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Introduction To Quantum Mechanics
Quantum mechanics is the study of matter and its interactions with energy on the scale of atomic and subatomic particles. By contrast, classical physics explains matter and energy only on a scale familiar to human experience, including the behavior of astronomical bodies such as the moon. Classical physics is still used in much of modern science and technology. However, towards the end of the 19th century, scientists discovered phenomena in both the large ( macro) and the small ( micro) worlds that classical physics could not explain. The desire to resolve inconsistencies between observed phenomena and classical theory led to two major revolutions in physics that created a shift in the original scientific paradigm: the ''theory of relativity'' and the development of ''quantum mechanics''. This article describes how physicists discovered the limitations of classical physics and developed the main concepts of the quantum theory that replaced it in the early decades of the 20th ...
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Matter
In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic particles, and in everyday as well as scientific usage, "matter" generally includes atoms and anything made up of them, and any particles (or combination of particles) that act as if they have both rest mass and volume. However it does not include massless particles such as photons, or other energy phenomena or waves such as light or heat. Matter exists in various states (also known as phases). These include classical everyday phases such as solid, liquid, and gas – for example water exists as ice, liquid water, and gaseous steam – but other states are possible, including plasma, Bose–Einstein condensates, fermionic condensates, and quark–gluon plasma. Usually atoms can be imagined as a nucleus of protons and neutrons, and a ...
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Spectrum
A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors in visible light after passing through a prism. As scientific understanding of light advanced, it came to apply to the entire electromagnetic spectrum. It thereby became a mapping of a range of magnitudes (wavelengths) to a range of qualities, which are the perceived "colors of the rainbow" and other properties which correspond to wavelengths that lie outside of the visible light spectrum. Spectrum has since been applied by analogy to topics outside optics. Thus, one might talk about the " spectrum of political opinion", or the "spectrum of activity" of a drug, or the "autism spectrum". In these uses, values within a spectrum may not be associated with precisely quantifiable numbers or definitions. Such uses imply a broad range of condit ...
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Complementarity (physics)
In physics, complementarity is a conceptual aspect of quantum mechanics that Niels Bohr regarded as an essential feature of the theory. The complementarity principle holds that objects have certain pairs of complementary properties which cannot all be observed or measured simultaneously. An example of such a pair is position and momentum. Bohr considered one of the foundational truths of quantum mechanics to be the fact that setting up an experiment to measure one quantity of a pair, for instance the position of an electron, excludes the possibility of measuring the other, yet understanding both experiments is necessary to characterize the object under study. In Bohr's view, the behavior of atomic and subatomic objects cannot be separated from the measuring instruments that create the context in which the measured objects behave. Consequently, there is no "single picture" that unifies the results obtained in these different experimental contexts, and only the "totality of the phenom ...
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Measurement
Measurement is the quantification of attributes of an object or event, which can be used to compare with other objects or events. In other words, measurement is a process of determining how large or small a physical quantity is as compared to a basic reference quantity of the same kind. The scope and application of measurement are dependent on the context and discipline. In natural sciences and engineering, measurements do not apply to nominal properties of objects or events, which is consistent with the guidelines of the ''International vocabulary of metrology'' published by the International Bureau of Weights and Measures. However, in other fields such as statistics as well as the social and behavioural sciences, measurements can have multiple levels, which would include nominal, ordinal, interval and ratio scales. Measurement is a cornerstone of trade, science, technology and quantitative research in many disciplines. Historically, many measurement systems existed fo ...
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Uncertainty Principle
In quantum mechanics, the uncertainty principle (also known as Heisenberg's uncertainty principle) is any of a variety of mathematical inequalities asserting a fundamental limit to the accuracy with which the values for certain pairs of physical quantities of a particle, such as position, ''x'', and momentum, ''p'', can be predicted from initial conditions. Such variable pairs are known as complementary variables or canonically conjugate variables; and, depending on interpretation, the uncertainty principle limits to what extent such conjugate properties maintain their approximate meaning, as the mathematical framework of quantum physics does not support the notion of simultaneously well-defined conjugate properties expressed by a single value. The uncertainty principle implies that it is in general not possible to predict the value of a quantity with arbitrary certainty, even if all initial conditions are specified. Introduced first in 1927 by the German physicist Werner Hei ...
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Correspondence Principle
In physics, the correspondence principle states that the behavior of systems described by the theory of quantum mechanics (or by the old quantum theory) reproduces classical physics in the limit of large quantum numbers. In other words, it says that for large orbits and for large energies, quantum calculations must agree with classical calculations. The principle was formulated by Niels Bohr in 1920, though he had previously made use of it as early as 1913 in developing his model of the atom. The term codifies the idea that a new theory should reproduce under some conditions the results of older well-established theories in those domains where the old theories work. This concept is somewhat different from the requirement of a formal limit under which the new theory reduces to the older, thanks to the existence of a deformation parameter. Classical quantities appear in quantum mechanics in the form of expected values of observables, and as such the Ehrenfest theorem (whic ...
