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Widom Scaling
Widom scaling (after Benjamin Widom) is a hypothesis in statistical mechanics regarding the free energy of a magnetic system near its critical point which leads to the critical exponents becoming no longer independent so that they can be parameterized in terms of two values. The hypothesis can be seen to arise as a natural consequence of the block-spin renormalization procedure, when the block size is chosen to be of the same size as the correlation length.Kerson Huang, Statistical Mechanics. John Wiley and Sons, 1987 Widom scaling is an example of universality. Definitions The critical exponents \alpha, \alpha', \beta, \gamma, \gamma' and \delta are defined in terms of the behaviour of the order parameters and response functions near the critical point as follows : M(t,0) \simeq (-t)^, for t \uparrow 0 : M(0,H) \simeq , H, ^ \mathrm(H), for H \rightarrow 0 : \chi_T(t,0) \simeq \begin (t)^, & \textrm \ t \downarrow 0 \\ (-t)^, & \textrm \ t \uparrow 0 \end : c_ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benjamin Widom
Benjamin Widom (born 13 October 1927) is the Goldwin Smith Professor of Chemistry at Cornell University. His research interests include physical chemistry and statistical mechanics. In 1998, Widom was awarded the Boltzmann Medal "for his illuminating studies of the statistical mechanics of fluids and fluid mixtures and their interfacial properties, especially his clear and general formulation of scaling hypotheses for the equation of state and surface tensions of fluids near critical points." Academic background Widom was born in Newark, New Jersey. He graduated from New York City's Stuyvesant High School in 1945, and received his BA from Columbia University in 1949, followed by his PhD from Cornell in 1953. He became an instructor of chemistry at Cornell in 1954, was appointed assistant professor in 1955 and a full professor in 1963. He was chair of the chemistry department between 1978 and 1981. He was elected a member of the National Academy of Sciences in 1974 and a fel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: * Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability di ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Free Energy
The thermodynamic free energy is a concept useful in the thermodynamics of chemical or thermal processes in engineering and science. The change in the free energy is the maximum amount of work that a thermodynamic system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point. Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is a thermodynamic state function, like the internal energy, enthalpy, and entropy. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, ''i.e.'', work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. Since first-law energy is always conserved, it is evident that free energ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetic System
Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particles give rise to a magnetic field, which acts on other currents and magnetic moments. Magnetism is one aspect of the combined phenomena of electromagnetism. The most familiar effects occur in ferromagnetic materials, which are strongly attracted by magnetic fields and can be magnetized to become permanent magnets, producing magnetic fields themselves. Demagnetizing a magnet is also possible. Only a few substances are ferromagnetic; the most common ones are iron, cobalt, and nickel and their alloys. The rare-earth metals neodymium and samarium are less common examples. The prefix ' refers to iron because permanent magnetism was first observed in lodestone, a form of natural iron ore called magnetite, Fe3O4. All substances exhibit some type of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Critical Point (thermodynamics)
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. The most prominent example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas cannot be liquefied by pressure alone. At the critical point, defined by a ''critical temperature'' ''T''c and a ''critical pressure'' ''p''c, phase boundaries vanish. Other examples include the liquid–liquid critical points in mixtures, and the ferromagnet–paramagnet transition ( Curie temperature) in the absence of an external magnetic field. Liquid–vapor critical point Overview For simplicity and clarity, the generic notion of ''critical point'' is best introduced by discussing a specific example, the vapor–liquid critical point. This was the first critical point to be discovered, and it is still the best known and most studied one. The fi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Critical Exponent
Critical or Critically may refer to: *Critical, or critical but stable, medical states **Critical, or intensive care medicine * Critical juncture, a discontinuous change studied in the social sciences. * Critical Software, a company specializing in mission and business critical information systems * Critical theory, a school of thought that critiques society and culture by applying knowledge from the social sciences and the humanities * Critically endangered, a risk status for wild species *Criticality (status), the condition of sustaining a nuclear chain reaction Art, entertainment, and media * ''Critical'' (novel), a medical thriller written by Robin Cook * ''Critical'' (TV series), a Sky 1 TV series * "Critical" (''Person of Interest''), an episode of the American television drama series ''Person of Interest'' *"Critical", a 1999 single by Zion I People *Cr1TiKaL (born 1994), an American YouTuber and Twitch streamer See also *Critic *Criticality (other) *Critical Con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Universality (dynamical Systems)
