Potassium Selenate
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Potassium Selenate
Potassium selenate, , is an odorless, white solid that forms as the potassium salt of selenic acid. Preparation Potassium selenate is produced by the reaction of selenium trioxide and potassium hydroxide. : Alternatively, it can be made by treating selenous acid Selenous acid (or selenious acid) is the chemical compound with the formula . Structurally, it is more accurately described by . It is the principal oxoacid of selenium; the other being selenic acid. Formation and properties Selenous acid is a ... with potassium hydroxide, followed by oxidization of the resulting potassium selenite with bromine water. : : Uses Potassium selenate can be used to produce selenium trioxide. It can also use to treat selenium deficiency in livestock. References {{Potassium compounds Potassium compounds Selenates ...
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Hygroscopic
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance's molecules, adsorbing substances can become physically changed, e.g., changing in volume, boiling point, viscosity or some other physical characteristic or property of the substance. For example, a finely dispersed hygroscopic powder, such as a salt, may become clumpy over time due to collection of moisture from the surrounding environment. ''Deliquescent'' materials are sufficiently hygroscopic that they absorb so much water that they become liquid and form an aqueous solution. Etymology and pronunciation The word ''hygroscopy'' () uses combining forms of '' hygro-'' and '' -scopy''. Unlike any other ''-scopy'' word, it no longer refers to a viewing or imaging mode. It did begin that way, with the word ''hygroscope'' referring in ...
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Potassium Sulfate
Potassium sulfate (US) or potassium sulphate (UK), also called sulphate of potash (SOP), arcanite, or archaically potash of sulfur, is the inorganic compound with formula K2SO4, a white water-soluble solid. It is commonly used in fertilizers, providing both potassium and sulfur. History Potassium sulfate (K2SO4) has been known since early in the 14th century. It was studied by Glauber, Boyle, and Tachenius. In the 17th century, it was named ''arcanuni'' or ''sal duplicatum'', as it was a combination of an acid salt with an alkaline salt. It was also known as ''vitriolic tartar'' and ''Glaser's salt'' or ''sal polychrestum Glaseri'' after the pharmaceutical chemist Christopher Glaser who prepared it and used medicinally. Known as ''arcanum duplicatum'' ("double secret") or ''panacea duplicata'' in pre-modern medicine, it was prepared from the residue (''caput mortuum'') left over from the production of aqua fortis (nitric acid, HNO3) from nitre (potassium nitrate, KNO3) and oil ...
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Sodium Selenate
Sodium selenate is the inorganic compound with the formula , not to be confused with sodium selenite. It exists as the anhydrous salt, the heptahydrate, and the decahydrate. These are white, water-soluble solids. The decahydrate is a common ingredient in multivitamins and livestock feed as a source of selenium. The anhydrous salt is used in the production of some glass. Although the selenates are much more toxic, many physical properties of sodium selenate and sodium sulfate are similar. Production Sodium selenate is produced by oxidation of selenium, first with nitric acid, producing selenous acid. The selenous acid is neutralized to form sodium selenite. The sodium selenite is oxidized in a basic medium hydrogen peroxide to form a selenate, which is then spray-dried. :Se + 2HNO → HSeO + NO + NO :HSeO + NaCO → NaSeO + HO + CO :NaSeO + HO → NaSeO + HO. It was prepared shortly after the discovery of selenium by Jöns Jacob Berzelius in 1817. Industrial uses Gla ...
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Potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmospheric oxygen to form flaky white potassium peroxide in only seconds of exposure. It was first isolated from potash, the ashes of plants, from which its name derives. In the periodic table, potassium is one of the alkali metals, all of which have a single valence electron in the outer electron shell, that is easily removed to create an ion with a positive charge – a cation, that combines with anions to form salts. Potassium in nature occurs only in ionic salts. Elemental potassium reacts vigorously with water, generating sufficient heat to ignite hydrogen emitted in the reaction, and burning with a lilac- colored flame. It is found dissolved in sea water (which is 0.04% potassium by weight), and occurs in many minerals such as orthocl ...
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Salt (chemistry)
In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is Salt, table salt, with positively charged sodium ions and negatively charged chloride ions. The component ions in a salt compound can be either inorganic compound, inorganic, such as chloride (Cl−), or organic chemistry, organic, such as acetate (). Each ion can be either monatomic ion, monatomic, such as fluoride (F−), or polyatomic ion, polyatomic, such as sulfate (). Types of salt Salts can be classified in a variety of ways. Salts that produce hydroxide ions when dissolved in water are called ''alkali salts'' and salts that produce hydrogen ions when dissolved in water are called ''acid salts''. ''Neutral salts'' are those salts that are neither acidic nor basic. Zwitterions contain an anionic and a cationic centre in the same molecule, but are not considered s ...