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Quantum Weirdness
Quantum weirdness encompasses the aspects of quantum mechanics that challenge and defy human physical intuition based on the Newtonian mechanics of classical physics. These aspects include: * quantum entanglement; * quantum nonlocality, referred to by Einstein as "spooky action at a distance"; see also EPR paradox; * quantum superposition, presented in dramatic form in the thought experiment known as Schrödinger's cat; * the uncertainty principle; * wave-particle duality; * the probabilistic nature of wave function collapse, decried by Einstein, saying, " God does not play dice". Many attempts have been made to construct an interpretation of quantum mechanics assigning a meaning to the laws of quantum mechanics in terms of an intuitively acceptable model. The so-called Copenhagen interpretation The Copenhagen interpretation is a collection of views about the meaning of quantum mechanics, principally attributed to Niels Bohr and Werner Heisenberg. It is one of the oldest of nu ...
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Ehrenfest's Theorem
The Ehrenfest theorem, named after Paul Ehrenfest, an Austrian theoretical physicist at Leiden University, relates the time derivative of the expectation values of the position and momentum operators ''x'' and ''p'' to the expectation value of the force F=-V'(x) on a massive particle moving in a scalar potential V(x), The Ehrenfest theorem is a special case of a more general relation between the expectation of any quantum mechanical operator and the expectation of the commutator of that operator with the Hamiltonian of the system where is some quantum mechanical operator and is its expectation value. It is most apparent in the Heisenberg picture of quantum mechanics, where it amounts to just the expectation value of the Heisenberg equation of motion. It provides mathematical support to the correspondence principle. The reason is that Ehrenfest's theorem is closely related to Liouville's theorem of Hamiltonian mechanics, which involves the Poisson bracket instead of a ...
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Richard Feynman
Richard Phillips Feynman (; May 11, 1918 – February 15, 1988) was an American theoretical physicist, known for his work in the path integral formulation of quantum mechanics, the theory of quantum electrodynamics, the physics of the superfluidity of supercooled liquid helium, as well as his work in particle physics for which he proposed the parton model. For contributions to the development of quantum electrodynamics, Feynman received the Nobel Prize in Physics in 1965 jointly with Julian Schwinger and Shin'ichirō Tomonaga. Feynman developed a widely used pictorial representation scheme for the mathematical expressions describing the behavior of subatomic particles, which later became known as Feynman diagrams. During his lifetime, Feynman became one of the best-known scientists in the world. In a 1999 poll of 130 leading physicists worldwide by the British journal ''Physics World'', he was ranked the seventh-greatest physicist of all time. He assisted in the developm ...
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Paradox
A paradox is a logically self-contradictory statement or a statement that runs contrary to one's expectation. It is a statement that, despite apparently valid reasoning from true premises, leads to a seemingly self-contradictory or a logically unacceptable conclusion. A paradox usually involves contradictory-yet-interrelated elements that exist simultaneously and persist over time. They result in "persistent contradiction between interdependent elements" leading to a lasting "unity of opposites". In logic, many paradoxes exist that are known to be invalid arguments, yet are nevertheless valuable in promoting critical thinking, while other paradoxes have revealed errors in definitions that were assumed to be rigorous, and have caused axioms of mathematics and logic to be re-examined. One example is Russell's paradox, which questions whether a "list of all lists that do not contain themselves" would include itself, and showed that attempts to found set theory on the identification ...
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Elementary Particles
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, antiquarks, and antileptons, which generally are matter particles and antimatter particles), as well as the fundamental bosons (gauge bosons and the Higgs boson), which generally are force particles that mediate interactions among fermions. A particle containing two or more elementary particles is a composite particle. Ordinary matter is composed of atoms, once presumed to be elementary particles – ''atomos'' meaning "unable to be cut" in Greek – although the atom's existence remained controversial until about 1905, as some leading physicists regarded molecules as mathematical illusions, and matter as ultimately composed of energy. Subatomic constituents of the atom were first identified in the early 1930s; the electron and the proton, alo ...
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Quantization (physics)
In physics, quantization (in British English quantisation) is the systematic transition procedure from a classical understanding of physical phenomena to a newer understanding known as quantum mechanics. It is a procedure for constructing quantum mechanics from classical mechanics. A generalization involving infinite degrees of freedom is field quantization, as in the "quantization of the electromagnetic field", referring to photons as field " quanta" (for instance as light quanta). This procedure is basic to theories of atomic physics, chemistry, particle physics, nuclear physics, condensed matter physics, and quantum optics. Historical overview In 1901, when Max Planck was developing the distribution function of statistical mechanics to solve ultraviolet catastrophe problem, he realized that the properties of blackbody radiation can be explained by the assumption that the amount of energy must be in countable fundamental units, i.e. amount of energy is not continuous ...
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