pyrolysis Pyrolysis is a process involving the Bond cleavage, separation of covalent bonds in organic matter by thermal decomposition within an Chemically inert, inert environment without oxygen. Etymology The word ''pyrolysis'' is coined from the Gree ...
of
silicon tetrachloride Silicon tetrachloride or tetrachlorosilane is the inorganic compound with the formula SiCl4. It is a colorless volatile liquid that fumes in air. It is used to produce high purity silicon and silica for commercial applications. It is a part of the ...
or from
quartz sand Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical fo ...
vaporized in a 3000 °C electric arc. Major global producers are
Evonik , products = Chemicals , revenue = {{Decrease €15.2 billion (2024){{cite web , url= https://www.evonik.com/en/investor-relations/Reporting.html#tabs-b118b10b7a-item-2d4ab0c2ad-tab , title=Evonik Financial Report 2024 , publisher=Evonik Industri ...
(who sells it under the name Aerosil),
Cabot Corporation Cabot Corporation is an American specialty chemicals and performance materials company headquartered in Boston, Massachusetts. The company operates in over 20 countries with 36 manufacturing plants, eight research and development facilities and ...
(Cab-O-Sil),
Wacker Chemie Wacker Chemie AG is a German multinational chemical company which was founded in 1914 by Alexander Wacker. The company is controlled by the Wacker family holding more than 50 percent of the shares. The corporation operates more than 25 producti ...
(HDK),
Dow Corning Dow Corning Corporation, was an American multinational corporation headquartered in Midland, Michigan, United States, and was originally established as a joint venture between The Dow Chemical Company and Corning Inc., Corning Incorporated. In 20 ...
,
Heraeus Heraeus is a German technology group with a focus on precious and special metals, medical technology, quartz glass and sensors as well as electronic components. Founded in Hanau in 1851, the company is one of the largest family-owned companies ...
(Zandosil),
Tokuyama Corporation is a Japanese, Tokyo-based chemical company and the world's fourth largest silicon manufacturer. The company was founded as Nihon Soda Kogyo Co., Ltd., a producer of soda ash in 1918 by Katsujiro Iwai. It changed name in 1936 to Tokuyama Soda ...
(Reolosil), OCI (Konasil)
Orisil
(Orisil) an
Xunyuchem
XYSIL).


Applications

Fumed silica serves as a universal
thickening agent A thickening agent or thickener is a substance which can increase the viscosity of a liquid without substantially changing its other properties. Edible thickeners are commonly used to thicken sauces, soups, and puddings without altering their ...
and an
anticaking agent An anticaking agent is an additive placed in powdered or granulated materials, such as table salt or confectioneries, to prevent the formation of lumps ( caking) and for easing packaging, transport, flowability, and consumption. Caking mechanism ...
(free-flow agent) in powders. Like
silica gel Silica gel is an amorphous and porosity, porous form of silicon dioxide (silica), consisting of an irregular three-dimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain wate ...
, it serves as a
desiccant A desiccant is a hygroscopic substance that is used to induce or sustain a state of dryness (desiccation) in its vicinity; it is the opposite of a humectant. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccant ...
. It is used in
cosmetics Cosmetics are substances that are intended for application to the body for cleansing, beautifying, promoting attractiveness, or altering appearance. They are mixtures of chemical compounds derived from either Natural product, natural source ...
for its light-diffusing properties. It is used as a light
abrasive An abrasive is a material, often a mineral, that is used to shape or finish a workpiece through rubbing which leads to part of the workpiece being worn away by friction. While finishing a material often means polishing it to gain a smooth, reflec ...
, in products like
toothpaste Toothpaste is a paste or gel dentifrice that is used with a toothbrush to clean and maintain the aesthetics of Human tooth, teeth. Toothpaste is used to promote oral hygiene: it is an abrasive that aids in removing dental plaque and food from th ...
. Other uses include filler in silicone elastomer and viscosity adjustment in
paint Paint is a material or mixture that, when applied to a solid material and allowed to dry, adds a film-like layer. As art, this is used to create an image or images known as a painting. Paint can be made in many colors and types. Most paints are ...
s,
coating A coating is a covering that is applied to the surface of an object, or substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquids, gases or solids e.g. powder coatings. Paints ...
s, printing inks,
adhesive Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advantage ...
s and unsaturated polyester resins. Fumed silica readily forms a network structure within
bitumen Bitumen ( , ) is an immensely viscosity, viscous constituent of petroleum. Depending on its exact composition, it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American Engl ...
and enhances its elasticity.


Health issues

Fumed silica is not listed as a carcinogen by
OSHA The Occupational Safety and Health Administration (OSHA; ) is a regulatory agency of the United States Department of Labor that originally had federal visitorial powers to inspect and examine workplaces. The United States Congress established ...
,
IARC IARC may refer to: * International Aerial Robotics Competition * International Age Rating Coalition * International Agency for Research on Cancer * International Arctic Research Center * Israel Association of Radio Communication * iArc, South Ko ...
, or NTP. Due to its fineness and thinness, fumed silica can easily become airborne, making it an inhalation hazard capable of causing irritation.


See also

*
Hydrophobic silica In chemistry, hydrophobicity is the chemical property of a molecule (called a hydrophobe) that is seemingly intermolecular force, repelled from a mass of water. In contrast, hydrophiles are attracted to water. Hydrophobic molecules tend to b ...
* Precipitated silica *
Nanoparticles A nanoparticle or ultrafine particle is a particle of matter 1 to 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At ...


References

{{reflist Ceramic materials Glass types Edible thickening agents Silicon dioxide