Aluminium Diethyl Phosphinate
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Aluminium Diethyl Phosphinate
Aluminium diethyl phosphinate is a chemical compound with formula Al()3. It decomposes above 300 °C. Applications In the family of dialkyl phosphinic acid salts, aluminium diethyl phosphinate has been found to be an excellent flame retardant for use in engineering plastics such as polyamides, polyesters, thermosets and elastomers. It was developed by Hoechst, later by Clariant chemicals and Ticona. In 2004 and 2012, Clariant chemicals opened its first and second commercial production lines respectively in Huerth-Knapsack near Cologne. Aluminium diethyl phosphinate acts as a flame retardant in the condensed phase in contributing to charring of the polymer matrix and thus protecting the substrate against heat and oxygen attack. In parallel it acts in the gas phase by radical reactions removing from the combustion zone the high energy radicals H. and OH., which determine flame propagation and heat release. The phosphinate partly vaporises and partly decomposes to volatile d ...
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Flame Retardant
The term flame retardants subsumes a diverse group of chemicals that are added to manufactured materials, such as plastics and textiles, and surface finishes and coatings. Flame retardants are activated by the presence of an ignition source and are intended to prevent or slow the further development of ignition by a variety of different physical and chemical methods. They may be added as a copolymer during the polymerisation process, or later added to the polymer at a moulding or extrusion process or (particularly for textiles) applied as a topical finish. Mineral flame retardants are typically additive while organohalogen and organophosphorus compounds can be either reactive or additive. Classes Both Reactive and Additive Flame retardants types, can be further separated into four distinct classes: * Minerals such as aluminium hydroxide (ATH), magnesium hydroxide (MDH), huntite and hydromagnesite, various hydrates, red phosphorus, and boron compounds, mostly borates. * Orga ...
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Polybutylene Terephthalate
Polybutylene terephthalate (PBT) is a thermoplastic engineering polymer that is used as an insulator in the electrical and electronics industries. It is a thermoplastic (semi-)crystalline polymer, and a type of polyester. PBT resists solvents, shrinks very little during forming, is mechanically strong, is heat-resistant up to (or with glass-fibre reinforcement), and can be treated with flame retardants to make it noncombustible. It was developed by Britain's Imperial Chemical Industries (ICI). PBT is closely related to other thermoplastic polyesters. Compared to PET ( polyethylene terephthalate), PBT has slightly lower strength and rigidity, slightly better impact resistance, and a slightly lower glass transition temperature. PBT and PET are sensitive to hot water above (140 °F). PBT and PET need UV protection if used outdoors, and most grades of these polyesters are flammable, although additives can be used to improve both UV and flammability properties. Application ...
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Nylon 46
Nylon 46 (nylon 4-6, nylon 4/6 or nylon 4,6, PA46, Polyamide 46) is a high heat resistant polyamide or nylon. DSM is the only commercial supplier of this resin, which markets under the trade name Stanyl. Nylon 46 is an aliphatic polyamide formed by the polycondensation of two monomers, one containing 4 carbon atoms, 1,4-diaminobutane (putrescine), and the other 6 carbon atoms, adipic acid, which give nylon 46 its name. It has a higher melting point than nylon 6 or nylon 66 and mainly used in applications which must withstand high temperatures. Nylon 46 withstands high loads and stresses at high temperatures and exposure to aggressive environments, and is therefore suitable for under-the-bonnet applications. Typical applications are to be found in the engine and transmission, engine-management, air-inlet, brake, air cooling and electronic systems. Many automotive components have also been produced in nylon 46, because of its excellent creep resistance, toughness and good wear charac ...
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Polyphthalamide
Polyphthalamide (aka. PPA, High Performance Polyamide) is a subset of thermoplastic synthetic resins in the polyamide (nylon) family defined as when 55% or more moles of the carboxylic acid portion of the repeating unit in the polymer chain is composed of a combination of terephthalic (TPA) and isophthalic (IPA) acids. The substitution of aliphatic diacids by aromatic diacids in the polymer backbone increases the melting point, glass transition temperature, chemical resistance and stiffness. PPA based resins are molded into parts to replace metals in applications requiring high temperature resistance such as automotive powertrain components, the housing for high temperature electrical connectors and many other uses. Structure The diamines in PPAs are aliphatic. PA6T homopolymer melts at 371 °C, which renders it intractable. To make usable polymers, it is necessary to lower the melting point, which can be achieved practically using either a longer diamine (with 9-12 ...
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Surface-mount Technology
Surface-mount technology (SMT), originally called planar mounting, is a method in which the electrical components are mounted directly onto the surface of a printed circuit board (PCB). An electrical component mounted in this manner is referred to as a surface-mount device (SMD). In industry, this approach has largely replaced the through-hole technology construction method of fitting components, in large part because SMT allows for increased manufacturing automation which reduces cost and improves quality. It also allows for more components to fit on a given area of substrate. Both technologies can be used on the same board, with the through-hole technology often used for components not suitable for surface mounting such as large transformers and heat-sinked power semiconductors. An SMT component is usually smaller than its through-hole counterpart because it has either smaller leads or no leads at all. It may have short lead (electronics), pins or leads of various styles, flat ...
