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Sulphide
Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (HS−) are the conjugate acids of sulfide. Chemical properties The sulfide ion does not exist in aqueous alkaline solutions of Na2S. Instead sulfide converts to hydrosulfide: :S2− + H2O → SH− + OH− Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: :S2− + H+ → SH− :SH− + H+ → H2S Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. :8 MgS + 8 I2 → S8 + 8 MgI2 Metal derivatives Aqu ...
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Dimethyl Sulfide
Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula . It is the simplest thioether and has a characteristic disagreeable odor. It is a flammable liquid that boils at . It is a component of the smell produced from cooking of certain vegetables (notably maize, cabbage, and beetroot) and seafoods. It is also an indication of bacterial contamination in malt production and brewing. It is a breakdown product of dimethylsulfoniopropionate (DMSP), and is also produced by the bacterial metabolism of methanethiol. Occurrence and production DMS originates primarily from DMSP, a major secondary metabolite in some marine algae. DMS is the most abundant biological sulfur compound emitted to the atmosphere. Emission occurs over the oceans by phytoplankton. DMS is also produced naturally by bacterial transformation of dimethyl sulfoxide (DMSO) waste that is disposed of into sewers, where it can cause environmental odor problems. DMS is oxidized in ...
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the human body produces small amounts of this sulfide and its mineral salts, and uses it as a signalling molecule. Hydrogen sulfide is often produced from the microbial breakdown of organic matter in the absence of oxygen, such as in swamps and sewers; this process is commonly known as anaerobic digestio ...
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Bisulfide
Bisulfide (or bisulphide in British English) is an inorganic anion with the chemical formula HS− (also written as SH−). It contributes no color to bisulfide salts, and its salts may have a distinctive putrid smell. It is a strong base. Bisulfide solutions are corrosive and attack the skin. It is an important chemical reagent and an industrial chemical, mainly used in paper pulp industry (Kraft process), textiles, synthetic flavors, coloring brasses, and iron control. Properties A variety of salts are known, including sodium hydrosulfide and potassium hydrosulfide. Ammonium hydrosulfide, a component of "stink bombs" has not been isolated as a pure solid. Some compounds described as salts of the sulfide dianion contain primarily hydrosulfide. For example, the hydrated form of sodium sulfide, nominally with the formula , is better described as . Aqueous bisulfide absorbs light at around 230 nm in the UV–visible spectrum. Using this approach, bisulfide has been d ...
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Cinnabar
Cinnabar (; ), or cinnabarite (), also known as ''mercurblende'' is the bright scarlet to brick-red form of Mercury sulfide, mercury(II) sulfide (HgS). It is the most common source ore for refining mercury (element), elemental mercury and is the historic source for the brilliant red or scarlet pigment termed vermilion and associated red mercury pigments. Cinnabar generally occurs as a vein-filling mineral associated with volcanic activity and Alkaline earth metal, alkaline hot springs. The mineral resembles quartz in symmetry and it exhibits birefringence. Cinnabar has a mean refractive index near 3.2, a mohs scale of mineral hardness, hardness between 2.0 and 2.5, and a specific gravity of approximately 8.1. The color and properties derive from a structure that is a hexagonal crystalline bravais lattice, lattice belonging to the trigonal crystal system, crystals that sometimes exhibit Crystal twinning, twinning. Cinnabar has been used for its color since antiquity in the Near ...
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Silver
Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. Silver is found in the Earth's crust in the pure, free elemental form ("native metal, native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc Refining (metallurgy), refining. Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes bimetallism, alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of the seven metals of antiquity, silver has had an enduring role in most human cultures. Other than in currency and as an in ...
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Argentite
In mineralogy, argentite () is cubic silver sulfide (Ag2S), which can only exist at temperatures above , , or . When it cools to ordinary temperatures it turns into its monoclinic polymorph, acanthite. The International Mineralogical Association has decided to reject argentite as a proper mineral. The name "argentite" sometimes also refers to pseudomorphs of argentite: specimens of acanthite which still display some of the outward signs of the cubic crystal form, even though their actual crystal structure is monoclinic due to the lower temperature. This form of acanthite is occasionally found as uneven cubes and octahedra, but more often as dendritic or earthy masses, with a blackish lead-grey color and metallic luster. Argentite belongs to the galena group. Cleavage, which is so prominent a feature in galena, here presents only in traces. The mineral is perfectly sectile and has a shining streak; hardness 2.5, specific gravity is 7.2–7.4. It occurs in mineral veins, and w ...
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Cations
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons (e.g. K+ ( potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl− ( chloride ion) and OH− (hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed ''monatomic ions'', ''atomic ions'' or ''simple ions'', while ions consisting of two or more atoms are termed polyatomic ions or ''molecular ions''. If only a + or − is present, it indica ...
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Mercury (element)
Mercury is a chemical element; it has Symbol (chemistry), symbol Hg and atomic number 80. It is commonly known as quicksilver. A Heavy metal element, heavy, silvery d-block element, mercury is the only metallic element that is known to be liquid at standard temperature and pressure; the only other element that is liquid under these conditions is the halogen bromine, though metals such as caesium, gallium, and rubidium melt just above room temperature. Mercury occurs in deposits throughout the world mostly as cinnabar (mercuric sulfide). The red pigment vermilion is obtained by Mill (grinding), grinding natural cinnabar or synthetic mercuric sulfide. Exposure to mercury and mercury-containing organic compounds is toxic to the nervous system, immune system and kidneys of humans and other animals; mercury poisoning can result from exposure to water-soluble forms of mercury (such as mercuric chloride or methylmercury) either directly or through mechanisms of biomagnification. Mercu ...
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Galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the Cubic (crystal system), cubic crystal system often showing octahedral forms. It is often associated with the minerals sphalerite, calcite and fluorite. As a pure specimen held in the hand, under standard temperature and pressure, galena is insoluble in water and so is almost non-toxic. Handling galena under these specific conditions (such as in a museum or as part of geology instruction) poses practically no risk; however, as lead(II) sulfide is reasonably reactive in a variety of environments, it can be highly toxic if swallowed or inhaled, particularly under prolonged or repeated exposure. Occurrence Galena is the main ore of lead, used since ancient times, since lead can be smelted from galena in an ordinary wood fire. G ...
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Lead
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable nuclide, stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its Amphoterism, amphoteric nature; lead and lead oxides react with acids and base (chemistry), bases, and it tends to form covalent bonds. Lead compounds, Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited ...
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