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Selenic Acid
Selenic acid is the inorganic compound with the formula . It is an oxoacid of selenium, and its structure is more accurately described as . It is a colorless compound. Although it has few uses, its derivative sodium selenate is used in the production of glass and animal feeds.Bernd E. Langner "Selenium and Selenium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. . Structure and bonding The molecule is tetrahedral, as predicted by VSEPR theory. The Se–O bond length is 161  pm. In the solid state, it crystallizes in an orthorhombic structure. Preparation It is prepared by oxidising selenium compounds in lower oxidation states. One method involves the oxidation of selenium dioxide with hydrogen peroxide: : Unlike the production sulfuric acid by hydration of sulfur trioxide, the hydration of selenium trioxide is an impractical method. Instead, selenic acid may also be prepared by the oxidation of selenous acid () with halogens, s ...
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Selenium Trioxide
Selenium trioxide is the inorganic compound with the formula Se O3. It is white, hygroscopic solid. It is also an oxidizing agent and a Lewis acid. It is of academic interest as a precursor to Se(VI) compounds.Egon Wiberg, Arnold Frederick Holleman (2001) ''Inorganic Chemistry'', Elsevier Preparation Selenium trioxide is difficult to prepare because it is unstable with respect to the dioxide: :2 SeO3 → 2 SeO2 + O2 It has been generated in a number of ways despite the fact that the dioxide does not combust under normal conditions. One method entails dehydration of anhydrous selenic acid with phosphorus pentoxide at 150–160 °C. Another method is the reaction of liquid sulfur trioxide with potassium selenate. :SO3 + K2SeO4 → K2SO4 + SeO3 Reactions In its chemistry SeO3 generally resembles sulfur trioxide, SO3, rather than tellurium trioxide, TeO3. At 120 °C SeO3 reacts with selenium dioxide to form the Se(VI)-Se(IV) compound diselenium pentaoxide:Z. Žák " ...
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Potassium Hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exploit its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive. Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous so ...
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Selenous Acid
Selenous acid (or selenious acid) is the chemical compound with the formula . Structurally, it is more accurately described by . It is the principal oxoacid of selenium; the other being selenic acid. Formation and properties Selenous acid is analogous to sulfurous acid, but it is more readily isolated. Selenous acid is easily formed upon the addition of selenium dioxide to water. As a crystalline solid, the compound can be seen as pyramidal molecules that are interconnected with hydrogen bonds. In solution it is a diprotic acid: : (p''K''a = 2.62) : (p''K''a = 8.32) It is moderately oxidizing in nature, but kinetically slow. In 1 M : : (''E''o = +0.74 V) In 1 M : : (''E''o = −0.37 V) Selenous acid is hygroscopic. Uses The major use is in protecting and changing the color of steel, especially steel parts on firearms. The so-called cold-bluing process uses selenous acid, copper(II) nitrate, and nitric acid to change the color of the ...
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Selenite
Selenite may refer to: Substances containing selenium *A selenium-containing anion or ionic compound with the SeO32− anion: **Selenite (ion), anion is a selenium oxoanion with the chemical formula SeO32− ***Selenous acid, the conjugate acid, with the formula H2SeO3 ***Salts of this anion: **** Silver selenite, an inorganic compound of formula Ag2SeO3 ****Sodium selenite, a salt, a colourless solid, and the most common water-soluble selenium compound *Selenite broth, an enrichment medium for the isolation of ''Salmonella'' species Other * Selenite (mineral), a variety of gypsum (CaSO4·2H2O) * ''Selenites'' is a synonym of ''Zophos'', a genus of land snails in the family Haplotrematidae * Selenite Range, a mountain range in Pershing County, Nevada ** Selenite Peak, a summit in the Selenite Range, Nevada * Selenite, a high class citizen that experienced space travel, from the videogame ''Event_0'' * Selenite, a fictional native inhabitant of the Moon; see Moon in science ficti ...
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Bromine Water
Bromine water is an oxidizing, intense brown mixture containing diatomic bromine (Br2) dissolved in water (H2O). It is often used as a reactive in chemical assays of recognition for substances which react with bromine in an aqueous environment with the halogenation mechanism, mainly unsaturated carbon compounds (carbon compounds with 1 or more double or triple bond(s)). The most common compounds that react well with bromine water are phenols, alkenes, enols, the acetyl group, aniline, and glucose. In addition, bromine water is commonly used to test for the presence of an alkene which contains a double covalent bond, reacting with the bromine water, changing its color from an intense yellow to a colorless solution. Bromine water is also commonly used to check for the presence of an aldehyde group In organic chemistry, an aldehyde () is an organic compound containing a functional group with the structure . The functional group itself (without the "R" side chain) can be referred to ...
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Potassium Compounds
Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmospheric oxygen to form flaky white potassium peroxide in only seconds of exposure. It was first isolated from potash, the ashes of plants, from which its name derives. In the periodic table, potassium is one of the alkali metals, all of which have a single valence electron in the outer electron shell, that is easily removed to create an ion with a positive charge – a cation, that combines with anions to form salts. Potassium in nature occurs only in ionic salts. Elemental potassium reacts vigorously with water, generating sufficient heat to ignite hydrogen emitted in the reaction, and burning with a lilac- colored flame. It is found dissolved in sea water (which is 0.04% potassium by weight), and occurs in many minerals such as orthoclase, ...
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