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Fertilizer Bomb
ANFO ( ) (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number 2 fuel oil (FO). The use of ANFO originated in the 1950s. ANFO accounts for an estimated 90% of the of explosives used annually in North America. It has found wide use in coal mining, quarrying, metal mining, and civil construction in applications where its low cost and ease of use may outweigh the benefits of other explosives, such as water resistance, oxygen balance, higher detonation velocity, or performance in small-diameter columns. ANFO is also widely used in avalanche hazard mitigation. Chemistry The chemistry of ANFO detonation is the reaction of ammonium nitrate with a long-chain alkane (CnH2n+2) to form nitrogen, carbon dioxide, and water. In an ideal stoichiometrically balanced reaction, ANFO is composed of about 94.5% AN and 5. ...
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Ammonium Nitrate-fuel Oil (ANFO) Explosive
The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by organic groups (indicated by R). Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted acids (proton donors): :H+ + NH3 -> H4 The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: : H4 + B- -> HB + NH3 Thus, treatment of concentrated solutions of ammonium salts with strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: :H2O + NH3 OH- + H4 The degree to which ammonia forms the ammonium ion depends on the pH of the solution. If the pH is low, the equilibrium shifts to the right: more ammonia molecules are conve ...
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Kerosene
Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning " wax", and was registered as a trademark by Canadian geologist and inventor Abraham Gesner in 1854 before evolving into a generic trademark. It is sometimes spelled kerosine in scientific and industrial usage. The term kerosene is common in much of Argentina, Australia, Canada, India, New Zealand, Nigeria, and the United States, while the term paraffin (or a closely related variant) is used in Chile, eastern Africa, South Africa, Norway, and in the United Kingdom. The term lamp oil, or the equivalent in the local languages, is common in the majority of Asia and the Southeastern United States. Liquid paraffin (called mineral oil in the US) is a more viscous and highly refined product which is used as a laxative. Paraffin wax is a waxy solid extracted from ...
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Deflagration
Deflagration (Lat: ''de + flagrare'', "to burn down") is subsonic combustion in which a pre-mixed flame propagates through a mixture of fuel and oxidizer. Deflagrations can only occur in pre-mixed fuels. Most fires found in daily life are diffusion flames. Deflagrations with flame speeds in the range of 1 m/sec differ from detonations which propagate supersonically through shock waves with speeds in the range of 1 km/sec. Applications Deflagrations are often used in engineering applications when the goal is to move an object such as a bullet in a firearm, or a piston in an internal combustion engine with the force of the expanding gas. Deflagration systems and products can also be used in mining, demolition and stone quarrying via gas pressure blasting as a beneficial alternative to high explosives. Flame physics The underlying flame physics can be understood with the help of an idealized model consisting of a uniform one-dimensional tube of unburnt and burned gaseous fuel, ...
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Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. The detonation velocity , velocity of detonation in solid and liquid explosives is much higher than that in gaseous ones, which allows the wave system to be observed with greater detail (higher Image resolution , resolution). A very wide variety of fuels may occur as gases (e.g. hydrogen), droplet fogs, or dust suspensions. In addition to dioxygen, oxidants can include halogen compounds, ozone, hydrogen peroxide and Nitrogen oxide , oxides of nitrogen. Gaseous detonations are often associated with a mixture of fuel and oxidan ...
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High Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Exp ...
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PETN
Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythritol, and is structurally very similar to nitroglycerin. Penta refers to the five carbon atoms of the neopentane skeleton. PETN is a very powerful explosive material with a relative effectiveness factor of 1.66. When mixed with a plasticizer, PETN forms a plastic explosive. Along with RDX it is the main ingredient of Semtex. PETN is also used as a vasodilator drug to treat certain heart conditions, such as for management of angina. History Pentaerythritol tetranitrate was first prepared and patented in 1894 by the explosives manufacturer Rheinisch-Westfälische Sprengstoff A.G. of Cologne, Germany. The production of PETN started in 1912, when the improved method of production was patented by the German government. PETN was used by the Ge ...
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Pentolite
Pentolite is a composite high explosive used for military and civilian purposes, e.g., warheads and booster charges. It is made of pentaerythritol tetranitrate (PETN) phlegmatized with trinitrotoluene (TNT) by melt casting.B. M. Dobratz & P. C. Crawford, ''LLNL Explosives Handbook'', Lawrence Livermore National Laboratory, UCRL-52997, Change 2, January 31, 1985. The most common military variety of pentolite (designated "Pentolite 50/50") is a mixture of 50% PETN and 50% TNT. (Unlike other compound explosives, the number before the slash is the mass percentage of TNT and the second number is the mass percentage of PETN). This 50:50 mixture has a density of 1.65 g/cm3 and a detonation velocity of 7400 m/s. Civilian pentolite sometimes contains a lower percentage of PETN, usually around 2% ("Pentolite 98/2"), 5% ("Pentolite 95/5") or 10% ("Pentolite 90/10"). Civilian pentolites have a detonation velocity Explosive velocity, also known as detonation velocity or velocity of ...
