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Iron Oxide Cycle
For chemical reactions, the iron oxide cycle (Fe3O4/FeO) is the original two-step thermochemical cycle proposed for use for hydrogen production. It is based on the reduction and subsequent oxidation of iron ions, particularly the reduction and oxidation between Fe3+ and Fe2+. The ferrites, or iron oxide, begins in the form of a spinel and depending on the reaction conditions, dopant metals and support material forms either Wüstites or different spinels. Process description The thermochemical two-step water splitting process uses two redox steps. The steps of solar hydrogen production by iron based two-step cycle are: : \begin \ce &\ce \\ \ce & \ce \end Where M can by any number of metals, often Fe itself, Co, Ni, Mn, Zn or mixtures thereof. The endothermic reduction step (1) is carried out at high temperatures greater than , though the " Hercynite cycle" is capable of temperatures as low as . The oxidative water splitting step (2) occurs at a lower ~ temperature which prod ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hercynite
Hercynite is a spinel mineral with the formula FeAl2O4. It occurs in high-grade metamorphosed iron-rich argillaceous (clay-containing) sediments as well as in mafic and ultramafic igneous rocks. Due to its hardness it also is found in placers. It was first described in 1847 and its name originates from the Latin name for the Harz, Silva Hercynia, where the species was first found. Hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ferrous (Fe2+) ions and aluminium ions (Al3+); however some ferric ions (Fe3+) may be located in the structure of hercynite. Melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state of matter, state from solid to liquid. At the melting point the solid and liquid phase (matter), phase exist in Thermodynamic equilib ... of this mineral is inbetween . References Iron minerals Aluminium minerals Ox ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zinc Zinc-oxide Cycle
Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It is the second most abundant trace metal in humans after iron, an important ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hybrid Sulfur Cycle
The hybrid sulfur cycle (HyS) is a two-step water-splitting process intended to be used for hydrogen production. Based on sulfur oxidation and reduction, it is classified as a hybrid thermochemical cycle because it uses an electrochemical (instead of a thermochemical) reaction for one of the two steps. The remaining thermochemical step is shared with the sulfur-iodine cycle. The Hybrid sulphur cycle (HyS)was initially proposed and developed by Westinghouse Electric Corp. in the 1970s, so it is also known as the "Westinghouse" cycle. Current development efforts in the United States are being led by the Savannah River National Laboratory. Process description The two reactions in the HyS cycle are as follows: # H2SO4 → H2O + SO2 + ½ O2 (thermochemical, ''T'' > 800 °C) # SO2 + 2 H2O → H2SO4 + H2 (electrochemical, ''T'' = 80-120 °C) : : Net reaction: H2O → H2 + ½ O2 Sulfur dioxide acts to depolarize the anode of the electrolyzer. This resu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(IV) Oxide-cerium(III) Oxide Cycle
A ceria based thermochemical cycle is a type of Thermochemical cycle, two-step thermochemical cycle that uses as oxygen carrier cerium oxides (CeO_2/Ce_2O_3) for synthetic fuel production such as hydrogen or syngas. These cycles are able to obtain either hydrogen (H_2) from the splitting of water molecules (H_2O), or also syngas, which is a mixture of hydrogen (H_2) and carbon monoxide (CO), by also splitting carbon dioxide (CO_2) molecules alongside water molecules. These types of thermochemical cycles are mainly studied for Concentrated solar power, concentrated solar applications. Types of cycles These cycles are based on the two step redox thermochemical cycle. In the first step, a Oxides, metal oxide, such as Cerium(IV) oxide, ceria, is reduced by providing heat to the material, liberating oxygen. In the second step, a stream of steam oxidises the previously obtained molecule back to its starting state, therefore closing the cycle. Depending on the stoichiometry of the reactio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminum Oxide
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, ALOX or alundum in various forms and applications and alumina is refined from bauxite. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire,which have an alumina content approaching 100%. Al2O3 is used as feedstock to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point. Natural occurrence Corundum is the most common naturally occurring crystalline form of aluminium oxide. Rubies and sapphires are gem-quality forms of corundum, which owe their characteristic colours to trace impurities. Rubies are given their ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solar Thermal Energy
Solar thermal energy (STE) is a form of energy and a technology for harnessing solar energy to generate thermal energy for use in Industrial sector, industry, and in the residential and commercial sectors. Solar thermal collectors are classified by the United States Energy Information Administration as low-, medium-, or high-temperature collectors. Low-temperature collectors are generally unglazed and used to heat swimming pools or to heat ventilation air. Medium-temperature collectors are also usually flat plates but are used for heating water or air for residential and commercial use. High-temperature collectors concentrate sunlight using mirrors or Lens (optics), lenses and are generally used for fulfilling heat requirements up to () / 20 Bar (unit), bar (300 psi) pressure in industries, and for electric power production. Two categories include Concentrated Solar Thermal (CST) for fulfilling heat requirements in industries, and concentrated solar power (CSP) when th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heliostat
A heliostat () is a device that reflects sunlight toward a target, turning to compensate for the Sun's apparent motion. The reflector is usually a plane mirror. The target may be a physical object, distant from the heliostat, or a direction in space. To do this, the reflective surface of the mirror is kept perpendicular to the bisector of the angle between the directions of the Sun and the target as seen from the mirror. In almost every case, the target is stationary relative to the heliostat, so the light is reflected in a fixed direction. According to contemporary sources the heliostata, as it was called at first, was invented by Willem 's Gravesande (1688–1742). Other contenders are Giovanni Alfonso Borelli (1608–1679) and Daniel Gabriel Fahrenheit (1686–1736). A heliostat designed by George Johnstone Storey is in the Science Museum Group collection. Currently, most heliostats are used for daylighting or for the production of concentrated solar power, us ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solar Power Tower
A solar power tower, also known as 'central tower' power plant or 'heliostat' power plant, is a type of solar furnace using a tower to receive focused sunlight. It uses an array of flat, movable mirrors (called heliostats) to focus the sun's rays upon a collector tower (the target). Concentrating Solar Power (CSP) systems are seen as one viable solution for renewable, pollution-free energy. Early designs used these focused rays to heat water and used the resulting steam to power a turbine. Newer designs using liquid sodium have been demonstrated, and systems using molten salts (40% potassium nitrate, 60% sodium nitrate) as the working fluids are now in operation. These working fluids have high heat capacity, which can be used to store the energy before using it to boil water to drive turbines. Storing the heat energy for later recovery allows power to be generated continuously, while the sun is shining, and for several hours after the sun has set (or been clouded over). Cost ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
