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Rokushō
is a traditional Japanese chemical compound used in the ''niiro'' process for artificially inducing patination in decorative non-ferrous metals, especially several copper alloys, with the results being metals of the ''irogane'' class. These "colour metals," virtually unknown outside Japan until the late 19th century, have achieved some popularity in craft circles in other parts of the world since then. Usage ''Rokushō'' is used to treat a number of metals, including raw natural copper, which holds impurities, purified copper, and copper alloy mixes with two to five metals, to produce ''irogane'' metals, including: ''shakudō'', an alloy of copper and gold, which becomes black to dark blue-violet; ''shibuichi'', an alloy of fine silver and copper (in a higher percentage than sterling), which turns grey to misty aquamarine or other shades of blue to green; ''kuromido'' which becomes dark coppery black. ''Rokushō'' was generally used to patinate all types of ''mokume-gane'' ("w ...
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Mokume-gane
is a Japanese metalworking procedure which produces a mixed-metal laminate with distinctive layered patterns; the term is also used to refer to the resulting laminate itself. The term translates closely to "wood grain metal" or "wood eye metal" and describes the way metal takes on the appearance of natural wood grain. fuses several layers of differently coloured precious metals together to form a sandwich of alloys called a "billet." The billet is then manipulated in such a way that a pattern resembling wood grain emerges over its surface. Numerous ways of working create diverse patterns. Once the metal has been rolled into a sheet or bar, several techniques are used to produce a range of effects. has been used to create many artistic objects. Though the technique was first developed for production of decorative sword fittings, the craft is today mostly used in the production of jewelry and hollowware. History Origins First developed in 17th-century Japan, was originally ...
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Irogane
''Irogane'' (色金 "coloured metals")Vienna, Bohlau Verlag, 2009: Griesser-Stermscheg & Krist, eds., Metallkonservierung, Metallrestaurierung: Geschichte, Methode, Praxis is the term for a set of Japanese metals – forms of copper (with natural impurities), and copper alloys – treated in '' niiro'' patination processes,London, UK, 1988: International Institute for Conservation of Historic and Artistic Works, Studies in Conservation – The Conservation of Far Eastern Art (Kyoto Congress 1988 Preprints), Mills ''et al''., eds., p. 133-136: Murakami et al, "Characterization of the black surface layer on a copper alloy coloured by traditional Japanese surface treatment" – "Irogane is the general term for the alloys coloured ..." traditionally used in sword-making, catches for sliding doors, and luxury highlights on larger objects, and in modern times, in jewellery. The alloys contain two to five metals. Some scholars believe that methods similar to those involved in iro ...
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Shakudō
''Shakudō'' (赤銅) is a Japanese billon of gold and copper (typically 4–10% gold, 96–90% copper), one of the '' irogane'' class of colored metals, which can be treated to develop a black, or sometimes indigo, patina, resembling lacquer. Unpatinated ''shakudō'' visually resembles bronze; the dark color is induced by the '' niiro'' artificial patination process, involving boiling in a solution, generally including '' rokushō''. Naming The characters in the name ''shaku-dō'' mean "red" and "copper" but combined they represent this material which begins with a darkened coppery-bronze color and is then modified to black or near-black. History Early uses The word "shakudō" first appears in records of the Japanese "Nara" period (710-784 AD), but it is not clear to what it referred (it could have been some form of copper, or a form of the now-known material). There are actual pieces known from the 12th century onwards. Shakudō was historically used to construct or decora ...
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Shibuichi
is a historically Japanese copper alloy, a member of the '' irogane'' class, which is patinated into a range of subtle greys and muted shades of blue, green, and brown, through the use of '' niiro'' processes, involving the '' rokushō'' compound. Naming ''Shibuichi'' means "one-fourth" in Japanese, and indicates the standard formulation of one part silver to three parts copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ..., though this may be varied considerably according to the desired effect. Several major variants of the alloy have specific names, as detailed below. In addition, the metal in general, and especially the paler shades, may be named ''rogin''. Composition Aside from the basic 25% silver to 75% copper mix, combinations as divergent as 5% silver to 95% cop ...
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Irogane
''Irogane'' (色金 "coloured metals")Vienna, Bohlau Verlag, 2009: Griesser-Stermscheg & Krist, eds., Metallkonservierung, Metallrestaurierung: Geschichte, Methode, Praxis is the term for a set of Japanese metals – forms of copper (with natural impurities), and copper alloys – treated in '' niiro'' patination processes,London, UK, 1988: International Institute for Conservation of Historic and Artistic Works, Studies in Conservation – The Conservation of Far Eastern Art (Kyoto Congress 1988 Preprints), Mills ''et al''., eds., p. 133-136: Murakami et al, "Characterization of the black surface layer on a copper alloy coloured by traditional Japanese surface treatment" – "Irogane is the general term for the alloys coloured ..." traditionally used in sword-making, catches for sliding doors, and luxury highlights on larger objects, and in modern times, in jewellery. The alloys contain two to five metals. Some scholars believe that methods similar to those involved in iro ...
