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Elastane
Spandex, Lycra, or elastane is a synthetic fiber known for its exceptional elasticity. It is a polyether- polyurea copolymer that was invented in 1958 by chemist Joseph Shivers at DuPont. Name The name ''spandex'', which is an anagram of the word "expands", is the preferred name in North America. In continental Europe, it is referred to by variants of ''elastane''. It is primarily known as ''Lycra'' in the UK, Ireland, Portugal, Spain, Latin America, Australia, and New Zealand. Brand names for spandex include Lycra (made by The Lycra Company, previously a division of DuPont Textiles and Interiors), Elaspan (The Lycra Company), Acepora ( Taekwang Group), Creora (Hyosung), INVIYA ( Indorama Corporation), ROICA and Dorlastan (Asahi Kasei), Linel (Fillattice), and ESPA (Toyobo). Production Unlike many other synthetic fibers, spandex cannot be melt-processed because the polymer degrades upon melting. Spandex fibers are produced by several spinning technologies. Typically, ...
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Cycling Kit Full Body Alt 3 (cropped)
Cycling, also known as bicycling or biking, is the activity of riding a bicycle or other types of pedal-driven human-powered vehicles such as balance bikes, unicycles, tricycles, and quadricycles. Cycling is practised around the world for purposes including transport, recreation, exercise, and competitive sport. History Cycling became popularized in Europe and North America in the latter part and especially the last decade of the 19th century. Today, over 50 percent of the human population knows how to ride a bike. War The bicycle has been used as a method of reconnaissance as well as transporting soldiers and supplies to combat zones. In this it has taken over many of the functions of horses in warfare. In the Second Boer War, both sides used bicycles for scouting. In World War I, France, Germany, Australia and New Zealand used bicycles to move troops. In its 1937 invasion of China, Japan employed some 50,000 bicycle troops, and similar forces were instrumental in Japan' ...
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Toyobo
is one of Japan's top makers of fibers and textiles, including synthetic fibers (polyester, nylon and acrylics) and natural fibers, such as cotton and wool. History Toyobo was established in 1882 by Eiichi Shibusawa as a cotton-spinning company in a context of post-Meiji Restoration. By the 1930s, Toyobo was the world's largest cotton-spinning company. In the 1960s, the company started to manufacture synthetic fibers and films. In August 2013, Toyobo bought the Spanish company Spinreact for 22.3 million euros. In 2015, Toyobo provided 40% of the yarn for airbags worldwide, and 50% of Japan's food packaging films. In March 2017, Toyobo introduced Cocomi, a t-shirt that tracks a driver's heartbeats and activates an alarm if somnolence is detected. In August 2017, Toyobo established a new group in Europe, Toyobo Chemicals Europe GmbH, with a focus on marketing specialty chemical products, and a new manufacturing base for airbag fabrics. In March 2018, Toyobo paid $66 millio ...
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Cotton
Cotton (), first recorded in ancient India, is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor percentages of waxes, fats, pectins, and water. Under natural conditions, the cotton bolls will increase the dispersal of the seeds. The plant is a shrub native to tropical and subtropical regions around the world, including the Americas, Africa, Egypt and India. The greatest diversity of wild cotton species is found in Mexico, followed by Australia and Africa. Cotton was independently domesticated in the Old and New Worlds. The fiber is most often spun into yarn or thread and used to make a soft, breathable, and durable textile. The use of cotton for fabric is known to date to prehistoric times; fragments of cotton fabric dated to the fifth millennium BC have been found in the Indus Valley civilizat ...
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Skin-tight Garment
A skin-tight garment is a garment that is held to the skin usually by elasticity (solid mechanics), elastic tension using some type of stretch fabric. Commercial stretch fabrics ('elastomerics') such as spandex or elastane (widely branded as 'Lycra') came onto the market in 1962, and revolutionized many areas of the clothing industry. A wide variety of clothing may be made to be skin-tight, and it is common for clothing to be skin-tight for some uses, such as in stockings, bodystockings, swimsuits and women's brassiere, bras. History and types Leotard In 1886, the name leotard was given to a one-piece skin-tight garment that covers the torso including the crotch, but not the legs or arms. The garment was named after French acrobatic performer Jules Léotard (1838–1870), many years after his death, who wore the garment in his acrobatic act. In the early 20th century, use of leotards was mainly confined to circus and acrobatic shows, but were also worn by professional dancers, su ...
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Mechanoreceptor
A mechanoreceptor, also called mechanoceptor, is a sensory receptor that responds to mechanical pressure or distortion. Mechanoreceptors are located on sensory neurons that convert mechanical pressure into action potential, electrical signals that, in animals, are sent to the central nervous system. Vertebrate mechanoreceptors Cutaneous mechanoreceptors Cutaneous mechanoreceptors respond to mechanical stimuli that result from physical interaction, including pressure and vibration. They are located in the skin, like other cutaneous receptors. They are all innervated by Aβ fibers, except the mechanorecepting free nerve endings, which are innervated by A delta fiber, Aδ fibers. Cutaneous mechanoreceptors can be categorized by what kind of sensation they perceive, by the rate of adaptation, and by morphology. Furthermore, each has a different receptive field. By sensation * The Slowly Adapting type 1 (SA1) mechanoreceptor, with the Merkel corpuscle end-organ (also known as M ...
