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Surface Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of th ...
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Area
Area is the quantity that expresses the extent of a region on the plane or on a curved surface. The area of a plane region or ''plane area'' refers to the area of a shape or planar lamina, while '' surface area'' refers to the area of an open surface or the boundary of a three-dimensional object. Area can be understood as the amount of material with a given thickness that would be necessary to fashion a model of the shape, or the amount of paint necessary to cover the surface with a single coat. It is the two-dimensional analogue of the length of a curve (a one-dimensional concept) or the volume of a solid (a three-dimensional concept). The area of a shape can be measured by comparing the shape to squares of a fixed size. In the International System of Units (SI), the standard unit of area is the square metre (written as m2), which is the area of a square whose sides are one metre long. A shape with an area of three square metres would have the same area as three suc ...
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Gamma
Gamma (uppercase , lowercase ; ''gámma'') is the third letter of the Greek alphabet. In the system of Greek numerals it has a value of 3. In Ancient Greek, the letter gamma represented a voiced velar stop . In Modern Greek, this letter represents either a voiced velar fricative or a voiced palatal fricative (while /g/ in foreign words is instead commonly transcribed as γκ). In the International Phonetic Alphabet and other modern Latin-alphabet based phonetic notations, it represents the voiced velar fricative. History The Greek letter Gamma Γ is a grapheme derived from the Phoenician letter (''gīml'') which was rotated from the right-to-left script of Canaanite to accommodate the Greek language's writing system of left-to-right. The Canaanite grapheme represented the /g/ phoneme in the Canaanite language, and as such is cognate with ''gimel'' ג of the Hebrew alphabet. Based on its name, the letter has been interpreted as an abstract representation of a c ...
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Euler–Lagrange Equation
In the calculus of variations and classical mechanics, the Euler–Lagrange equations are a system of second-order ordinary differential equations whose solutions are stationary points of the given action functional. The equations were discovered in the 1750s by Swiss mathematician Leonhard Euler and Italian mathematician Joseph-Louis Lagrange. Because a differentiable functional is stationary at its local extrema, the Euler–Lagrange equation is useful for solving optimization problems in which, given some functional, one seeks the function minimizing or maximizing it. This is analogous to Fermat's theorem in calculus, stating that at any point where a differentiable function attains a local extremum its derivative is zero. In Lagrangian mechanics, according to Hamilton's principle of stationary action, the evolution of a physical system is described by the solutions to the Euler equation for the action of the system. In this context Euler equations are usually called Lagrang ...
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Water Droplet Lying On A Damask
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. Water cover ...
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Young–Laplace Equation
In physics, the Young–Laplace equation () is an algebraic equation that describes the capillary pressure difference sustained across the interface between two static fluids, such as water and air, due to the phenomenon of surface tension or wall tension, although use of the latter is only applicable if assuming that the wall is very thin. The Young–Laplace equation relates the pressure difference to the shape of the surface or wall and it is fundamentally important in the study of static capillary surfaces. It's a statement of normal stress balance for static fluids meeting at an interface, where the interface is treated as a surface (zero thickness): \begin \Delta p &= -\gamma \nabla \cdot \hat n \\ &= -2\gamma H_f \\ &= -\gamma \left(\frac + \frac\right) \end where \Delta p is the Laplace pressure, the pressure difference across the fluid interface (the exterior pressure minus the interior pressure), \gamma is the surface tension (or wall tension), \hat n is the unit no ...
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Meniscus (liquid)
The meniscus (plural: ''menisci'', from the Greek for "crescent") is the curve in the upper surface of a liquid close to the surface of the container or another object, produced by surface tension. A concave meniscus occurs when the attraction between the particles of the liquid and the container ( adhesion) is more than half the attraction of the particles of the liquid to each other ( cohesion), causing the liquid to climb the walls of the container (see surface tension#Causes). This occurs between water and glass. Water-based fluids like sap, honey, and milk also have a concave meniscus in glass or other wettable containers. Conversely, a convex meniscus occurs when the adhesion energy is less than half the cohesion energy. Convex menisci occur, for example, between mercury and glass in barometers and thermometers. In general, the shape of the surface of a liquid can be complex. For a sufficiently small circular tube, the shape of the meniscus will approximate a sect ...
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Contact Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of ...
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Wetting
Wetting is the ability of a liquid to maintain contact with a solid surface, resulting from intermolecular interactions when the two are brought together. This happens in presence of a gaseous phase or another liquid phase not miscible with the first one. The degree of wetting (wettability) is determined by a force balance between adhesive and cohesive forces. Wetting is important in the bonding or adherence of two materials. Wetting and the surface forces that control wetting are also responsible for other related effects, including capillary effects. There are two types of wetting: non-reactive wetting and reactive wetting. Wetting deals with three phases of matter: gas, liquid, and solid. It is now a center of attention in nanotechnology and nanoscience studies due to the advent of many nanomaterials in the past two decades (e.g. graphene, Carbon nano tube, carbon nanotube, boron nitride nanomesh). Explanation Adhesive forces between a liquid and solid cause a liqu ...
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Internal Pressure
Internal pressure is a measure of how the internal energy of a system changes when it expands or contracts at constant temperature. It has the same dimensions as pressure, the SI unit of which is the pascal. Internal pressure is usually given the symbol \pi_T. It is defined as a partial derivative of internal energy with respect to volume at constant temperature: \pi _T = \left ( \frac \right )_T Thermodynamic equation of state Internal pressure can be expressed in terms of temperature, pressure and their mutual dependence: \pi_T = T \left ( \frac \right )_V - p This equation is one of the simplest thermodynamic equations. More precisely, it is a thermodynamic property relation, since it holds true for any system and connects the equation of state to one or more thermodynamic energy properties. Here we refer to it as a "thermodynamic equation of state." : Perfect gas In a perfect gas, there are no potential energy interactions between the particles, so any change in the i ...
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Surface Stress
Surface stress was first defined by Josiah Willard Gibbs (1839-1903) as the amount of the reversible work per unit area needed to elastically stretch a pre-existing surface. A suggestion is surface stress define as association with the amount of the reversible work per unit area needed to elastically stretch a pre-existing surface instead of up definition. A similar term called "surface free energy", which represents the excess free energy per unit area needed to create a new surface, is easily confused with "surface stress". Although surface stress and surface free energy of liquid–gas or liquid–liquid interface are the same, they are very different in solid–gas or solid–solid interface, which will be discussed in details later. Since both terms represent a force per unit length, they have been referred to as "surface tension", which contributes further to the confusion in the literature. Thermodynamics of surface stress Definition of surface free energy is seemly th ...
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