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Quantization (physics)
In physics, quantization (in British English quantisation) is the systematic transition procedure from a classical understanding of physical phenomena to a newer understanding known as quantum mechanics. It is a procedure for constructing quantum mechanics from classical mechanics. A generalization involving infinite degrees of freedom is field quantization, as in the "quantization of the electromagnetic field", referring to photons as field " quanta" (for instance as light quanta). This procedure is basic to theories of atomic physics, chemistry, particle physics, nuclear physics, condensed matter physics, and quantum optics. Historical overview In 1901, when Max Planck was developing the distribution function of statistical mechanics to solve ultraviolet catastrophe problem, he realized that the properties of blackbody radiation can be explained by the assumption that the amount of energy must be in countable fundamental units, i.e. amount of energy is not continuous ...
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Wigner–Weyl Transform
In quantum mechanics, the Wigner–Weyl transform or Weyl–Wigner transform (after Hermann Weyl and Eugene Wigner) is the invertible mapping between functions in the quantum phase space formulation and Hilbert space operators in the Schrödinger picture. Often the mapping from functions on phase space to operators is called the Weyl transform or Weyl quantization, whereas the inverse mapping, from operators to functions on phase space, is called the Wigner transform. This mapping was originally devised by Hermann Weyl in 1927 in an attempt to map symmetrized ''classical'' phase space functions to operators, a procedure known as ''Weyl quantization''. It is now understood that Weyl quantization does not satisfy all the properties one would require for consistent quantization and therefore sometimes yields unphysical answers. On the other hand, some of the nice properties described below suggest that if one seeks a single consistent procedure mapping functions on the classica ...
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Blackbody Radiation
Black-body radiation is the thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body (an idealized opaque, non-reflective body). It has a specific, continuous spectrum of wavelengths, inversely related to intensity, that depend only on the body's temperature, which is assumed, for the sake of calculations and theory, to be uniform and constant., Chapter 13. A perfectly insulated enclosure which is in thermal equilibrium internally contains black-body radiation, and will emit it through a hole made in its wall, provided the hole is small enough to have a negligible effect upon the equilibrium. The thermal radiation spontaneously emitted by many ordinary objects can be approximated as black-body radiation. Of particular importance, although planets and stars (including the Earth and Sun) are neither in thermal equilibrium with their surroundings nor perfect black bodies, black-body radiation is ...
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Vacuum State
In quantum field theory, the quantum vacuum state (also called the quantum vacuum or vacuum state) is the quantum state with the lowest possible energy. Generally, it contains no physical particles. The word zero-point field is sometimes used as a synonym for the vacuum state of a quantized field which is completely individual. According to present-day understanding of what is called the vacuum state or the quantum vacuum, it is "by no means a simple empty space". According to quantum mechanics, the vacuum state is not truly empty but instead contains fleeting electromagnetic waves and particles that pop into and out of the quantum field. The QED vacuum of quantum electrodynamics (or QED) was the first vacuum of quantum field theory to be developed. QED originated in the 1930s, and in the late 1940s and early 1950s it was reformulated by Feynman, Tomonaga, and Schwinger, who jointly received the Nobel prize for this work in 1965. For a historical discussion, see for e ...
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Quantum State
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in time exhausts all that can be predicted about the system's behavior. A mixture of quantum states is again a quantum state. Quantum states that cannot be written as a mixture of other states are called pure quantum states, while all other states are called mixed quantum states. A pure quantum state can be represented by a ray in a Hilbert space over the complex numbers, while mixed states are represented by density matrices, which are positive semidefinite operators that act on Hilbert spaces. Pure states are also known as state vectors or wave functions, the latter term applying particularly when they are represented as functions of position or momentum. For example, when dealing with the energy spectrum of the electron in a hydrog ...
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Creation And Annihilation Operators
Creation operators and annihilation operators are mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. An annihilation operator (usually denoted \hat) lowers the number of particles in a given state by one. A creation operator (usually denoted \hat^\dagger) increases the number of particles in a given state by one, and it is the adjoint of the annihilation operator. In many subfields of physics and chemistry, the use of these operators instead of wavefunctions is known as second quantization. They were introduced by Paul Dirac. Creation and annihilation operators can act on states of various types of particles. For example, in quantum chemistry and many-body theory the creation and annihilation operators often act on electron states. They can also refer specifically to the ladder operators for the quantum harmonic oscillator. In the latter case, the raising operator is i ...
