Selectivity (electronic)
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Selectivity (electronic)
Selectivity may refer to: Psychology and behaviour * Choice, making a selection among options * Discrimination, the ability to recognize differences * Socioemotional selectivity theory, in social psychology Engineering * Selectivity (radio), a measure of the performance of a radio receiver to respond only to the radio signal it is tuned * Selectivity (circuit breakers), the coordination of overcurrent protection devices in an electrical installation Biology * Binding selectivity, in pharmacology * Functional selectivity, in pharmacology * Natural selection Natural selection is the differential survival and reproduction of individuals due to differences in phenotype. It is a key mechanism of evolution, the change in the Heredity, heritable traits characteristic of a population over generation ..., in biology Chemistry * Reactivity–selectivity principle, in general chemistry * Chemoselectivity, a term used in organic chemistry to describe reactivity of one funct ...
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Choice
A choice is the range of different things from which a being can choose. The arrival at a choice may incorporate Motivation, motivators and Choice modelling, models. Freedom of choice is generally cherished, whereas a severely limited or artificially restricted choice can lead to discomfort with choosing, and possibly an unsatisfactory outcome. In contrast, a choice with excessively numerous options may lead to confusion, reduced satisfaction, regret of the alternatives not taken, and indifference in an unstructured existence; and the illusion that choosing an object or a course, necessarily leads to the control of that object or course, can cause psychological problems. Types One can distinguish four or five main types of decisions, although they can be expressed in different ways. Brian Tracy breaks them down into: # command decisions, which can only be made by you, as the "Commander in Chief", or owner of a company # delegated decisions, which may be made by anyone. Decisio ...
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Discrimination (information)
Discrimination in the original and broadest sense is the act of distinguishing one thing from another. Business and engineering * Discrimination testing is a technique employed in sensory analysis to determine whether there is a detectable difference among two or more products. * Markovian discrimination is a method used in spam filters to model the statistical behaviors of spam and nonspam. * Net bias (also called data discrimination) is the differentiation of price or quality of Internet data transmission. * Price discrimination, or price differentiation, is a pricing strategy where identical or similar goods or services are sold at different prices by the same provider to different customers. * Selectivity (circuit breakers) (also known as ''circuit breaker discrimination'') is the coordination of overcurrent protection devices so that a fault in the installation is cleared by the protection device located immediately upstream of the fault. * Term discrimination is a way to ...
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Socioemotional Selectivity Theory
Socioemotional selectivity theory (SST; developed by Stanford psychologist Laura L. Carstensen) is a life-span theory of motivation. The theory maintains that as time horizons shrink, as they typically do with age, people become increasingly selective, investing greater resources in emotionally meaningful goals and activities. According to the theory, motivational shifts also influence cognitive processing. Aging is associated with a relative preference for positive over negative information in individuals who have had rewarding relationships. This selective narrowing of social interaction maximizes positive emotional experiences and minimizes emotional risks as individuals become older. According to this theory, older adults systematically hone their social networks so that available social partners satisfy their emotional needs. The theory also focuses on the types of goals that individuals are motivated to achieve. Knowledge-related goals aim at knowledge acquisition, career plan ...
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Selectivity (radio)
Selectivity is a measure of the performance of a radio receiver to respond only to the radio signal it is tuned to (such as a radio station) and reject other signals nearby in frequency, such as another broadcast on an adjacent channel. Selectivity is usually measured as a ratio in decibels (dB), comparing the signal strength received against that of a similar signal on another frequency. If the signal is at the adjacent channel of the selected signal, this measurement is also known as adjacent-channel rejection ratio (ACRR). Selectivity also provides some immunity to blanketing interference. LC circuits are often used as filters; the Q ("Quality" factor) determines the bandwidth of each LC tuned circuit in the radio. The L/C ratio, in turn, determines their Q and so their selectivity, because the rest of the circuit - the aerial or amplifier feeding the tuned circuit for example - will contain present resistance. For a series resonant circuit, the higher the inductance and t ...
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Selectivity (circuit Breakers)
Selectivity, also known as circuit breaker discrimination, is the coordination of overcurrent protection devices so that a fault in the installation is cleared by the protection device located immediately upstream of the fault. The purpose of selectivity is to minimize the impact of a failure on the network. Faults in an installation are, for example, overload and short circuit. There are four ways in which selectivity is achieved:{{cite web, url=https://eduscol.education.fr/sti/sites/eduscol.education.fr.sti/files/ressources/techniques/3363/3363-ect201.pdf, title=Discrimination with LV power circuit-breakers, author=Jean-Pierre Nereau, date=April 2001, publisher=Schneider Electric Schneider Electric SE is a French multinational corporation that specializes in digital automation and energy management. Registered as a Societas Europaea, Schneider Electric is a ''Fortune'' Global 500 company, publicly traded on the Euronex ..., page=6, language=en, access-date=18 September 2021 ...
