|
Ceramic Flux
Fluxes are substances, usually oxides, used in glasses, glazes and ceramic bodies to lower the high melting point of the main glass forming constituents, usually silica and alumina. A ceramic flux functions by promoting partial or complete liquefaction. The most commonly used fluxing oxides in a ceramic glaze contain lead, sodium, potassium, lithium, calcium, magnesium, barium, zinc, strontium, and manganese. These are introduced to the raw glaze as compounds, for example lead as lead oxide. Boron is considered by many to be a glass former rather than a flux. Some oxides, such as calcium oxide, flux significantly only at high temperature. Lead oxide is the traditional low temperature flux used for crystal glass, but it is now avoided because it is toxic even in small quantities. It is being replaced by other substances, especially boron and zinc oxides. In clay bodies a flux creates a limited and controlled amount of glass, which works to cement crystalline phases to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide
An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of (called a passivation layer) that protects the foil from further oxidation.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Stoichiometry Oxides are extraordinarily diverse in terms of stoichiometries (the measurable relationship between reactants and chemical equations of an equation or reaction) and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide.Greenwood, N. N.; & Earnsh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zinc
Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It is the second most abundant trace metal in humans after iron, an import ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Oxide
Sodium oxide is a chemical compound with the formula . It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered. Instead "sodium oxide" is used to describe components of various materials such as glasses and fertilizers which contain oxides that include sodium and other elements. Sodium oxide is a component. Structure The structure of sodium oxide has been determined by X-ray crystallography. Most alkali metal oxides (M = Li, Na, K, Rb) crystallise in the antifluorite structure. In this motif the positions of the anions and cations are reversed relative to their positions in , with sodium ions tetrahedrally coordinated to 4 oxide ions and oxide cubically coordinated to 8 sodium ions. Preparation Sodium oxide is produced by the reaction of sodium with sodium hydroxide, sodium peroxide, or sodium nitrite: : To the extent that NaOH is contaminated with water, correspondingly greater amounts of sodium are employed. Excess sodium is disti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Oxide
Potassium oxide ( K O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertilizers and cements, are assayed assuming the percent composition that would be equivalent to K2O. Production Potassium oxide is produced from the reaction of oxygen and potassium; this reaction affords potassium peroxide, K2O2. Treatment of the peroxide with potassium produces the oxide: : Alternatively and more conveniently, K2O is synthesized by heating potassium nitrate with metallic potassium: : Other possibility is to heat potassium peroxide at 500 °C which decomposes at that temperature giving pure potassium oxide and oxygen. : Potassium hydroxide cannot be further dehydrated to the oxide but it can react with molten potassium to produce it, releasing hydrogen as a byproduct. : Properties and reactions K2O crystallises ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Melting-point Depression
:''This article deals with melting/freezing point depression due to very small particle size. For depression due to the mixture of another compound, see freezing-point depression.'' Melting-point depression is the phenomenon of reduction of the melting point of a material with a reduction of its size. This phenomenon is very prominent in nanoscale materials, which melt at temperatures hundreds of degrees lower than bulk materials. Introduction The melting temperature of a bulk material is not dependent on its size. However, as the dimensions of a material decrease towards the atomic scale, the melting temperature scales with the material dimensions. The decrease in melting temperature can be on the order of tens to hundreds of degrees for metals with nanometer dimensions. Melting-point depression is most evident in nanowires, nanotubes and nanoparticles, which all melt at lower temperatures than bulk amounts of the same material. Changes in melting point occur because nanosca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vitrification