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Canonical Coordinate
In mathematics and classical mechanics, canonical coordinates are sets of coordinates on phase space which can be used to describe a physical system at any given point in time. Canonical coordinates are used in the Hamiltonian formulation of classical mechanics. A closely related concept also appears in quantum mechanics; see the Stone–von Neumann theorem and canonical commutation relations for details. As Hamiltonian mechanics are generalized by symplectic geometry and canonical transformations are generalized by contact transformations, so the 19th century definition of canonical coordinates in classical mechanics may be generalized to a more abstract 20th century definition of coordinates on the cotangent bundle of a manifold (the mathematical notion of phase space). Definition in classical mechanics In classical mechanics, canonical coordinates are coordinates q^i and p_i in phase space that are used in the Hamiltonian formalism. The canonical coordinates satisfy ...
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Commutation Relation
In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory. Group theory The commutator of two elements, and , of a group , is the element : . This element is equal to the group's identity if and only if and commute (from the definition , being equal to the identity if and only if ). The set of all commutators of a group is not in general closed under the group operation, but the subgroup of ''G'' generated by all commutators is closed and is called the ''derived group'' or the ''commutator subgroup'' of ''G''. Commutators are used to define nilpotent and solvable groups and the largest abelian quotient group. The definition of the commutator above is used throughout this article, but many other group theorists define the commutator as :. Identities (group theory) Commutator identities are an important tool in group theory. The e ...
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Henri Poincaré
Jules Henri Poincaré ( S: stress final syllable ; 29 April 1854 – 17 July 1912) was a French mathematician, theoretical physicist, engineer, and philosopher of science. He is often described as a polymath, and in mathematics as "The Last Universalist", since he excelled in all fields of the discipline as it existed during his lifetime. As a mathematician and physicist, he made many original fundamental contributions to pure and applied mathematics, mathematical physics, and celestial mechanics. In his research on the three-body problem, Poincaré became the first person to discover a chaotic deterministic system which laid the foundations of modern chaos theory. He is also considered to be one of the founders of the field of topology. Poincaré made clear the importance of paying attention to the invariance of laws of physics under different transformations, and was the first to present the Lorentz transformations in their modern symmetrical form. Poincaré disc ...
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Niels Bohr
Niels Henrik David Bohr (; 7 October 1885 – 18 November 1962) was a Danish physicist who made foundational contributions to understanding atomic structure and quantum theory, for which he received the Nobel Prize in Physics in 1922. Bohr was also a philosopher and a promoter of scientific research. Bohr developed the Bohr model of the atom, in which he proposed that energy levels of electrons are discrete and that the electrons revolve in stable orbits around the atomic nucleus but can jump from one energy level (or orbit) to another. Although the Bohr model has been supplanted by other models, its underlying principles remain valid. He conceived the principle of complementarity: that items could be separately analysed in terms of contradictory properties, like behaving as a wave or a stream of particles. The notion of complementarity dominated Bohr's thinking in both science and philosophy. Bohr founded the Institute of Theoretical Physics at the University of ...
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Photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always move at the speed of light in vacuum, (or about ). The photon belongs to the class of bosons. As with other elementary particles, photons are best explained by quantum mechanics and exhibit wave–particle duality, their behavior featuring properties of both waves and particles. The modern photon concept originated during the first two decades of the 20th century with the work of Albert Einstein, who built upon the research of Max Planck. While trying to explain how matter and electromagnetic radiation could be in thermal equilibrium with one another, Planck proposed that the energy stored within a material object should be regarded as composed of an integer number of discrete, equal-sized parts. To explain the photoelectr ...
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Electromagnetic Wave
In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible) light, ultraviolet, X-rays, and gamma rays. All of these waves form part of the electromagnetic spectrum. Classically, electromagnetic radiation consists of electromagnetic waves, which are synchronized oscillations of electric and magnetic fields. Depending on the frequency of oscillation, different wavelengths of electromagnetic spectrum are produced. In a vacuum, electromagnetic waves travel at the speed of light, commonly denoted ''c''. In homogeneous, isotropic media, the oscillations of the two fields are perpendicular to each other and perpendicular to the direction of energy and wave propagation, forming a transverse wave. The position of an electromagnetic wave within the electromagnetic spectrum can be characterized ...
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Photoelectric Effect
The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, and solid state and quantum chemistry to draw inferences about the properties of atoms, molecules and solids. The effect has found use in electronic devices specialized for light detection and precisely timed electron emission. The experimental results disagree with classical electromagnetism, which predicts that continuous light waves transfer energy to electrons, which would then be emitted when they accumulate enough energy. An alteration in the intensity of light would theoretically change the kinetic energy of the emitted electrons, with sufficiently dim light resulting in a delayed emission. The experimental results instead show that electrons are dislodged only when the light exceeds a certain frequency—regardless of the light's intensity o ...
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