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Binding Selectivity
In chemistry, binding selectivity is defined with respect to the binding of ligands to a substrate forming a complex. Binding selectivity describes how a ligand may bind more preferentially to one receptor than another. A selectivity coefficient is the equilibrium constant for the reaction of displacement by one ligand of another ligand in a complex with the substrate. Binding selectivity is of major importance in biochemistry and in chemical separation processes. Selectivity coefficient The concept of selectivity is used to quantify the extent to which one chemical substance, A, binds each of two other chemical substances, B and C. The simplest case is where the complexes formed have 1:1 stoichiometry. Then, the two interactions may be characterized by equilibrium constants and .The constant used here are ''association'' constants. ''Dissociation'' constants are used in some contexts. A dissociation constant is the reciprocal of an association constant. \begin \ce;& \quad ...
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Functional Selectivity
Functional selectivity (or agonist trafficking, biased agonism, biased signaling, ligand bias, and differential engagement) is the ligand-dependent selectivity for certain signal transduction pathways relative to a reference ligand (often the endogenous hormone or peptide) at the same receptor. Functional selectivity can be present when a receptor has several possible signal transduction pathways. To which degree each pathway is activated thus depends on which ligand binds to the receptor. Functional selectivity, or biased signaling, is most extensively characterized at G protein coupled receptors (GPCRs). A number of biased agonists, such as those at muscarinic M2 receptors tested as analgesics or antiproliferative drugs, or those at opioid receptors that mediate pain, show potential at various receptor families to increase beneficial properties while reducing side effects. For example, pre-clinical studies with G protein biased agonists at the μ-opioid receptor show equivalent ...
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Natural Selection
Natural selection is the differential survival and reproduction of individuals due to differences in phenotype. It is a key mechanism of evolution, the change in the Heredity, heritable traits characteristic of a population over generations. Charles Darwin popularised the term "natural selection", contrasting it with selective breeding, artificial selection, which is intentional, whereas natural selection is not. Genetic diversity, Variation of traits, both Genotype, genotypic and phenotypic, exists within all populations of organisms. However, some traits are more likely to facilitate survival and reproductive success. Thus, these traits are passed the next generation. These traits can also become more Allele frequency, common within a population if the environment that favours these traits remains fixed. If new traits become more favoured due to changes in a specific Ecological niche, niche, microevolution occurs. If new traits become more favoured due to changes in the ...
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Reactivity–selectivity Principle
In chemistry the reactivity–selectivity principle or RSP states that a more reactive chemical compound or reactive intermediate is less selective in chemical reactions. In this context selectivity represents the ratio of reaction rates. This principle was generally accepted until the 1970s when too many exceptions started to appear. The principle is now considered obsolete. A classic example of perceived RSP found in older organic chemistry textbooks concerns the free radical halogenation of simple alkanes. Whereas the relatively unreactive bromine reacts with 2-methylbutane predominantly to 2-bromo-2-methylbutane, the reaction with much more reactive chlorine results in a mixture of all four regioisomers. Another example of RSP can be found in the selectivity of the reaction of certain carbocations with azides and water. The very stable triphenylmethyl carbocation derived from solvolysis of the corresponding triphenylmethyl chloride reacts 100 times faster with the azide ...
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Chemoselectivity
Chemoselectivity is the preferential reaction of a chemical reagent with one of two or more different functional groups. In a chemoselective system, a reagent in the presence of an aldehyde and an ester would mostly target the aldehyde, even if it has the option to react with the ester. Chemoselectivity is an area of interest in chemistry because scientists want to recreate complex biological compounds, such as natural products, and make specific modifications to them. Most chemical reactions bring together atoms that have negative charge character and atoms that have positive charge character. When evaluating possible reaction outcomes, several factors should be considered. The most important being identifying where in the molecule has the most electron density and where has the least. This analysis gives a good prediction of reactivity, but more factors such as connectivity, atomic orbital overlap, solvent effects, and the addition of supporting reagents can affect the reaction o ...
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Stereoselectivity
In chemistry, stereoselectivity is the property of a chemical reaction in which a single reactant forms an unequal mixture of stereoisomers during a non- stereospecific creation of a new stereocenter or during a non-stereospecific transformation of a pre-existing one. The selectivity arises from differences in steric and electronic effects in the mechanistic pathways leading to the different products. Stereoselectivity can vary in degree but it can never be total since the activation energy difference between the two pathways is finite: both products are at least possible and merely differ in amount. However, in favorable cases, the minor stereoisomer may not be detectable by the analytic methods used. An enantioselective reaction is one in which one enantiomer is formed in preference to the other, in a reaction that creates an optically active product from an achiral starting material, using either a chiral catalyst, an enzyme or a chiral reagent. The degree of selectivity is ...
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Regioselectivity
In organic chemistry, regioselectivity is the preference of chemical bonding or breaking in one direction over all other possible directions. It can often apply to which of many possible positions a reagent will affect, such as which proton a strong base will abstract from an organic molecule, or where on a substituted benzene ring a further substituent will be added. A specific example is a halohydrin formation reaction with 2-propenylbenzene: : Because of the preference for the formation of one product over another, the reaction is selective. This reaction is regioselective because it selectively generates one constitutional isomer rather than the other. Various examples of regioselectivity have been formulated as rules for certain classes of compounds under certain conditions, many of which are named. Among the first introduced to chemistry students are Markovnikov's rule for the addition of protic acids to alkenes, and the Fürst-Plattner rule for the addition of ...
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