In statistical mechanics, universality is the observation that there are properties for a large class of systems that are independent of the dynamical details of the system. Systems display universality in a scaling limit, when a large number of interacting parts come together. The modern meaning of the term was introduced by Leo Kadanoff in the 1960s, but a simpler version of the concept was already implicit in the van der Waals equation and in the earlier Landau theory of phase transitions, which did not incorporate scaling correctly. The term is slowly gaining a broader usage in several fields of mathematics, including combinatorics and probability theory, whenever the quantitative features of a structure (such as asymptotic behaviour) can be deduced from a few global parameters appearing in the definition, without requiring knowledge of the details of the system. The renormalization group provides an intuitively appealing, albeit mathematically non-rigorous, explanation of u ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Approach To Scaling
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Approach may refer to: Aviation *Visual approach *Instrument approach * Final approach Music * ''Approach'' (album), by Von Hertzen Brothers * ''The Approach'', an album by I:Scintilla Other uses *Approach Beach, a gazetted beach in Ting Kau, Hong Kong *Approach shot (other) *Lotus Approach, a database * Bridge approach * Approaches to scientific method *Bowling action in the sport of cricket *Flirting See also *Capability approach, in economic theory *Final approach (other) In aeronautics, the final approach (also called the final leg and final approach leg) is the last leg in an aircraft's approach to landing, when the aircraft is lined up with the runway and descending for landing.Crane, Dale: ''Dictionary of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Homogeneous Function
In mathematics, a homogeneous function is a function of several variables such that, if all its arguments are multiplied by a scalar, then its value is multiplied by some power of this scalar, called the degree of homogeneity, or simply the ''degree''; that is, if is an integer, a function of variables is homogeneous of degree if :f(sx_1,\ldots, sx_n)=s^k f(x_1,\ldots, x_n) for every x_1, \ldots, x_n, and s\ne 0. For example, a homogeneous polynomial of degree defines a homogeneous function of degree . The above definition extends to functions whose domain and codomain are vector spaces over a field : a function f : V \to W between two -vector spaces is ''homogeneous'' of degree k if for all nonzero s \in F and v \in V. This definition is often further generalized to functions whose domain is not , but a cone in , that is, a subset of such that \mathbf\in C implies s\mathbf\in C for every nonzero scalar . In the case of functions of several real variables and rea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Partial Derivative
In mathematics, a partial derivative of a function of several variables is its derivative with respect to one of those variables, with the others held constant (as opposed to the total derivative, in which all variables are allowed to vary). Partial derivatives are used in vector calculus and differential geometry. The partial derivative of a function f(x, y, \dots) with respect to the variable x is variously denoted by It can be thought of as the rate of change of the function in the x-direction. Sometimes, for z=f(x, y, \ldots), the partial derivative of z with respect to x is denoted as \tfrac. Since a partial derivative generally has the same arguments as the original function, its functional dependence is sometimes explicitly signified by the notation, such as in: :f'_x(x, y, \ldots), \frac (x, y, \ldots). The symbol used to denote partial derivatives is ∂. One of the first known uses of this symbol in mathematics is by Marquis de Condorcet from 1770, who used it f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isothermal Susceptibility
In thermodynamics, an isothermal process is a type of thermodynamic process in which the temperature ''T'' of a system remains constant: Δ''T'' = 0. This typically occurs when a system is in contact with an outside thermal reservoir, and a change in the system occurs slowly enough to allow the system to be continuously adjusted to the temperature of the reservoir through heat exchange (see quasi-equilibrium). In contrast, an ''adiabatic process'' is where a system exchanges no heat with its surroundings (''Q'' = 0). Simply, we can say that in an isothermal process * T = \text * \Delta T = 0 * dT = 0 * For ideal gases only, internal energy \Delta U = 0 while in adiabatic processes: * Q = 0. Etymology The adjective "isothermal" is derived from the Greek words "ἴσος" ("isos") meaning "equal" and "θέρμη" ("therme") meaning "heat". Examples Isothermal processes can occur in any kind of system that has some means of regulating the temperature, including hi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Specific Heat
In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat that must be added to one unit of mass of the substance in order to cause an increase of one unit in temperature. The SI unit of specific heat capacity is joule per kelvin per kilogram, J⋅kg−1⋅K−1. For example, the heat required to raise the temperature of of water by is , so the specific heat capacity of water is . Specific heat capacity often varies with temperature, and is different for each state of matter. Liquid water has one of the highest specific heat capacities among common substances, about at 20 °C; but that of ice, just below 0 °C, is only . The specific heat capacities of iron, granite, and hydrogen gas are about 449 J⋅kg−1⋅K−1, 790 J⋅kg−1⋅K−1, and 14300 J⋅kg−1⋅K ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
