Superparamagnetism
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Superparamagnetism
Superparamagnetism is a form of magnetism which appears in small ferromagnetic or ferrimagnetic nanoparticles. In sufficiently small nanoparticles, magnetization can randomly flip direction under the influence of temperature. The typical time between two flips is called the Néel relaxation time. In the absence of an external magnetic field, when the time used to measure the magnetization of the nanoparticles is much longer than the Néel relaxation time, their magnetization appears to be in average zero; they are said to be in the superparamagnetic state. In this state, an external magnetic field is able to magnetize the nanoparticles, similarly to a paramagnet. However, their magnetic susceptibility is much larger than that of paramagnets. The Néel relaxation in the absence of magnetic field Normally, any ferromagnetic or ferrimagnetic material undergoes a transition to a paramagnetic state above its Curie temperature. Superparamagnetism is different from this standard t ...
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Néel Relaxation Theory
Néel relaxation theory is a theory developed by Louis Néel in 1949 to explain time-dependent magnetic phenomena known as ''magnetic viscosity''. It is also called ''Néel-Arrhenius theory'', after the Arrhenius equation, and ''Néel-Brown theory'' after a more rigorous derivation by William Fuller Brown, Jr. Néel used his theory to develop a model of thermoremanent magnetization in single-domain (magnetic), single-domain magnetic mineralogy, ferromagnetic minerals that explained how these minerals could reliably record the geomagnetic field. He also modeled frequency-dependent Magnetic susceptibility, susceptibility and alternating field demagnetization. Superparamagnetism Superparamagnetism occurs in ferromagnetic and ferrimagnetic nanoparticles which are single domain (magnetic), single-domain, i.e. composed of a single magnetic domain. This is possible when their diameter is below 3–50 nm, depending on the materials. In this condition, it is considered that the magnetiz ...
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Ferromagnetic
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials are the familiar metals noticeably attracted to a magnet, a consequence of their large magnetic permeability. Magnetic permeability describes the induced magnetization of a material due to the presence of an ''external'' magnetic field, and it is this temporarily induced magnetization inside a steel plate, for instance, which accounts for its attraction to the permanent magnet. Whether or not that steel plate acquires a permanent magnetization itself, depends not only on the strength of the applied field, but on the so-called coercivity of that material, which varies greatly among ferromagnetic materials. In physics, several different types of material magnetism are distinguished. Ferromagnetism (along with the similar effect ferrimagneti ...
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Single Domain (magnetic)
Single domain, in magnetism, refers to the state of a ferromagnet in which the magnetization does not vary across the magnet. A magnetic particle that stays in a single domain state for all magnetic fields is called a single domain particle (but other definitions are possible; see below). Such particles are very small (generally below a micrometre in diameter). They are also very important in a lot of applications because they have a high coercivity. They are the main source of hardness in hard magnets, the carriers of magnetic storage in tape drives, and the best recorders of the ancient Earth's magnetic field (see paleomagnetism). History Early theories of magnetization in ferromagnets assumed that ferromagnets are divided into magnetic domains and that the magnetization changed by the movement of domain walls. However, as early as 1930, Frenkel and Dorfman predicted that sufficiently small particles could only hold one domain, although they greatly overestimated the upper ...
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Hard Disk Drive
A hard disk drive (HDD), hard disk, hard drive, or fixed disk is an electro-mechanical data storage device that stores and retrieves digital data using magnetic storage with one or more rigid rapidly rotating platters coated with magnetic material. The platters are paired with magnetic heads, usually arranged on a moving actuator arm, which read and write data to the platter surfaces. Data is accessed in a random-access manner, meaning that individual blocks of data can be stored and retrieved in any order. HDDs are a type of non-volatile storage, retaining stored data when powered off. Modern HDDs are typically in the form of a small rectangular box. Introduced by IBM in 1956, HDDs were the dominant secondary storage device for general-purpose computers beginning in the early 1960s. HDDs maintained this position into the modern era of servers and personal computers, though personal computing devices produced in large volume, like cell phones and tablets, rely ...
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Bit-patterned Recording
Patterned media (also known as bit-patterned media or BPM) is a potential future hard disk drive technology to record data in magnetic islands (one bit per island), as opposed to current hard disk drive technology where each bit is stored in within a continuous magnetic film. The islands would be patterned from a precursor magnetic film using nanolithography. It is one of the proposed technologies to succeed perpendicular recording due to the greater storage densities it would enable. BPM was introduced by Toshiba in 2010. Comparison with existing HDD technology In existing hard disk drives, data is stored in a thin magnetic film. This film is deposited so that it consists of isolated (weakly exchange coupled) grains of material of around diameter. One bit of data consists of around that are magnetized in the same direction (either "up" or "down", with respect to the plane of the disk). One method of increasing storage density has been to reduce the average grain volume. Howev ...