Vitrification (, via French ') is the full or partial transformation of a substance into a glass, that is to say, a non- crystalline or amorphous solid. Glasses differ from liquids structurally and glasses possess a higher degree of connectivity with the same Hausdorff dimensionality of bonds as crystals: dimH = 3. In the production of ceramics, vitrification is responsible for their impermeability to water. Vitrification is usually achieved by heating materials until they liquify, then cooling the liquid, often rapidly, so that it passes through the glass transition to form a glassy solid. Certain chemical reactions also result in glasses. In terms of chemistry, vitrification is characteristic for amorphous materials or disordered systems and occurs when bonding between elementary particles (atoms, molecules, forming blocks) becomes higher than a certain threshold value. Thermal fluctuations break the bonds; therefore, the lower the temperature, the higher the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zinc Oxide
Zinc oxide is an inorganic compound with the Chemical formula, formula . It is a white powder which is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, Zinc metabolism, food supplements, rubbers, plastics, ceramics, glass, cement, lubricants, paints, sunscreens, ointments, adhesives, sealants, pigments, foods, batteries, ferrites, fire retardants, semi conductors, and first-aid tapes. Although it occurs naturally as the mineral zincite, most zinc oxide is produced synthetically. History Early humans probably used zinc compounds in processed and unprocessed forms, as paint or medicinal ointment; however, their composition is uncertain. The use of ''pushpanjan'', probably zinc oxide, as a salve for eyes and open wounds is mentioned in the Indian medical text the Charaka Samhita, thought to date from 500 BC or before. Zinc oxide ointment is also mentioned by the Greek physician Dioscorides (1st century AD). Galen suggested treatin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boron Oxide
Boron oxide may refer to one of several oxides of boron: *Boron trioxide (B2O3, diboron trioxide), the most common form *Boron monoxide (BO) *Boron suboxide Boron suboxide (chemical formula B6O) is a solid compound with a structure built of eight icosahedra at the apexes of the rhombohedral unit cell. Each icosahedron is composed of twelve boron atoms. Two oxygen atoms are located in the interstices ... (B6O) Boron compounds {{Chemistry index ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Glass
Lead glass, commonly called crystal, is a variety of glass in which lead replaces the calcium content of a typical potash glass. Lead glass contains typically 18–40% (by mass) lead(II) oxide (PbO), while modern lead crystal, historically also known as flint glass due to the original silica source, contains a minimum of 24% PbO. Lead glass is often desirable for a variety of uses due to its clarity. In marketing terms it is often called crystal glass. The term ''lead crystal'' is, technically, not an accurate term to describe lead glass, because glass lacks a crystalline structure and is instead an amorphous solid. The use of the term remains popular for historical and commercial reasons, but is sometimes changed to simply ''crystal'' because of lead's reputation as a toxic substance. It is retained from the Venetian word to describe the rock crystal (quartz) imitated by Murano glassmakers. This naming convention has been maintained to the present day to describe de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Oxide
Lead oxides are a group of inorganic compounds with formulas including lead (Pb) and oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ... (O). Common lead oxides include: * Lead(II) oxide, PbO, litharge (red), massicot (yellow) * Lead tetroxide or ''red lead'', , minium, which is a lead (II,IV) oxide and may be thought of as lead(II) orthoplumbate(IV) , vivid orange crystals * Lead dioxide (lead(IV) oxide), , dark-brown or black powder Less common lead oxides are: * Lead sesquioxide, , which is a lead (II,IV) oxide as well ( lead(II) metaplumbate(IV) ), reddish yellow * , monoclinic, dark-brown or black crystals * The so-called ''black lead oxide'', which is a mixture of PbO and fine-powdered Pb metal and used in the production of lead–acid batteries. {{Authority ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcium Oxide
Calcium oxide (formula: Ca O), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term '' lime'' connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, ''quicklime'' specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime. Quicklime is relatively inexpensive. Both it and the chemical derivative calcium hydroxide (of which quicklime is the base anhydride) are important commodity chemicals. Preparation Calcium oxide is usually made by the thermal decomposition of materials, such as limestone or seashells, that contain calcium carbonate (CaCO3; mineral calcite) in a lime kiln. This is accomplished by heating the material to above , ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boron
Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral sodium borate, and the ultra-hard crystals of boron carbide and boron nitride. Boron is synthesized entirely by cosmic ray spallation and supernovas and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals. Elemental boron is found in smal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