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Cast Booster
{{unreferenced, date=August 2011 An explosive booster is a sensitive explosive charge that acts as a bridge between a (relatively weak) conventional detonator and a low-sensitivity (but typically high-energy) explosive such as TNT. By itself, the initiating detonator would not deliver sufficient energy to set off the low-sensitivity charge. However, it detonates the primary charge (the booster), which then delivers an explosive shockwave that is sufficient to detonate the secondary, main, high-energy charge. Unlike C4 plastic explosive, not all explosives can be detonated simply by inserting a detonator and firing it. An initiator such as a shock tube, cannon fuse, or even a conventional detonator does not deliver sufficient shock to detonate charges comprising TNT, Composition B, ANFO and many other high explosives. Therefore, some form of "booster" is required to amplify the energy released by the detonator so that the main charge will detonate. At first, picric acid was u ...
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Tovex
Tovex (also known as Trenchrite, Seismogel, and Seismopac) is a water-gel explosive composed of ammonium nitrate and methylammonium nitrate that has several advantages over traditional dynamite, including lower toxicity and safer manufacture, transport, and storage. It has thus almost entirely replaced dynamite. There are numerous versions ranging from shearing charges to aluminized common blasting agents. Tovex is used by 80% of international oil companies for seismic exploration. History The Tovex family of products, sometimes generically called "water gels," were developed by the Explosives Department at DuPont (E.I. du Pont de Nemours & Company, Inc.) in the mid-to-late 1960s when pelletized TNT was included in aqueous gels to create a slurry form of ANFO that displayed water-resistant properties in wet bore holes. TNT-sensitized water gels were commercially successful, but the TNT led to problems with oxygen balance: namely elevated amounts of combustion by-products such as ...
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Dynamite
Dynamite is an explosive made of nitroglycerin, sorbents (such as powdered shells or clay), and stabilizers. It was invented by the Swedish chemist and engineer Alfred Nobel in Geesthacht, Northern Germany, and patented in 1867. It rapidly gained wide-scale use as a more robust alternative to black powder. History Dynamite was invented by Swedish chemist Alfred Nobel in the 1860s and was the first safely manageable explosive stronger than black powder. Alfred Nobel's father, Immanuel Nobel, was an industrialist, engineer, and inventor. He built bridges and buildings in Stockholm and founded Sweden's first rubber factory. His construction work inspired him to research new methods of blasting rock that were more effective than black powder. After some bad business deals in Sweden, in 1838 Immanuel moved his family to Saint Petersburg, where Alfred and his brothers were educated privately under Swedish and Russian tutors. At age 17, Alfred was sent abroad for two year ...
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Explosive Booster
{{unreferenced, date=August 2011 An explosive booster is a sensitive explosive charge that acts as a bridge between a (relatively weak) conventional detonator and a low-sensitivity (but typically high-energy) explosive such as TNT. By itself, the initiating detonator would not deliver sufficient energy to set off the low-sensitivity charge. However, it detonates the primary charge (the booster), which then delivers an explosive shockwave that is sufficient to detonate the secondary, main, high-energy charge. Unlike C4 plastic explosive, not all explosives can be detonated simply by inserting a detonator and firing it. An initiator such as a shock tube, cannon fuse, or even a conventional detonator does not deliver sufficient shock to detonate charges comprising TNT, Composition B, ANFO and many other high explosives. Therefore, some form of "booster" is required to amplify the energy released by the detonator so that the main charge will detonate. At first, picric acid was u ...
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Detonator
A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common. The commercial use of explosives uses electrical detonators or the capped fuse which is a length of safety fuse to which an ordinary detonator has been joined. Many detonators' primary explosive is a material called ASA compound. This compound is formed from lead azide, lead styphnate and aluminium and is pressed into place above the base charge, usually TNT or tetryl in military detonators and PETN in commercial detonators. Other materials such as DDNP (diazo dinitro phenol) are also used as the primary charge to reduce the amount of lead emitted into the atmosphere by mining and quarrying operations. Old detonators used mercury fulminate as the primary, often mixed with potassium chlorate to yield better performance. A blasting cap is a small sensitive primary explosive dev ...
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