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Chain Extender
In polymer chemistry, a chain extender is a low molecular weight (MW) reagent that converts polymeric precursors to higher molecular weight derivatives. Often, it is convenient to prepare a polymer at an intermediate MW, which are suitable for solution- or melt-processing. At or near the final stages of production, the material is treated with a chain extender. Typically, chain extenders are bifunctional, i.e., they have two functional groups, which can link together two polymers. Representative classes of chain extenders are diglycidyl ethers, diols, diamines, or dianhydrides. Chain extenders are often applied to polyurethane Polyurethane (; often abbreviated PUR and PU) is a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane term ...s.{{cite book , doi=10.1016/C2012-0-02516-1 , title=Reactive Polymers Fundamentals and Applications , y ...
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Methylene Diphenyl Diisocyanate
Methylene diphenyl diisocyanate (MDI) is an aromaticity, aromatic diisocyanate. Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2′-MDI, 2,4′-MDI, and 4,4′-MDI. The 4,4′ isomer is most widely used, and is also known as 4,4′-diphenylmethane diisocyanate. This isomer is also known as Pure MDI. MDI reacts with polyols in the manufacture of polyurethane. It is the most produced diisocyanate, accounting for 61.3% of the global market in the year 2000. Production Total world production of MDI and polymeric MDI is over 7.5 million tonnes per year (in 2017). As of 2019, the largest producer was Wanhua Chemical Group. Other major producers are Covestro, BASF, Dow Chemical Company, Dow, Huntsman Corporation, Huntsman, Tosoh Corporation, Tosoh, Kumho Mitsui Chemicals. All major producers of MDI are members of the International Isocyanate Institute, whose aim is the promotion of the safe handling of MDI and Toluene diisocyanate, TDI ...
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Adipic Acid
Adipic acid or hexanedioic acid is the organic compound with the formula C6H10O4. It a white crystalline powder at standard temperature and pressure. From an industrial perspective, it is the most important dicarboxylic acid at about 2.5 billion kilograms produced annually, mainly as a precursor for the production of nylon. Adipic acid otherwise rarely occurs in nature, but it is known as manufactured E number food additive E355. Salts and esters of adipic acid are known as adipates. Preparation and reactivity Adipic acid is produced by oxidation of a mixture of cyclohexanone and cyclohexanol, which is called KA oil, an abbreviation of ketone-alcohol oil. Nitric acid is the oxidant. The pathway is multistep. Early in the reaction, the cyclohexanol is converted to the ketone, releasing nitrous acid: : The cyclohexanone is then nitrosated, setting the stage for the scission of the C-C bond: : : Side products of the method include glutaric and succinic acids. Nitrous oxide is ...
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Polytetrahydrofuran
Polytetrahydrofuran, also called poly(tetramethylene ether) glycol or poly(tetramethylene oxide), is a collection of chemical compounds with formula or HO((CH2)4O-)''n''-H. The material is a mixture of polyether diols terminated with alcohol groups. It is produced by polymerization of tetrahydrofuran as well as 1,4-butanediol. The product is commercially available as polymers of low average molecular weights, between 250 and 3000 daltons. In this form it is a white waxy solid that melts between 20 and 30 °C. The commercial product can be processed further into polymers with molecular weights of 40,000 and higher. The product is sold under various trade names including Terathane from Invista and PolyTHF from BASF. The BASF plant in Ludwigshafen at one point was producing 250,000 metric tons per year. Applications The main use of polytetrahydrofuran is to make elastic fibres such as spandex (elastane) for stretchable fabrics and for polyurethane resins. The latter ...
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Tetrahydrofuran
Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH2)4O. The compound is classified as heterocyclic compound, specifically a cyclic ether. It is a colorless, water- miscible organic liquid with low viscosity. It is mainly used as a precursor to polymers. Being polar and having a wide liquid range, THF is a versatile solvent. It is an isomer of another solvent, butanone. Production About 200,000 tonnes of tetrahydrofuran are produced annually. The most widely used industrial process involves the acid-catalyzed dehydration of 1,4-Butanediol, 1,4-butanediol. Ashland Inc., Ashland/ISP is one of the biggest producers of this chemical route. The method is similar to the production of diethyl ether from ethanol. The butanediol is derived from Condensation reaction, condensation of acetylene with formaldehyde followed by hydrogenation. DuPont developed a process for producing THF by oxidizing Butane#Isomers, ''n''-butane to crude maleic anhydride, follow ...
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Oligomer
In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relative molecular mass, the structure of which essentially comprises a small plurality of units derived, actually or conceptually, from molecules of lower relative molecular mass.'' The name is composed of Greek elements '' oligo-'', "a few" and '' -mer'', "parts". An adjective form is ''oligomeric''. The oligomer concept is contrasted to that of a polymer, which is usually understood to have a large number of units, possibly thousands or millions. However, there is no sharp distinction between these two concepts. One proposed criterion is whether the molecule's properties vary significantly with the removal of one or a few of the units. An oligomer with a specific number of units is referred to by the Greek prefix denoting that number, w ...
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Diisocyanate
In organic chemistry, isocyanate is the functional group with the formula . Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate. Diisocyanates are manufactured for the production of polyurethanes, a class of polymers. Isocyanates should not be confused with cyanate esters and isocyanides, very different families of compounds. The cyanate (cyanate ester) functional group () is arranged differently from the isocyanate group (). Isocyanides have the connectivity , lacking the oxygen of the cyanate groups. Structure and bonding In terms of bonding, isocyanates are closely related to carbon dioxide (CO2) and carbodiimides (C(NR)2). The C−N=C=O unit that defines isocyanates is planar, and the N=C=O linkage is nearly linear. In phenyl isocyanate, the C=N and C=O distances are respectively 1.195 and 1.173  Å. The C−N=C angle is 134.9° and the N=C=O angle is 173.1� ...
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