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Solder
Solder (; NA: ) is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics. Soft solder typically has a melting point range of , and is commonly used in electronics, plumbing, and sheet metal work. Alloys that melt between are the most commonly used. Soldering performed using alloys with a melting point above is called "hard soldering", "silver soldering", or brazing. In specific proportions, some alloys are eutectic — that is, the alloy's melting point is the lowest possible for a mixture of those components, and co ...
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Restriction Of Hazardous Substances Directive
The Restriction of Hazardous Substances Directive 2002/95/EC (RoHS 1), short for Directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment, was adopted in February 2003 by the European Union. The initiative was to prevent an overabundance of chemicals in electronics. Thus, as a result electronics were restricted. The RoHS 1 directive took effect on 1 July 2006, and is required to be enforced and became a law in each member state. This directive restricts (with exceptions) the use of ten hazardous materials in the manufacture of various types of electronic and electrical equipment. In addition to the exceptions, there are exclusions for products such as solar panels. It is closely linked with the Waste Electrical and Electronic Equipment Directive (WEEE) 2002/96/EC (now superseded) which sets collection, recycling and recovery targets for electrical goods and is part of a legislative initiative to solve the problem of h ...
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Comparative Tracking Index
The Comparative Tracking Index (CTI) is used to measure the electrical breakdown (tracking) properties of an insulating material. Tracking is an electrical breakdown on the ''surface'' of an insulating material wherein an initial exposure to electrical arcing heat carbonizes the material. The carbonized areas are more conductive than the pristine insulator, increasing current flow, resulting in increased heat generation, and eventually the insulation becomes completely conductive. Details A large voltage difference gradually creates a conductive leakage path across the surface of the material by forming a carbonized track. Testing method is specified in IEC standard 60112 and ASTM D3638. To measure the tracking, 50 drops of 0.1% ammonium chloride solution are dropped on the material, and the voltage measured for a 3 mm thickness is considered representative of the material performance. Also term PTI (Proof Tracking Index) is used: it means voltage at which during testing o ...
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UL 94
UL 94, the Standard for Safety of Flammability of Plastic Materials for Parts in Devices and Appliances testing, is a plastics flammability standard released by Underwriters Laboratories of the United States. The standard determines the material’s tendency to either extinguish or spread the flame once the specimen has been ignitedUL-94is now harmonized with IECbr>60695-11-10an60695-11-20and ISObr>9772an The VW-1 (vertical wire burn) rating is sometimes erroneously associated with UL 94, but it (and some other flammability tests) is described by UL 1581 (Reference Standard for Electrical Wires, Cables, and Flexible Cords). Classifications From lowest (Least flame-retardant) to highest (Most flame-retardant): *HB: slow burning on a horizontal specimen; burning rate < 76 mm/min for thickness < 3 mm or burning stops before 100 mm *V-2: burning stops within 30 seconds on a vertical specimen; drips of flaming particles are allowed. *V-1: burning stops within 30 secon ...
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Nylon 66
Nylon 66 (loosely written nylon 6-6, nylon 6/6, nylon 6,6, or nylon 6:6) is a type of polyamide or nylon. It, and nylon 6, are the two most common for textile and plastic industries. Nylon 66 is made of two monomers each containing 6 carbon atoms, hexamethylenediamine and adipic acid, which give nylon 66 its name. Aside from its superior physical characteristics, nylon 66 is attractive because its precursors are inexpensive. Synthesis and manufacturing Hexamethylenediamine (top) and adipic acid (bottom), monomers used for polycondensation of Nylon 66. Nylon 66 is synthesized by polycondensation of hexamethylenediamine and adipic acid. Equivalent amounts of hexamethylenediamine and adipic acid are combined in water. In the original implementation, the resulting ammonium/ carboxylate salt was isolated and then heated either in batches or continuously to induce polycondensation.n(HOOC - (CH2)4 - COOH) + n(H2N - (CH2)6 - NH2) -> OC - (CH2)4 - CO - NH - (CH2)6 - NH - n + (2 ...
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Polyamide
A polyamide is a polymer with repeating units linked by amide bonds. Polyamides occur both naturally and artificially. Examples of naturally occurring polyamides are proteins, such as wool and silk. Artificially made polyamides can be made through step-growth polymerization or solid-phase synthesis yielding materials such as nylons, aramids, and sodium polyaspartate. Synthetic polyamides are commonly used in textiles, automotive industry, carpets, kitchen utensils and sportswear due to their high durability and strength. The transportation manufacturing industry is the major consumer, accounting for 35% of polyamide (PA) consumption. Classification Polymers of amino acids are known as polypeptides or proteins. According to the composition of their main chain, synthetic polyamides are classified as follows: All polyamides are made by the formation of an amide function to link two molecules of monomer together. The monomers can be amides themselves (usually in the form of a c ...
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