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Tellurium Tetrabromide
Tellurium tetrabromide ( Te Br4) is an inorganic chemical compound. It has a similar tetrameric structure to TeCl4.''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 It can be made by reacting bromine and tellurium. In the vapour TeBr4 dissociates: :TeBr4 → TeBr2 + Br2 It is a conductor when molten, dissociating into the ions TeBr3+ and Br−. When dissolved in benzene and toluene, TeBr4 is present as the unionized tetramer Te4Br16. In solvents with donor properties such as acetonitrile Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula and structure . This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed ..., CH3CN ionic complexes are formed which make the solution conducting: :TeBr4 + 2CH3CN → (CH3CN)2TeBr3+ + Br− References Bromides Tellurium halides Tellurium(IV) compounds Chalcohalides {{inorg ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tellurium Tetrafluoride
Tellurium tetrafluoride, TeF4, is a stable, white, hygroscopic crystalline solid and is one of two fluorides of tellurium. The other binary fluoride is tellurium hexafluoride.''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 The widely reported Te2F10 has been shown to be F5TeOTeF5 There are other tellurium compounds that contain fluorine, but only the two mentioned contain solely tellurium and fluorine. Tellurium difluoride, TeF2, and ditellurium difluoride, Te2F2 are not known. Preparation Tellurium tetrafluoride can be prepared by the following reaction: : TeO2 + 2 SF4 → TeF4 + 2 SOF2 It is also prepared by reacting nitryl fluoride with tellurium or from the elements at 0 °C or by reacting selenium tetrafluoride with tellurium dioxide at 80 °C. Fluorine in nitrogen can react with TeCl2 or TeBr2 to form TeF4. PbF2 will also fluorinate tellurium to TeF4. Reactivity Tellurium tetrafluoride will react with water or silica and form ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tellurium Tetrachloride
Tellurium tetrachloride is the inorganic compound with the empirical formula TeCl4. The compound is volatile, subliming at 200 °C at 0.1 mmHg. Molten TeCl4 is ionic, dissociating into TeCl3+ and Te2Cl102−. Structure TeCl4 is monomeric in the gas phase, with a structure similar to that of SF4. In the solid state, it is a tetrameric cubane-type cluster, consisting of a Te4Cl4 core and three terminal chloride ligands for each Te. Alternatively, this tetrameric structure can be considered as a Te4 tetrahedron with face-capping chlorines and three terminal chlorines per tellurium atom, giving each tellurium atom a distorted octahedral environment Synthesis TeCl4 is prepared by chlorination of tellurium powder: :Te + 2 Cl2 → TeCl4 The reaction is initiated with heat. The product is isolated by distillation. Applications TeCl4 is of occasional interest in organic synthesis. and It adds to alkenes to give Cl-C-C-TeCl3 derivatives, wherein the Te can be subsequently ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tellurium Tetraiodide
Tellurium tetraiodide ( Te I4) is an inorganic chemical compound. It has a tetrameric structure which is different from the tetrameric solid forms of TeCl4 and TeBr4. In TeI4 the Te atoms are octahedrally coordinated and edges of the octahedra are shared. TeI4 can be prepared from the elements or by reacting Te and iodomethane, CH3I. In the vapour TeI4 dissociates:''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 :TeI4 → TeI2 + I2 It is a conductor when molten, dissociating into the ions TeI3+ and I−. In solvents with donor properties such as acetonitrile Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula and structure . This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed ..., CH3CN ionic complexes are formed which make the solution conducting: :TeI4 + 2 CH3CN → (CH3CN)2TeI3+ + I− References Iodides Tellu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Selenium Tetrabromide
Selenium tetrabromide is an inorganic compound with a chemical formula SeBr4. Preparation Selenium tetrabromide could be produced by mixing elemental bromine and selenium: :\rm \ Se + 2Br_2 \rightarrow SeBr_4 Properties Selenium tetrabromide exists in two polymorphs, the trigonal, black α-SeBr4 and the monoclinic, orange-reddish β-SeBr4, both of which feature tetrameric cubane-like Se4Br16 units but differ in how they are arranged. It dissolves in carbon disulfide, chloroform and ethyl bromide, but decomposes in water, so that it produces selenous acid Selenous acid (or selenious acid) is the chemical compound with the formula . Structurally, it is more accurately described by . It is the principal oxoacid of selenium; the other being selenic acid. Formation and properties Selenous acid is an ... in wet air. The compound is only stable under a bromine-saturated atmosphere; gas phase measurements of the gas density indicate that the compound decomposes into selenium ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ditellurium Bromide
