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Zinc Refining
Zinc refining is the process of purifying zinc to ''special high grade'' (SHG) zinc, which is at least 99.995% pure. This process is not usually required when smelting of zinc is done through electrolysis processes, but is needed when zinc is produced by pyrometallurgical processes, because it is only 98.5% pure. There are various refining methods, but the refluxing process is the most commonly used. High purity zinc is required industrially to avoid zinc pest, a slow distortion and cracking of zinc die castings caused by impurities precipitating out. Refluxing process The New Jersey Zinc Company invented this process in 1930. The process take advantage of the relatively low boiling point of zinc () as compared to the impurities being removed in the first "column": iron and aluminium. Therefore, in the first column the zinc is heated above its boiling point and allowed to rise to a condenser. The iron and aluminium impurities sink to the bottom in the form of a solid or liquid. ...
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Zinc
Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It is the second most abundant trace metal in humans after iron, an import ...
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Electrolysis
In chemistry and manufacturing, electrolysis is a technique that uses Direct current, direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of chemical element, elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential. The word "lysis" means to separate or break, so in terms, electrolysis would mean "breakdown via electricity." Etymology The word "electrolysis" was introduced by Michael Faraday in 1834, using the Greek language, Greek words "amber", which since the 17th century was associated with electrical phenomena, and ' meaning "dissolution". Nevertheless, electrolysis, as a tool to study chemical reactions and obtain pure chemical element, elements, precedes the coinage of the term and formal description by Faraday. History In the early nineteenth century, ...
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Pyrometallurgical
Pyrometallurgy is a branch of extractive metallurgy. It consists of the thermal treatment of minerals and metallurgical ores and concentrates to bring about physical and chemical transformations in the materials to enable recovery of valuable metals. Pyrometallurgical treatment may produce products able to be sold such as pure metals, or intermediate compounds or alloys, suitable as feed for further processing. Examples of elements extracted by pyrometallurgical processes include the oxides of less reactive elements like iron, copper, zinc, chromium, tin, and manganese. Pyrometallurgical processes are generally grouped into one or more of the following categories: * calcining, * roasting, * smelting, * refining. Most pyrometallurgical processes require energy input to sustain the temperature at which the process takes place. The energy is usually provided in the form of combustion or from electrical heat. When sufficient material is present in the feed to sustain the proce ...
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Zinc Pest
Zinc pest (from German ''Zinkpest'' "zinc plague"), also known as zinc rot, mazak rot and zamak rot, is a destructive, intercrystalline corrosion process of zinc alloys containing lead impurities. Prepared under the direction of the ASM International Handbook Committee. While impurities of the alloy are the primary cause of the problem, environmental conditions such as high humidity (greater than 65%) may accelerate the process. It was first discovered to be a problem in 1923, and primarily affects die-cast zinc articles that were manufactured during the 1920s through 1950s. The New Jersey Zinc Company developed zamak alloys in 1929 using 99.99% pure zinc metal to avoid the problem, and articles made after 1960 are usually considered free of the risk of zinc pest since the use of purer materials and more controlled manufacturing conditions make zinc pest degradation unlikely. Affected objects may show surface irregularities such as small cracks and fractures, blisters or pit ...
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New Jersey Zinc Company
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Iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's outer and inner core. It is the fourth most abundant element in the Earth's crust, being mainly deposited by meteorites in its metallic state. Extracting usable metal from iron ores requires kilns or furnaces capable of reaching , about 500 °C (900 °F) higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BC and the use of iron tools and weapons began to displace copper alloys – in some regions, only around 1200 BC. That event is considered the transition from the Bronze Age to the Iron Age. In the modern world, iron alloys, such as steel, stainless steel, cast iron and special steels, are by far the most common industrial metals, due to their mechan ...
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Aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has a great affinity towards oxygen, passivation (chemistry), forming a protective layer of aluminium oxide, oxide on the surface when exposed to air. It visually resembles silver, both in its color and in its great ability to reflect light. It is soft, magnetism, nonmagnetic, and ductility, ductile. It has one stable isotope, 27Al, which is highly abundant, making aluminium the abundance of the chemical elements, 12th-most abundant element in the universe. The radioactive decay, radioactivity of aluminium-26, 26Al leads to it being used in radiometric dating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ ...
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Lead
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable nuclide, stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its Amphoterism, amphoteric nature; lead and lead oxides react with acids and base (chemistry), bases, and it tends to form covalent bonds. Lead compounds, Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited ...
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Cadmium
Cadmium is a chemical element; it has chemical symbol, symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Like zinc, it demonstrates oxidation state +2 in most of its compounds, and like mercury, it has a lower melting point than the transition metals in group 3 element, groups 3 through group 11 element, 11. Cadmium and its Congener (chemistry), congeners in group 12 are often not considered transition metals, in that they do not have partly filled ''d'' or ''f'' electron shells in the elemental or common oxidation states. The average concentration of cadmium in Earth's crust is between 0.1 and 0.5 parts per million (ppm). It was discovered in 1817 simultaneously by Friedrich Stromeyer, Stromeyer and Karl Samuel Leberecht Hermann, Hermann, both in Germany, as an impurity in zinc carbonate. Cadmium occurs as a minor component in most zinc ores and i ...
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Zinc Smelting
Zinc smelting is the process of converting zinc concentrates ( ores that contain zinc) into pure zinc. Zinc smelting has historically been more difficult than the smelting of other metals, e.g. iron, because in contrast, zinc has a low boiling point. At temperatures typically used for smelting metals, zinc is a gas that will escape from a furnace with the flue gas and be lost, unless specific measures are taken to prevent it. The most common zinc concentrate processed is zinc sulfide,. which is obtained by concentrating sphalerite via froth flotation. Secondary (recycled) zinc material, such as zinc oxide, is also processed with the zinc sulfide.. Approximately 30% of all zinc produced is from recycled sources. Methods There are two methods of smelting zinc: the pyrometallurgical process and the electrolysis process. Both methods are still used. Both of these processes share the same first step: roasting. Roasting Roasting is a process of oxidizing zinc sulfide concentrat ...
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ZAMAK
ZAMAK (or Zamac, formerly trademarked as MAZAK) is an eclectic family of alloys with a base metal of zinc and alloying elements of aluminium, magnesium, and copper. Zamak alloys are part of the zinc aluminium alloy family; they are distinguished from the other ZA alloys because of their constant 4% aluminium composition. The name ''zamak'' is an acronym of the German names for the metals of which the alloys are composed: (zinc), , and (copper). The New Jersey Zinc Company developed zamak alloys in 1929. The most common zamak alloy is zamak 3. Besides that, zamak 2, zamak 5 and zamak 7 are also commercially used. These alloys are most commonly die cast. Zamak alloys (particularly #3 and #5) are frequently used in the spin casting industry. A large problem with early zinc die casting materials was zinc pest, owing to impurities in the alloys. Zamak avoided this by the use of 99.99% pure zinc metal, produced by New Jersey Zinc's use of a refluxer as part of the refining p ...
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Metallurgical Processes
Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals, including the production of metals and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist. The science of metallurgy is further subdivided into two broad categories: chemical metallurgy and physical metallurgy. Chemical metallurgy is chiefly concerned with the reduction and oxidation of metals, and the chemical performance of metals. Subjects of study in chemical metallurgy include mineral processing, the extraction of ...
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