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Preignition
In spark ignition internal combustion engines, knocking (also knock, detonation, spark knock, pinging or pinking) occurs when combustion of some of the air/fuel mixture in the cylinder does not result from propagation of the flame front ignited by the spark plug, but one or more pockets of air/fuel mixture explode outside the envelope of the normal combustion front. The fuel-air charge is meant to be ignited by the spark plug only, and at a precise point in the piston's stroke. Knock occurs when the peak of the combustion process no longer occurs at the optimum moment for the four-stroke cycle. The shock wave creates the characteristic metallic "pinging" sound, and cylinder pressure increases dramatically. Effects of engine knocking range from inconsequential to completely destructive. Knocking should not be confused with pre-ignition—they are two separate events. However, pre-ignition can be followed by knocking. The phenomenon of detonation was described in November 1914 ...
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Flathead Engine
A flathead engine, also known as a sidevalve engine''American Rodder'', 6/94, pp.45 & 93. or valve-in-block engine is an internal combustion engine with its poppet valves contained within the engine block, instead of in the cylinder head, as in an overhead valve engine. Flatheads were widely used internationally by automobile manufacturers from the late 1890s until the mid-1950s but were replaced by more efficient overhead valve and overhead camshaft engines. They are currently experiencing a revival in low-revving aero-engines such as the D-Motor. The side-valve design The valve gear comprises a camshaft sited low in the cylinder block which operates the poppet valves via tappets and short pushrods (or sometimes with no pushrods at all). The flathead system obviates the need for further valvetrain components such as lengthy pushrods, rocker arms, overhead valves or overhead camshafts. The sidevalves are typically adjacent, sited on one side of the cylinder(s), though so ...
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Pre-ignition
Pre-ignition (or preignition) in a spark-ignition engine is a technically different phenomenon from engine knocking, and describes the event wherein the air/fuel mixture in the cylinder ignites before the spark plug fires. Pre-ignition is initiated by an ignition source other than the spark, such as hot spots in the combustion chamber, a spark plug that runs too hot for the application, or carbonaceous deposits in the combustion chamber heated to incandescence by previous engine combustion events. The phenomenon is also referred to as 'after-run', or 'run-on' or sometimes dieseling, when it causes the engine to carry on running after the ignition is shut off. This effect is more readily achieved on carbureted gasoline engines, because the fuel supply to the carburetor is typically regulated by a passive mechanical float valve and fuel delivery can feasibly continue until fuel line pressure has been relieved, provided the fuel can be somehow drawn past the throttle plate. The occur ...
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Tetraethyl Lead
Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb( C2H5)4. It is a fuel additive, first being mixed with gasoline beginning in the 1920s as a patented octane rating booster that allowed engine compression to be raised substantially. This in turn increased vehicle performance and fuel economy. TEL was first synthesised by German chemist Carl Jacob Löwig in 1853. American chemical engineer Thomas Midgley Jr., who was working for General Motors, was the first to discover its effectiveness as an antiknock agent in 1921, after spending several years attempting to find an additive that was both highly effective and inexpensive. Concerns were later raised over the toxic effects of lead, especially on children. On cars not designed to operate on leaded gasoline, lead and lead oxides coat the catalyst in catalytic converters, rendering them ineffective, and can sometimes foul spark plugs. Starting in the 1970s, many co ...
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Spark Ignition
A spark-ignition engine (SI engine) is an internal combustion engine, generally a petrol engine, where the combustion process of the air-fuel mixture is ignited by a spark from a spark plug. This is in contrast to compression-ignition engines, typically diesel engines, where the heat generated from compression together with the injection of fuel is enough to initiate the combustion process, without needing any external spark. Fuels Spark-ignition engines are commonly referred to as "gasoline engines" in North America, and "petrol engines" in Britain and the rest of the world. Spark-ignition engines can (and increasingly are) run on fuels other than petrol/gasoline, such as autogas ( LPG), methanol, ethanol, bioethanol, compressed natural gas (CNG), hydrogen, and (in drag racing) nitromethane. Working cycle The working cycle of both spark-ignition and compression-ignition engines may be either two-stroke or four-stroke. A four-stroke spark-ignition engine is an Otto cycle engin ...
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Hypereutectic Piston
A hypereutectic piston is an internal combustion engine piston cast using a hypereutectic aluminum alloy with silicon content greater than the eutectic system, eutectic point of 12 weight percent silicon. Most aluminum-silicon casting alloys are hypoeutectic (Si content lower than the eutectic point) and contain relatively fine elemental silicon crystals formed through the eutectic reaction during solidification. In addition to fine silicon crystals, hypereutectic alloys also contain large primary silicon crystals that form before the eutectic reaction, and as a result contain a much higher phase fraction of silicon. Consequently hypereutectic aluminum has a lower coefficient of thermal expansion, which allows engine designers to specify much tighter clearances. The silicon content of these alloys is typically 16-19 weight percent, and above this content the mechanical properties and castability degrade substantially. Special moulds, casting, and cooling techniques are required to o ...
