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Peroxynonanoic Acid
Peroxynonanoic acid (also peroxypelargonic acid) is a peroxycarboxylic acid. It is formed from precursor compounds contained in detergents and acts as a bleach. Properties Peroxynonanoic acid crystallizes in the monoclinic crystal system in the space group P21/c with the lattice parameters ''a'' = 23.49 Å; ''b'' = 4.80 Å, ''c'' = 9.64 Å and ''β'' = 106.0° as well as four unit cells. Use Peroxynonanoic acid acts as a bleaching agent in detergents but is not contained in the detergent itself; it is only formed during the washing process. Hydroperoxide ions, for example from sodium perborate, react with an activator to form peroxycarboxylic acid, which acts as the actual bleaching agent, achieving satisfactory results at lower temperatures than with sodium perborate alone. The main activators used are tetraacetylethylenediamine, which produces peroxyacetic acid (mainly in Europe), and sodium nonanoyloxybenzenesulfonate Sodium nonanoyloxybenzenesulfonate (NOBS) is an import ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mole (unit)
The mole (symbol mol) is a unit of measurement, the base unit in the International System of Units (SI) for ''amount of substance'', an SI base quantity proportional to the number of elementary entities of a substance. One mole is an aggregate of exactly elementary entities (approximately 602 sextillion or 602 billion times a trillion), which can be atoms, molecules, ions, ion pairs, or other particles. The number of particles in a mole is the Avogadro number (symbol ) and the numerical value of the '' Avogadro constant'' (symbol ) expressed in mol−1. The relationship between the mole, Avogadro number, and Avogadro constant can be expressed in the following equation:1\text = \frac = \frac The current SI value of the mole is based on the historical definition of the mole as the amount of substance that corresponds to the number of atoms in 12 grams of 12C, which made the molar mass of a compound in grams per mole, numerically equal to the average molecular mass or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peroxycarboxylic Acid
A peroxy acid (often spelled as one word, peroxyacid, and sometimes called peracid) is an acid which contains an acidic group. The two main classes are those derived from conventional mineral acids, especially sulfuric acid, and the peroxy derivatives of organic carboxylic acids. They are generally strong oxidizers. Inorganic peroxy acids Peroxymonosulfuric acid (Caro's acid) is probably the most important inorganic peracid, at least in terms of its production scale. It is used for the bleaching of pulp and for the detoxification of cyanide in the mining industry. It is produced by treating sulfuric acid with hydrogen peroxide. Peroxymonophosphoric acid () is prepared similarly. Some peroxy acids are only hypothetical, but their anions are known. This is the case for peroxycarbonate and perborate (see sodium perborate). Organic peracids Production Several organic peroxyacids are commercially useful. They can be prepared in several ways. Most commonly, peracids are g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detergent
A detergent is a surfactant or a mixture of surfactants with Cleanliness, cleansing properties when in Concentration, dilute Solution (chemistry), solutions. There are a large variety of detergents. A common family is the alkylbenzene sulfonates, which are soap-like compounds that are more soluble than soap in hard water, because the polar sulfonate is less likely than the polar carboxylate of soap to bind to calcium and other ions found in hard water. Definitions The word ''detergent'' is derived from the Latin adjective , from the verb , meaning to wipe or polish off. Detergent can be defined as a surfactant or a mixture of surfactants with cleansing properties when in Concentration, dilute Solution (chemistry), solutions. However, conventionally, detergent is used to mean synthetic cleaning compounds as opposed to ''soap'' (a salt of the natural fatty acid), even though soap is also a detergent in the true sense. In domestic contexts, the term ''detergent'' refers to househ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bleach
Bleach is the generic name for any chemical product that is used industrially or domestically to remove color from (i.e. to whiten) fabric or fiber (in a process called bleaching) or to disinfect after cleaning. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach". Many bleaches have broad-spectrum bactericidal properties, making them useful for disinfecting and sterilizing. They are used in swimming pool sanitation to control bacteria, viruses, and algae and in many places where sterile conditions are required. They are also used in many industrial processes, notably in the bleaching of wood pulp. Bleaches also have other minor uses, like removing mildew, killing weeds, and increasing the longevity of cut flowers. Bleaches work by reacting with many colored organic compounds, such as natural pigments, and turning them into colorless ones. While most bleaches are oxidizing agents (chemicals that can remove electrons from ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoclinic Crystal System
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below organizes the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lattice Parameter
A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal. A simple cubic crystal has only one lattice constant, the distance between atoms, but, in general, lattices in three dimensions have six lattice constants: the lengths ''a'', ''b'', and ''c'' of the three cell edges meeting at a vertex, and the angles ''α'', ''β'', and ''γ'' between those edges. The crystal lattice parameters ''a'', ''b'', and ''c'' have the dimension of length. The three numbers represent the size of the unit cell, that is, the distance from a given atom to an identical atom in the same position and orientation in a neighboring cell (except for very simple crystal structures, this will not necessarily be distance to the nearest neighbor). Their SI unit is the meter, and they are traditionally specified in angstroms (Å); an angstrom being 0.1 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Unit Cell
