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Iodic Acid
Iodic acid is a white water-soluble solid with the chemical formula . Its robustness contrasts with the instability of chloric acid and bromic acid. Iodic acid features iodine in the oxidation state +5 and is one of the most stable oxo-acids of the halogens. When heated, samples dehydrate to give iodine pentoxide. On further heating, the iodine pentoxide further decomposes, giving a mix of iodine, oxygen and lower oxides of iodine. Preparation Iodic acid can be produced by oxidizing iodine with strong oxidizers such as nitric acid, chlorine, chloric acid or hydrogen peroxide, for example: : Iodic acid is also produced by the reaction of iodine monochloride with water: : Structure Iodic acid crystallises from acidic solution as orthorhombic α- in space group ''P''212121. The structure consists of pyramidal molecules linked by hydrogen bonding and intermolecular iodine-oxygen interactions. The I=O bond lengths are 1.81 Å while the I–OH distance is 1.89 Å. Several othe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodate
An iodate is the polyatomic anion with the formula . It is the most common form of iodine in nature, as it comprises the major iodine-containing ores. Iodate salts are often colorless. They are the salts of iodic acid. Structure Iodate is pyramidal in structure. The O–I–O angles range from 97° to 105°, somewhat smaller than the O–Cl–O angles in chlorate. Reactions Redox Iodate is one of several oxyanions of iodine, and has an oxidation number of +5. It participates in several redox reactions, such as the iodine clock reaction. Iodate shows no tendency to disproportionate to periodate and iodide, in contrast to the situation for chlorate. Iodate is reduced by sulfite: : Iodate oxidizes iodide in acidic conditions: : Similarly, chlorate oxidizes iodide to iodate: : Iodate is also obtained by reducing a periodate with a sulfide. The byproduct of the reaction is a sulfoxide. Acid-base Iodate is unusual in that it forms a strong hydrogen bond with its parent ac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halogens
The halogens () are a group (periodic table), group in the periodic table consisting of six chemically related chemical element, elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and tennessine (Ts), though some authors would exclude tennessine as its chemistry is unknown and is theoretically expected to be more like that of gallium. In the modern IUPAC nomenclature, this group is known as group 17. The word "halogen" means "salt former" or "salt maker". When halogens react with metals, they produce a wide range of Salt (chemistry), salts, including calcium fluoride, sodium chloride (common table salt), silver bromide and potassium iodide. The group of halogens is the only Group (periodic table), periodic table group that contains elements in three of the main State of matter, states of matter at standard temperature and pressure, though not far above room temperature the same becomes true of groups alkali metals, 1 and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zeitschrift Für Anorganische Und Allgemeine Chemie
The ''Zeitschrift für anorganische und allgemeine Chemie'' (''Journal of Inorganic and General Chemistry'') is a semimonthly peer-reviewed scientific journal covering inorganic chemistry, published by Wiley-VCH. The editors-in-chief are Thomas F. Fässler, Christian Limberg, Guodong Qian, and David Scheschkewitz. Originally the journal was published in German, but nowadays it is completely in English. Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2022 impact factor of 1.4. History In 1892, Gerhard Krüss (Ludwig Maximilian University of Munich), established the journal under the name ''Zeitschrift für Anorganische Chemie''. Krüss died three years later, and was succeeded by Richard Lorenz and Walther Nernst Walther Hermann Nernst (; 25 June 1864 – 18 November 1941) was a German physical chemist known for his work in thermodynamics, physical chemistry, electrochemistry, and solid-sta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acta Chemica Scandinavica
''Acta Chemica Scandinavica'' was a peer-reviewed Nordic scientific journal in the fields of chemistry. The journal was established in 1947 and was jointly managed during 53 years from beginning of 1947 until end of 1999 by the chemical societies in Denmark ( The Danish Chemical Society), Finland ( Finnish Chemical Societies), Norway ( The Norwegian Chemical Society) and Sweden ( The Swedish Chemical Society). The journal was jointly owned by the four chemical societies through ''the Publishing Association Acta Chemica Scandinavica''. The Swedish Chemical Society managed the administration of the Publishing Association at their Secretariat in Stockholm. When making citations or references to articles in ''Acta Chemica Scandinavica'' the abbreviation ''Acta Chem. Scand.'' is used. Background During the turbulent years after World War II, it was difficult for Nordic scientists to publish results from fundamental chemical research in magazines with international recognition. The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of The American Chemical Society