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Japan
Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north toward the East China Sea, Philippine Sea, and Taiwan in the south. Japan is a part of the Ring of Fire, and spans an archipelago of 6852 islands covering ; the five main islands are Hokkaido, Honshu (the "mainland"), Shikoku, Kyushu, and Okinawa. Tokyo is the nation's capital and largest city, followed by Yokohama, Osaka, Nagoya, Sapporo, Fukuoka, Kobe, and Kyoto. Japan is the eleventh most populous country in the world, as well as one of the most densely populated and urbanized. About three-fourths of the country's terrain is mountainous, concentrating its population of 123.2 million on narrow coastal plains. Japan is divided into 47 administrative prefectures and eight traditional regions. The Greater Tokyo Ar ...
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Copper Sulfate
Copper sulfate may refer to: * Copper(II) sulfate Copper(II) sulfate, also known as copper sulphate, is an inorganic compound with the chemical formula . It forms hydrates , where ''n'' can range from 1 to 7. The pentahydrate (''n'' = 5), a bright blue crystal, is the most commonly encountered hy ..., CuSO4, a common compound used as a fungicide and herbicide * Copper(I) sulfate, Cu2SO4, which is uncommonly used * Copper(II) sulfate, CuSO4 is greenish blue Copper compounds {{Chem-stub ...
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Artistic Techniques
Art is a diverse range of human activity, and resulting product, that involves creative or imaginative talent expressive of technical proficiency, beauty, emotional power, or conceptual ideas. There is no generally agreed definition of what constitutes art, and its interpretation has varied greatly throughout history and across cultures. In the Western tradition, the three classical branches of visual art are painting, sculpture, and architecture. Theatre, dance, and other performing arts, as well as literature, music, film and other media such as interactive media, are included in a broader definition of the arts. Until the 17th century, ''art'' referred to any skill or mastery and was not differentiated from crafts or sciences. In modern usage after the 17th century, where aesthetic considerations are paramount, the fine arts are separated and distinguished from acquired skills in general, such as the decorative or applied arts. The nature of art and related concepts, ...
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Pumice
Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular volcanic rock that differs from pumice in having larger vesicles, thicker vesicle walls, and being dark colored and denser.Jackson, J.A., J. Mehl, and K. Neuendorf (2005) ''Glossary of Geology'' American Geological Institute, Alexandria, Virginia. 800 pp. McPhie, J., M. Doyle, and R. Allen (1993) ''Volcanic Textures A guide to the interpretation of textures in volcanic rocks'' Centre for Ore Deposit and Exploration Studies, University of Tasmania, Hobart, Tasmania..198 pp. Pumice is created when super-heated, highly pressurized rock is violently ejected from a volcano. The unusual foamy configuration of pumice happens because of simultaneous rapid cooling and rapid depressurization. The depressurization creates bubbles by lowering the solu ...
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Daikon Radish
Daikon or mooli, ''Raphanus sativus'' var. ''longipinnatus,'' is a mild-flavored winter radish usually characterized by fast-growing leaves and a long, white, root. Originally native to continental East Asia, daikon is harvested and consumed throughout the region, as well as in South Asia, and is available internationally. In some locations, daikon is planted for its ability to break up compacted soils and recover nutrients, but is not harvested. Names In culinary contexts, ''daikon'' ( ja, 大根, lit=big root) or are the most common names in all forms of English. Historical ties to South Asia permit ''mooli'' () as a general synonym in English. The generic terms white radish, winter radish, Oriental radish, long white radish, and other terms are also used. Other synonyms usually vary by region or describe regional varieties of the vegetable. When it is necessary to distinguish the usual Japanese form from others, it is sometimes known as Japanese radish.Robert Bailey ...
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Sulfuric Acid
Sulfuric acid ( American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released ...
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Oxalic Acid
Oxalic acid is an organic acid with the systematic name ethanedioic acid and formula . It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name comes from the fact that early investigators isolated oxalic acid from flowering plants of the genus '' Oxalis'', commonly known as wood-sorrels. It occurs naturally in many foods. Excessive ingestion of oxalic acid or prolonged skin contact can be dangerous. Oxalic acid has much greater acid strength than acetic acid. It is a reducing agent and its conjugate base, known as oxalate (), is a chelating agent for metal cations. Typically, oxalic acid occurs as the dihydrate with the formula . History The preparation of salts of oxalic acid (crab acid) from plants had been known, at least since 1745, when the Dutch botanist and physician Herman Boerhaave isolated a salt from wood sorrel. By 1773, François Pierre Savary of Fribourg, Switzerland had isolated oxalic acid ...
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