Solid Harmonic
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Solid Harmonic
In physics and mathematics, the solid harmonics are solutions of the Laplace equation in spherical polar coordinates, assumed to be (smooth) functions \mathbb^3 \to \mathbb. There are two kinds: the ''regular solid harmonics'' R^m_\ell(\mathbf), which are well-defined at the origin and the ''irregular solid harmonics'' I^m_(\mathbf), which are singular at the origin. Both sets of functions play an important role in potential theory, and are obtained by rescaling spherical harmonics appropriately: R^m_(\mathbf) \equiv \sqrt\; r^\ell Y^m_(\theta,\varphi) I^m_(\mathbf) \equiv \sqrt \; \frac Derivation, relation to spherical harmonics Introducing , , and for the spherical polar coordinates of the 3-vector , and assuming that \Phi is a (smooth) function \mathbb^3 \to \mathbb, we can write the Laplace equation in the following form \nabla^2\Phi(\mathbf) = \left(\frac \fracr - \frac\right)\Phi(\mathbf) = 0 , \qquad \mathbf \ne \mathbf, where is the square of the nondimensional ...
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Physics
Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." Physics is one of the most fundamental scientific disciplines, with its main goal being to understand how the universe behaves. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physic ...
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Eigenvector
In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted by \lambda, is the factor by which the eigenvector is scaled. Geometrically, an eigenvector, corresponding to a real nonzero eigenvalue, points in a direction in which it is stretched by the transformation and the eigenvalue is the factor by which it is stretched. If the eigenvalue is negative, the direction is reversed. Loosely speaking, in a multidimensional vector space, the eigenvector is not rotated. Formal definition If is a linear transformation from a vector space over a field into itself and is a nonzero vector in , then is an eigenvector of if is a scalar multiple of . This can be written as T(\mathbf) = \lambda \mathbf, where is a scalar in , known as the eigenvalue, characteristic value, or characteristic root ...
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Atomic Physics
Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned with the way in which electrons are arranged around the nucleus and the processes by which these arrangements change. This comprises ions, neutral atoms and, unless otherwise stated, it can be assumed that the term ''atom'' includes ions. The term ''atomic physics'' can be associated with nuclear power and nuclear weapons, due to the synonymous use of ''atomic'' and ''nuclear'' in standard English. Physicists distinguish between atomic physics—which deals with the atom as a system consisting of a nucleus and electrons—and nuclear physics, which studies nuclear reactions and special properties of atomic nuclei. As with many scientific fields, strict delineation can be highly contrived and atomic physics is often considered in the wider ...
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Special Hypergeometric Functions
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Partial Differential Equations
In mathematics, a partial differential equation (PDE) is an equation which imposes relations between the various partial derivatives of a multivariable function. The function is often thought of as an "unknown" to be solved for, similarly to how is thought of as an unknown number to be solved for in an algebraic equation like . However, it is usually impossible to write down explicit formulas for solutions of partial differential equations. There is, correspondingly, a vast amount of modern mathematical and scientific research on methods to numerically approximate solutions of certain partial differential equations using computers. Partial differential equations also occupy a large sector of pure mathematical research, in which the usual questions are, broadly speaking, on the identification of general qualitative features of solutions of various partial differential equations, such as existence, uniqueness, regularity, and stability. Among the many open questions are the e ...
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Unitary Matrix
In linear algebra, a complex square matrix is unitary if its conjugate transpose is also its inverse, that is, if U^* U = UU^* = UU^ = I, where is the identity matrix. In physics, especially in quantum mechanics, the conjugate transpose is referred to as the Hermitian adjoint of a matrix and is denoted by a dagger (†), so the equation above is written U^\dagger U = UU^\dagger = I. The real analogue of a unitary matrix is an orthogonal matrix. Unitary matrices have significant importance in quantum mechanics because they preserve norms, and thus, probability amplitudes. Properties For any unitary matrix of finite size, the following hold: * Given two complex vectors and , multiplication by preserves their inner product; that is, . * is normal (U^* U = UU^*). * is diagonalizable; that is, is unitarily similar to a diagonal matrix, as a consequence of the spectral theorem. Thus, has a decomposition of the form U = VDV^*, where is unitary, and is diagonal and ...
