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Electrochromism
Electrochromism is a phenomenon in which a material displays changes in color or Opacity (optics), opacity in response to an voltage, electrical stimulus. In this way, a smart window made of an electrochromic material can block specific wavelengths of ultraviolet, visible light, visible or (near) infrared light. The ability to control the transmittance of near-infrared light can increase the efficient energy use, energy efficiency of a building, reducing the amount of energy needed to cool during summer and heat during winter. As the color change is persistent and energy needs only to be applied to effect a change, electrochromic materials are used to control the amount of light and heat allowed to pass through a surface, most commonly "smart windows". One popular application is in the automobile Industry (economics), industry where it is used to automatically Window film, tint rear-view mirrors in various lighting conditions. Principle The phenomenon of electrochromism occurs ...
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PEDOT
Poly(3,4-ethylenedioxythiophene) (PEDOT or PEDT; ''IUPAC'' name poly(2,3-dihydrothieno[3,4-''b''][1,4]dioxane-5,7-diyl)) is a conducting polymer based on 3,4-Ethylenedioxythiophene, 3,4-ethylenedioxythiophene or EDOT. It was first reported by Bayer AG in 1989. Polymer PEDOT possesses many advantageous properties compared to earlier conducting polythiophenes like Polythiophene#3-Alkylthiophenes, 3-alkylthiophenes. For example, the polymer is Transparency (optics), optically transparent in its electrical conduction, conducting state and has high stability, moderate band gap, and low oxidation potential, redox potential. Its major disadvantage is its poor solubility, which is partly circumvented by use of composite materials such as PEDOT:PSS and PEDOT-TMA. The polymer is generated by oxidation. The process begins with production of the radical cation of EDOT monomer, [C2H4O2C4H2S]+. This cation adds to a neutral EDOT followed by deprotonation. The idealized conversion using perox ...
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Smart Window
Smart glass, also known as switchable glass, dynamic glass, and smart-tinting glass, is a type of glass that can change its optical properties, becoming opaque or tinted, in response to electrical or thermal signals. This can be used to prevent sunlight and heat from entering a building during hot days, improving energy efficiency. It can also be used to conveniently provide privacy or visibility to a room. There are two primary classifications of smart glass: active or passive. The most common active glass technologies used today are electrochromic, liquid crystal, and suspended particle devices (SPD). Thermochromic and photochromic are classified as passive technologies. When installed in the envelope of buildings, smart glass helps to create climate adaptive building shells, which benefits include things such as natural light adjustment, visual comfort, UV and infrared blocking, reduced energy use, thermal comfort, resistance to extreme weather conditions, and privacy. Some ...
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Gentex (automotive Manufacturer)
Gentex Corporation is an American electronics and technology company that develops, designs, and manufactures automatic-dimming rear-view mirrors, camera-based driver assistance systems, and other equipment for the automotive industry. They produce dimmable aircraft windows for the commercial, business and general aviation markets. In addition, the company produces photoelectric smoke detectors, signaling devices, and the HomeLink Wireless Control System for the North American fire protection market. Founded in 1974, Gentex Corporation is based in Zeeland, Michigan. They created the first dual-sensor photoelectric smoke detector, and pioneered electrochromic automatic-dimming mirrors for the automotive industry and smart windows for the aviation industry. Gentex has more than 1,700 patents on various technologies and products. In analyses of the industry in 2001, Gentex had the highest market-to-book value of any automotive supplier. As of 2020, about 98 percent of the compan ...
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Rear-view Mirror
A rear-view mirror (or rearview mirror) is a, usually plane mirror, flat, mirror in automobiles and other vehicles, designed to allow the driver to see rearward through the vehicle's rear window (rear windshield). In cars, the rear-view mirror is usually affixed to the top of the windshield on a double-swivel mount allowing it to be adjusted to suit the height and viewing angle of any driver and to swing harmlessly out of the way if impacted by a vehicle occupant in a Traffic collision, collision. The rear-view mirror is augmented by one or more Wing mirror, side-view mirrors, which serve as the only rear-vision mirrors on trucks, motorcycles and bicycles. History Early use of fixed mirrors was described as early as 1906, with a trade magazine noting mirrors for showing what is coming behind were now popular on closed bodied automobiles, and were likely to be widely adopted in a short time. The same year, a Mr. Bilal Ghanty from France patented a "''Warning mirror for au ...
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Tungsten Trioxide
Tungsten(VI) oxide, also known as tungsten trioxide is a chemical compound of oxygen and the transition metal tungsten, with formula WO3. The compound is also called tungstic anhydride, reflecting its relation to tungstic acid . It is a light yellow crystalline solid. Tungsten(VI) oxide occurs naturally in the form of hydrates, which include minerals: tungstite WO3·H2O, meymacite WO3·2H2O and hydrotungstite (of the same composition as meymacite, however sometimes written as H2WO4). These minerals are rare to very rare secondary tungsten minerals. History In 1841, a chemist named Robert Oxland gave the first procedures for preparing tungsten trioxide and sodium tungstate. He was granted patents for his work soon after, and is considered to be the founder of systematic tungsten chemistry. Structure and properties The crystal structure of tungsten trioxide is temperature dependent. It is tetragonal at temperatures above 740 °C, orthorhombic from 330 to 740 °C ...