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Squish (piston Engine)
Squish is an effect in internal combustion engines which creates sudden turbulence of the air-fuel mixture as the piston approaches top dead centre (TDC)."The Combustion Chamber"
Retrieved 16 June 2013.
In an engine designed to use the squish effect, at top dead centre the piston crown comes very close (typically less than 1 mm) to the cylinder head. The gases are suddenly "squished" out within the , creating turbulence which promotes thorough air-fuel mixing, a factor beneficial to efficient . Squish effect may be found in
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Alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula . The alkanes range in complexity from the simplest case of methane (), where ''n'' = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like pentacontane () or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (). The International Union of Pure and Applied Chemistry (IUPAC) defines alkanes as "acyclic branched or unbranched hydrocarbons having the general formula , and therefore consisting entirely of hydrogen atoms and saturated carbon atoms". However, some sources use the term to denote ''any'' saturated hydrocarbon, including those that are either monocyclic (i.e. the cycloalkanes ...
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Water Injection (engines)
In internal combustion engines, water injection, also known as anti-detonant injection (ADI), can spray water into the incoming air or fuel- air mixture, or directly into the combustion chamber to cool certain parts of the induction system where "hot points" could produce premature ignition. In jet engines it increases engine thrust at low speeds and at takeoff. Water injection was used historically to increase the power output of military aviation engines for short durations, such as dogfights or takeoff. However it has also been used in motor sports and notably in drag racing. In Otto cycle engines, the cooling effects of water injection also enables greater compression ratios by reducing engine knocking (detonation). Alternatively, this reduction in engine knocking in Otto cycle engines means that some applications gain significant performance when water injection is used in conjunction with a supercharger, turbocharger, or modifications such as aggressive ignition timing. De ...
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Manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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Thallium
Thallium is a chemical element with the symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes and Claude-Auguste Lamy discovered thallium independently in 1861, in residues of sulfuric acid production. Both used the newly developed method of flame spectroscopy, in which thallium produces a notable green spectral line. Thallium, from Greek , , meaning "green shoot" or "twig", was named by Crookes. It was isolated by both Lamy and Crookes in 1862; Lamy by electrolysis, and Crookes by precipitation and melting of the resultant powder. Crookes exhibited it as a powder precipitated by zinc at the international exhibition, which opened on 1 May that year. Thallium tends to form the +3 and +1 oxidation states. The +3 state resembles that of the other elements in group 13 ( boron, aluminium, gallium, indium). However, the +1 state, whic ...
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Ignition Timing
In a spark ignition internal combustion engine, ignition timing is the timing, relative to the current piston position and crankshaft angle, of the release of a spark in the combustion chamber near the end of the compression stroke. The need for advancing (or retarding) the timing of the spark is because fuel does not completely burn the instant the spark fires. The combustion gases take a period of time to expand and the angular or rotational speed of the engine can lengthen or shorten the time frame in which the burning and expansion should occur. In a vast majority of cases, the angle will be described as a certain angle advanced ''before top dead center'' (BTDC). Advancing the spark BTDC means that the spark is energized prior to the point where the combustion chamber reaches its minimum size, since the purpose of the power stroke in the engine is to force the combustion chamber to expand. Sparks occurring after top dead center (ATDC) are usually counter-productive (produ ...
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Exhaust Gas Recirculation
In internal combustion engines, exhaust gas recirculation (EGR) is a nitrogen oxide () emissions reduction technique used in petrol/gasoline, diesel engines and some hydrogen engines. EGR works by recirculating a portion of an engine's exhaust gas back to the engine cylinders. The exhaust gas displaces atmospheric air and reduces in the combustion chamber. Reducing the amount of oxygen reduces the amount of fuel that can burn in the cylinder thereby reducing peak in-cylinder temperatures. The actual amount of recirculated exhaust gas varies with the engine operating parameters. In the combustion cylinder, is produced by high-temperature mixtures of atmospheric nitrogen and oxygen, and this usually occurs at cylinder peak pressure. In a spark-ignition engine, an ancillary benefit of recirculating exhaust gases via an external EGR valve is an increase in efficiency, as charge dilution allows a larger throttle position and reduces associated pumping losses. Mazda's turbocharge ...
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