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Nanoparticles
A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At the lowest range, metal particles smaller than 1 nm are usually called atom clusters instead. Nanoparticles are usually distinguished from microparticles (1-1000 µm), "fine particles" (sized between 100 and 2500 nm), and "coarse particles" (ranging from 2500 to 10,000 nm), because their smaller size drives very different physical or chemical properties, like colloidal properties and ultrafast optical effects or electric properties. Being more subject to the brownian motion, they usually do not sediment, like colloidal particles that conversely are usually understood to range from 1 to 1000 nm. Being much smaller than the wavelengths of visible light (400-700 nm), na ...
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Paramagnet
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, diamagnetic materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field. Paramagnetic materials include most chemical elements and some compounds; they have a relative magnetic permeability slightly greater than 1 (i.e., a small positive magnetic susceptibility) and hence are attracted to magnetic fields. The magnetic moment induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a SQUID magnetometer. Paramagnetism is due to the presence of unpaired electrons in the material, so most atom ...
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Curie Temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Curie temperature is named after Pierre Curie, who showed that magnetism was lost at a critical temperature. The force of magnetism is determined by the magnetic moment, a dipole moment within an atom which originates from the angular momentum and spin of electrons. Materials have different structures of intrinsic magnetic moments that depend on temperature; the Curie temperature is the critical point at which a material's intrinsic magnetic moments change direction. Permanent magnetism is caused by the alignment of magnetic moments and induced magnetism is created when disordered magnetic moments are forced to align in an applied magnetic field. For example, the ordered magnetic moments (ferromagnetic, Figure 1) change and become disordere ...
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Perpendicular Recording
Perpendicular recording (or perpendicular magnetic recording, PMR), also known as conventional magnetic recording (CMR), is a technology for data recording on magnetic media, particularly hard disks. It was first proven advantageous in 1976 by Shun-ichi Iwasaki, then professor of the Tohoku University in Japan, and first commercially implemented in 2005. The first industry-standard demonstration showing unprecedented advantage of PMR over longitudinal magnetic recording (LMR) at nanoscale dimensions was made in 1998 at IBM Almaden Research Center in collaboration with researchers oData Storage Systems Center(DSSC) – a National Science Foundation (NSF) Engineering Research Center (ERCs) at Carnegie Mellon University (CMU). Advantages Perpendicular recording can deliver more than three times the storage density of traditional longitudinal recording. In 1986, Maxell announced a floppy disk using perpendicular recording that could store . Perpendicular recording was later use ...
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Hitachi
() is a Japanese multinational conglomerate corporation headquartered in Chiyoda, Tokyo, Japan. It is the parent company of the Hitachi Group (''Hitachi Gurūpu'') and had formed part of the Nissan ''zaibatsu'' and later DKB Group and Fuyo Group of companies before DKB and Fuji Bank (the core Fuyo Group company) merged into the Mizuho Financial Group. As of 2020, Hitachi conducts business ranging from IT, including AI, the Internet of Things, and big data, to infrastructure. Hitachi is listed on the Tokyo Stock Exchange and Nagoya Stock Exchange and its Tokyo listing is a constituent of the Nikkei 225 and TOPIX Core30 indices. It is ranked 38th in the 2012 Fortune Global 500 and 129th in the 2012 Forbes Global 2000. History Hitachi was founded in 1910 by electrical engineer Namihei Odaira (1874–1951) in Ibaraki Prefecture. The company's first product was Japan's first induction motor, initially developed for use in copper mining. The company began as an in-house ven ...
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Heat-assisted Magnetic Recording
Heat-assisted magnetic recording (HAMR) (pronounced "''hammer")'' is a magnetic storage technology for greatly increasing the amount of data that can be stored on a magnetic device such as a hard disk drive by temporarily heating the disk material during writing, which makes it much more receptive to magnetic effects and allows writing to much smaller regions (and much higher levels of data on a disk). The technology was initially seen as extremely difficult to achieve, with doubts expressed about its feasibility in 2013. The regions being written must be heated in a tiny area - small enough that diffraction prevents the use of normal laser focused heating - and requires a heating, writing and cooling cycle of less than 1 nanosecond, while also controlling the effects of repeated spot-heating on the drive platters, the drive-to-head contact, and the adjacent magnetic data which must not be affected. These challenges required the development of nano-scale surface plasmons (surfac ...
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