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Polypyrrole
Polypyrrole (PPy) is an organic polymer obtained by oxidative polymerization of pyrrole. It is a solid with the formula H(C4H2NH)nH. It is an intrinsically conducting polymer, used in electronics, optical, biological and medical fields. History Some of the first examples of PPy were reported in 1919 by Angeli and Pieroni, who reported the formation of pyrrole blacks from pyrrole magnesium bromide. Since then pyrrole oxidation reaction has been studied and reported in scientific literature. Work on conductive polymers including polypyrrole, polythiophene, polyaniline, and polyacetylene was awarded the Nobel Prize in Chemistry in 2000 to Alan J. Heeger, Alan G. MacDiarmid and Hideki Shirakawa . Synthesis Different methods can be used to synthesize PPy, but the most common are electrochemical synthesis and chemical oxidation. Chemical oxidation of pyrrole: :n C4H4NH + 2n FeCl3 → (C4H2NH)n + 2n FeCl2 + 2n HCl The process is thought to occur via the formation of the ...
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Titanium Dioxide
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound derived from titanium with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or Colour Index International, CI 77891. It is a white solid that is insoluble in water, although mineral forms can appear black. As a pigment, it has a wide range of applications, including paint, sunscreen, and food coloring. When used as a food coloring, it has E number E171. World production in 2014 exceeded 9 million tonnes. It has been estimated that titanium dioxide is used in two-thirds of all pigments, and pigments based on the oxide have been valued at a price of $13.2 billion. Structure In all three of its main dioxides, titanium exhibits Octahedral molecular geometry, octahedral geometry, being bonded to six oxide anions. The oxides in turn are bonded to three Ti centers. The overall crystal structures of rutile and anatase are tetragonal in symmetry ...
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Viologen
Viologens are organic compounds with the formula (C5H4NR)2n+. In some viologens, the pyridyl groups are further modified. Viologens are called so, because these compounds produce violet color on reduction [violet + Latin ''gen'', generator of]. The viologen paraquat (R = methyl), is a widely used herbicide. As early as in the 1930s, paraquat was being used as an oxidation-reduction indicator, because it becomes violet on reduction. Other viologens have been commercialized because they can change color reversibly many times through Redox, reduction and oxidation. The name viologen alludes to violet, one color it can exhibit, and the radical ion, radical cation (C5H4NR)2+ is colored intensely blue. Types of viologens As bipyridinium derivatives, the viologens are related to 4,4'-bipyridyl. The basic nitrogen centers in these compounds are alkylated to give viologens: :(C5H4N)2 + 2 RX → [(C5H4NR)2]2+(X−)2 The alkylation is a form of quaternization. When the alkylati ...
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Organic Materials
Organic matter, organic material or natural organic matter is the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have come from the feces and remains of organisms such as plants and animals. Organic molecules can also be made by chemical reactions that do not involve life. Basic structures are created from cellulose, tannin, cutin, and lignin, along with other various proteins, lipids, and carbohydrates. Organic matter is very important in the movement of nutrients in the environment and plays a role in water retention on the surface of the planet. Formation Living organisms are composed of organic compounds. In life, they secrete or excrete organic material into their environment, shed body parts such as leaves and roots and after organisms die, their bodies are broken down by bacterial and fungal action. Larger molecules of organic matter can be formed from th ...
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Viologens
Viologens are organic compounds with the formula (C5H4NR)2n+. In some viologens, the pyridyl groups are further modified. Viologens are called so, because these compounds produce violet color on reduction iolet + Latin ''gen'', generator of The viologen paraquat (R = methyl), is a widely used herbicide. As early as in the 1930s, paraquat was being used as an oxidation-reduction indicator, because it becomes violet on reduction. Other viologens have been commercialized because they can change color reversibly many times through reduction and oxidation. The name viologen alludes to violet, one color it can exhibit, and the radical cation (C5H4NR)2+ is colored intensely blue. Types of viologens As bipyridinium derivatives, the viologens are related to 4,4'-bipyridyl. The basic nitrogen centers in these compounds are alkylated to give viologens: :(C5H4N)2 + 2 RX → C5H4NR)2sup>2+(X−)2 The alkylation is a form of quaternization. When the alkylating agent is a small ...
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Niobium
Niobium is a chemical element; it has chemical symbol, symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and Ductility, ductile transition metal. Pure niobium has a Mohs scale of mineral hardness, Mohs hardness rating similar to pure titanium, and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere very slowly, hence its application in jewelry as a hypoallergenic alternative to nickel. Niobium is often found in the minerals pyrochlore and columbite. Its name comes from Greek mythology: Niobe, daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, which makes them difficult to distinguish. English chemist Charles Hatchett reported a new element similar to tantalum in 1801 and named it columbium. In 1809, English chemist William Hyde Wollaston wrongly concluded that tantalum and columbium were identical. German chemist He ...
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Titanium
Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine. Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide (TiO2), is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and cata ...
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