The ''Journal of the American Chemical Society'' (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. The journal has absorbed two other publications in its history, the ''Journal of Analytical and Applied Chemistry'' (July 1893) and the ''American Chemical Journal'' (January 1914). It covers all fields of chemistry. Since 2021, the editor-in-chief is Erick M. Carreira (ETH Zurich). In 2014, the journal moved to a hybrid open access publishing model. Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2023 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a type of journal ranking. Journals with higher impact factor values are considered more prestigious or important within their field. The Impact Factor of a journa ... of 14.4. Editors-in-chief The following people are or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bond Length
In molecular geometry, bond length or bond distance is defined as the average distance between Atomic nucleus, nuclei of two chemical bond, bonded atoms in a molecule. It is a Transferability (chemistry), transferable property of a bond between atoms of fixed types, relatively independent of the rest of the molecule. Explanation Bond length is related to bond order: when more electrons participate in bond formation the bond is shorter. Bond length is also inversely related to bond strength and the bond dissociation energy: all other factors being equal, a stronger bond will be shorter. In a bond between two identical atoms, half the bond distance is equal to the covalent radius. Bond lengths are measured in the solid phase by means of X-ray diffraction, or approximated in the gas phase by microwave spectroscopy. A bond between a given pair of atoms may vary between different molecules. For example, the carbon to hydrogen bonds in methane are different from those in methyl chlori ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Bonding
In chemistry, a hydrogen bond (H-bond) is a specific type of molecular interaction that exhibits partial covalent character and cannot be described as a purely electrostatic force. It occurs when a hydrogen (H) atom, Covalent bond, covalently bonded to a more Electronegativity, electronegative donor atom or group (Dn), interacts with another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Unlike simple Dipole–dipole attraction, dipole–dipole interactions, hydrogen bonding arises from charge transfer (nB → σ*AH), Atomic orbital, orbital interactions, and quantum mechanical Delocalized electron, delocalization, making it a resonance-assisted interaction rather than a mere electrostatic attraction. The general notation for hydrogen bonding is Dn−H···Ac, where the solid line represents a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. The most frequent donor and acceptor atoms are nitrogen (N), oxyg ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
List Of Space Groups
There are 230 space groups in three dimensions, given by a number index, and a full name in Hermann–Mauguin notation, and a short name (international short symbol). The long names are given with spaces for readability. The groups each have a point group of the unit cell. Symbols In Hermann–Mauguin notation, space groups are named by a symbol combining the point group identifier with the uppercase letters describing the lattice type. Translations within the lattice in the form of screw axes and glide planes are also noted, giving a complete crystallographic space group. These are the Bravais lattices in three dimensions: *P primitive *I body centered (from the German ''Innenzentriert'') *F face centered (from the German ''Flächenzentriert'') *A centered on A faces only *B centered on B faces only *C centered on C faces only *R rhombohedral A reflection plane m within the point groups can be replaced by a glide plane, labeled as a, b, or c depending on which axis the glide i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Orthorhombic Crystal System
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal In mathematics, orthogonality (mathematics), orthogonality is the generalization of the geometric notion of ''perpendicularity''. Although many authors use the two terms ''perpendicular'' and ''orthogonal'' interchangeably, the term ''perpendic .... Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , ro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodine Monochloride
Iodine monochloride is an interhalogen compound with the formula . It is a red-brown chemical compound that melts near room temperature. Because of the difference in the electronegativity of iodine and chlorine, this molecule is highly polar and behaves as a source of I+. Discovered in 1814 by Gay-Lussac, iodine monochloride is the first interhalogen compound discovered. Preparation Iodine monochloride is produced simply by combining the halogens in a 1:1 molar ratio, according to the equation : When chlorine gas is passed through iodine crystals, one observes the brown vapor of iodine monochloride. Dark brown iodine monochloride liquid is collected. Excess chlorine converts iodine monochloride into iodine trichloride in a reversible reaction: : Polymorphs has two polymorphs; α-ICl, which exists as black needles (red by transmitted light) with a melting point of 27.2 °C, and β-ICl, which exists as black platelets (red-brown by transmitted light) with a melt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitric Acid
Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as synthetic dyes and medicines (e.g. metronidazole). Nitric acid is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