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Spherical Harmonics
In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. Since the spherical harmonics form a complete set of orthogonal functions and thus an orthonormal basis, each function defined on the surface of a sphere can be written as a sum of these spherical harmonics. This is similar to periodic functions defined on a circle that can be expressed as a sum of circular functions (sines and cosines) via Fourier series. Like the sines and cosines in Fourier series, the spherical harmonics may be organized by (spatial) angular frequency, as seen in the rows of functions in the illustration on the right. Further, spherical harmonics are basis functions for irreducible representations of SO(3), the group of rotations in three dimensions, and thus play a central role in the group theoretic discussion of SO(3). Spherical harmonics or ...
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Legendre Polynomial
In physical science and mathematics, Legendre polynomials (named after Adrien-Marie Legendre, who discovered them in 1782) are a system of complete and orthogonal polynomials, with a vast number of mathematical properties, and numerous applications. They can be defined in many ways, and the various definitions highlight different aspects as well as suggest generalizations and connections to different mathematical structures and physical and numerical applications. Closely related to the Legendre polynomials are associated Legendre polynomials, Legendre functions, Legendre functions of the second kind, and associated Legendre functions. Definition by construction as an orthogonal system In this approach, the polynomials are defined as an orthogonal system with respect to the weight function w(x) = 1 over the interval 1,1/math>. That is, P_n(x) is a polynomial of degree n, such that \int_^1 P_m(x) P_n(x) \,dx = 0 \quad \text n \ne m. With the additional standardization condi ...
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Multipole Moments
A multipole expansion is a mathematical series representing a function that depends on angles—usually the two angles used in the spherical coordinate system (the polar and azimuthal angles) for three-dimensional Euclidean space, \R^3. Similarly to Taylor series, multipole expansions are useful because oftentimes only the first few terms are needed to provide a good approximation of the original function. The function being expanded may be real- or complex-valued and is defined either on \R^3, or less often on \R^n for some other Multipole expansions are used frequently in the study of electromagnetic and gravitational fields, where the fields at distant points are given in terms of sources in a small region. The multipole expansion with angles is often combined with an expansion in radius. Such a combination gives an expansion describing a function throughout three-dimensional space. The multipole expansion is expressed as a sum of terms with progressively finer angular featu ...
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Atomic Orbital
In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus. The term ''atomic orbital'' may also refer to the physical region or space where the electron can be calculated to be present, as predicted by the particular mathematical form of the orbital. Each orbital in an atom is characterized by a set of values of the three quantum numbers , , and , which respectively correspond to the electron's energy, angular momentum, and an angular momentum vector component (magnetic quantum number). Alternative to the magnetic quantum number, the orbitals are often labeled by the associated harmonic polynomials (e.g., ''xy'', ). Each such orbital can be occupied by a maximum of two electrons, each with its own projection of spin m_s. The simple names s orbital ...
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Associated Legendre Polynomial
In mathematics, the associated Legendre polynomials are the canonical solutions of the general Legendre equation \left(1 - x^2\right) \frac P_\ell^m(x) - 2 x \frac P_\ell^m(x) + \left \ell (\ell + 1) - \frac \rightP_\ell^m(x) = 0, or equivalently \frac \left \left(1 - x^2\right) \frac P_\ell^m(x) \right+ \left \ell (\ell + 1) - \frac \rightP_\ell^m(x) = 0, where the indices ''ℓ'' and ''m'' (which are integers) are referred to as the degree and order of the associated Legendre polynomial respectively. This equation has nonzero solutions that are nonsingular on only if ''ℓ'' and ''m'' are integers with 0 ≤ ''m'' ≤ ''ℓ'', or with trivially equivalent negative values. When in addition ''m'' is even, the function is a polynomial. When ''m'' is zero and ''ℓ'' integer, these functions are identical to the Legendre polynomials. In general, when ''ℓ'' and ''m'' are integers, the regular solutions are sometimes called "associated Legendre polynomials", even though they are ...
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Spherical Coordinates
In mathematics, a spherical coordinate system is a coordinate system for three-dimensional space where the position of a point is specified by three numbers: the ''radial distance'' of that point from a fixed origin, its ''polar angle'' measured from a fixed zenith direction, and the ''azimuthal angle'' of its orthogonal projection on a reference plane that passes through the origin and is orthogonal to the zenith, measured from a fixed reference direction on that plane. It can be seen as the three-dimensional version of the polar coordinate system. The radial distance is also called the ''radius'' or ''radial coordinate''. The polar angle may be called '' colatitude'', '' zenith angle'', '' normal angle'', or ''inclination angle''. When radius is fixed, the two angular coordinates make a coordinate system on the sphere sometimes called spherical polar coordinates. The use of symbols and the order of the coordinates differs among sources and disciplines. This article wi ...
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