Ditellurium bromide is the inorganic compound with the formula Te2 Br. It is one of the few stable lower bromides of tellurium. Unlike sulfur and selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium ..., tellurium forms families of polymeric subhalides where the halide/chalcogen ratio is less than 2. Preparation and properties Te2Br is a gray solid. Its structure consists of a chain of Te atoms with Br occupying a doubly bridged site. It is prepared by heating tellurium with the appropriate stoichiometry of bromine near 215 °C. The corresponding chloride and iodide, Te2Cl and Te2I, are also known. Other tellurium bromides include the yellow liquid Te2Br2, the orange solid TeBr4,Zhengtao Xu "Recent Developments in Binary Halogen–Chalcogen Compounds, Polyanions and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tellurium
Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.Anderson, Don L.; "Chemical Composition of the Mantle" in ''Theory of the Earth'', pp. 147-175 Tellurium-bearing compounds were first discovered in 1782 in a gold mine in Kleinschlatten, Transylvania (now Zlatna, Romania) by Austrian mineralogist Franz-Joseph Müller von Reichenstein, although it was Martin Heinrich Klaproth who named the new element in 1798 after the Latin 'earth'. Gold telluride mine ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromine
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table ( halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek (bromos) meaning "stench", referring to its sharp and pungent smell. Elemental bromine is very reactive and thus does not occur as a native element in nature but it occurs in colourless soluble crystalline mineral halide salts, analogous to table salt. In fact, bromine and all the halogens are so reactive that they form bonds in pairs—never in single atoms. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its accumulation in the oceans. Comme ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of moder ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, using ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tellurium Tetrachloride
Tellurium tetrachloride is the inorganic compound with the empirical formula TeCl4. The compound is volatile, subliming at 200 °C at 0.1 mmHg. Molten TeCl4 is ionic, dissociating into TeCl3+ and Te2Cl102−. Structure TeCl4 is monomeric in the gas phase, with a structure similar to that of SF4. In the solid state, it is a tetrameric cubane-type cluster, consisting of a Te4Cl4 core and three terminal chloride ligands for each Te. Alternatively, this tetrameric structure can be considered as a Te4 tetrahedron with face-capping chlorines and three terminal chlorines per tellurium atom, giving each tellurium atom a distorted octahedral environment Synthesis TeCl4 is prepared by chlorination of tellurium powder: :Te + 2 Cl2 → TeCl4 The reaction is initiated with heat. The product is isolated by distillation. Applications TeCl4 is of occasional interest in organic synthesis. and It adds to alkenes to give Cl-C-C-TeCl3 derivatives, wherein the Te can be subsequently ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzene
Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, benzene is classed as a hydrocarbon. Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Due to the cyclic continuous pi bonds between the carbon atoms, benzene is classed as an aromatic hydrocarbon. Benzene is a colorless and highly flammable liquid with a sweet smell, and is partially responsible for the aroma of gasoline. It is used primarily as a precursor to the manufacture of chemicals with more complex structure, such as ethylbenzene and cumene, of which billions of kilograms are produced annually. Although benzene is a major industrial chemical, it finds limited use in consumer items because of its toxicity. History Discovery The word "''benzene''" derives from "''gum benzoin''" (benz ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Toluene
Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) attached to a phenyl group. As such, its systematic IUPAC name is methylbenzene. Toluene is predominantly used as an industrial feedstock and a solvent. As the solvent in some types of paint thinner, permanent markers, contact cement and certain types of glue, toluene is sometimes used as a recreational inhalant and has the potential of causing severe neurological harm. History The compound was first isolated in 1837 through a distillation of pine oil by the Polish chemist Filip Walter, who named it ''rétinnaphte''. In 1841, French chemist Henri Étienne Sainte-Claire Deville isolated a hydrocarbon from balsam of Tolu (an aromatic extract from the tropical Colombian tree ''Myroxylon balsamum''), which Deville recognized as simila ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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