In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector In mathematics, a unit vector in a normed vector space is a Vector (mathematics and physics), vector (often a vector (geometry), spatial vector) of Norm (mathematics), length 1. A unit vector is often denoted by a lowercase letter with a circumfle ..., for example) does not necessarily have unit size, or even a particular size at all. Rather, the primitive cell is the closest analogy to a unit vector, since it has a determined size for a given lattice and is the basic building block from which larger cells are constructed. The concept is used particularly in describing crystal structure in two and three dimensions, though it makes sense in all dimensions. A lattice can be characterized by the geometry of its unit cell, which is a section of the tiling (a parallelogra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Perborate
Sodium perborate are chemical compounds with chemical formula (H2O)x. Commonly encountered salts are the anhydrous form (x = 0) and as a hydrate, hexahydrate (x = 6). These two species are sometimes called, respectively, "monohydrate" or PBS-1 and "tetrahydrate" or PBS-4, after the historic assumption that would be the anhydrous form). Both the anhydrous and hexahydrate salts are white, odorless, water-soluble solids. Peroxyborates are widely used in laundry detergents, as one of the peroxide-based bleaches. Sodium perborate was first obtained in 1898, independently, by Sebastian Tanatar and by P. Melikoff and L. Pissadewsky; the researchers prepared sodium perborate by treating sodium borate with a solution of hydrogen peroxide and sodium hydroxide, but Tanatar also obtained sodium perborate by electrolysis of a solution of sodium borate. Structure Unlike sodium percarbonate, the peroxyborates are not adducts of hydrogen peroxide. Rather, they contain a peroxyborate anion , ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetraacetylethylenediamine
Tetraacetylethylenediamine, commonly abbreviated as TAED, is an organic compound with the formula (CH3C(O))2NCH2CH2N(C(O)CH3)2. It is a white solid commonly used as a bleach activator in laundry detergents and in the production of paper pulp. TAED is synthesized through the acetylation of ethylenediamine. Use and mechanism of action TAED is an important component of laundry detergents that use "active oxygen" bleaching agents. Active oxygen bleaching agents include sodium perborate, sodium percarbonate, sodium perphosphate, sodium persulfate, and urea peroxide. These compounds release hydrogen peroxide during the wash cycle, but the release of hydrogen peroxide is low when these compounds are used in temperatures below . TAED and hydrogen peroxide react to form peroxyacetic acid, a more efficient bleach, allowing lower temperature wash cycles, around . TAED was first used in a commercial laundry detergent in 1978 ( Skip by Unilever). Currently, TAED is the main bleach ac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peroxyacetic Acid
Peracetic acid (also known as peroxyacetic acid, or Percidine) is an organic compound with the formula CH3CO3H. This peroxy acid is a colorless liquid with a characteristic acrid odor reminiscent of acetic acid. It can be highly corrosive. Peracetic acid is a weaker acid than the parent acetic acid, with a p''K''a of 8.2. Production Peracetic acid is produced industrially by the autoxidation of acetaldehyde: :O2 + CH3CHO → CH3CO3H Peracetic acid is conventionally prepared by combining acetic acid and hydrogen peroxide with homogeneous acid catalysts (e.g., sulfuric acid), which facilitate the reaction and achieve equilibrium between the reagents and product: :H2O2 + CH3CO2H CH3CO3H + H2O While it is feasible to create peracetic acid by combining consumer-grade vinegar (5% acetic acid) and hydrogen peroxide (3%) without an acid catalyst, the low concentration of reagents will result in a slow reaction rate at room temperature. Extrapolating from published reaction rates, th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Nonanoyloxybenzenesulfonate
Sodium nonanoyloxybenzenesulfonate (NOBS) is an important component of laundry detergents and bleaches. It is known as a bleach activator for active oxygen sources, allowing formulas containing hydrogen peroxide releasing chemicals (specifically sodium perborate, sodium percarbonate, sodium perphosphate, sodium persulfate, and urea peroxide) to effect bleaching at lower temperatures. Synthesis NOBS is formed by the reaction of nonanoic acid (or its esters) with phenol followed by aromatic sulfonation using SO3 to form a sulfonic acid at the para-position. Bleach activation NOBS was developed by Procter & Gamble The Procter & Gamble Company (P&G) is an American multinational consumer goods corporation headquartered in Cincinnati, Ohio. It was founded in 1837 by William Procter and James Gamble. It specializes in a wide range of personal health/con ... in 1983 and was first used in American laundry detergents in 1988. NOBS is the main bleach activator used in the U ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nonyl Compounds
Nonane is a linear alkane hydrocarbon with the chemical formula C9H20. It is a colorless, flammable liquid, occurring primarily in the component of the petroleum distillate fraction commonly called kerosene, which is used as a heating, tractor, and jet fuel. Nonane is also used as a solvent, distillation chaser, fuel additive, and a component in biodegradable detergents. It is also a minor component of diesel fuel. Nonane has 35 structural isomers. Its substituent form is nonyl. Its cycloalkane counterpart is cyclononane, (C9H18). Unlike most alkanes, the numeric prefix in its name is from Latin, not Greek. (A name using a Greek prefix would be enneane.) Combustion reactions Nonane undergoes combustion reactions that are similar to other alkanes. In the presence of sufficient oxygen, nonane burns to form water and carbon dioxide. : C9 H20 + 14 O2 → 9 CO2 + 10 H2O When insufficient oxygen is available for complete combustion, the burning products include carbon monoxide ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
