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Thermodynamic Operation
A thermodynamic operation is an externally imposed manipulation that affects a thermodynamic system. The change can be either in the connection or wall between a thermodynamic system and its surroundings, or in the value of some variable in the surroundings that is in contact with a wall of the system that allows transfer of the extensive quantity belonging that variable.Giles, R. (1964), p. 22.Lieb, E.H., Yngvason, J. (1999). It is assumed in thermodynamics that the operation is conducted in ignorance of any pertinent microscopic information. A thermodynamic operation requires a contribution from an independent external agency, that does not come from the passive properties of the systems. Perhaps the first expression of the distinction between a thermodynamic operation and a thermodynamic process is in Kelvin's statement of the second law of thermodynamics: "It is impossible, by means of inanimate material agency, to derive mechanical effect from any portion of matter by cooling i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic System
A thermodynamic system is a body of matter and/or radiation, confined in space by walls, with defined permeabilities, which separate it from its surroundings. The surroundings may include other thermodynamic systems, or physical systems that are not thermodynamic systems. A wall of a thermodynamic system may be purely notional, when it is described as being 'permeable' to all matter, all radiation, and all forces. A state of a thermodynamic system can be fully described in several different ways, by several different sets of thermodynamic state variables. A widely used distinction is between ''isolated'', ''closed'', and ''open'' thermodynamic systems. An isolated thermodynamic system has walls that are non-conductive of heat and perfectly reflective of all radiation, that are rigid and immovable, and that are impermeable to all forms of matter and all forces. (Some writers use the word 'closed' when here the word 'isolated' is being used.) A closed thermodynamic system is c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carnot Heat Engine
A Carnot heat engine is a heat engine that operates on the Carnot cycle. The basic model for this engine was developed by Nicolas Léonard Sadi Carnot in 1824. The Carnot engine model was graphically expanded by Benoît Paul Émile Clapeyron in 1834 and mathematically explored by Rudolf Clausius in 1857, work that led to the fundamental thermodynamic concept of entropy. The Carnot engine is the most efficient heat engine which is theoretically possible. The efficiency depends only upon the absolute temperatures of the hot and cold heat reservoirs between which it operates. A heat engine acts by transferring energy from a warm region to a cool region of space and, in the process, converting some of that energy to mechanical work. The cycle may also be reversed. The system may be worked upon by an external force, and in the process, it can transfer thermal energy from a cooler system to a warmer one, thereby acting as a refrigerator or heat pump rather than a heat engine. Every th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Poincaré Recurrence Theorem
In mathematics and physics, the Poincaré recurrence theorem states that certain dynamical systems will, after a sufficiently long but finite time, return to a state arbitrarily close to (for continuous state systems), or exactly the same as (for discrete state systems), their initial state. The Poincaré recurrence time is the length of time elapsed until the recurrence. This time may vary greatly depending on the exact initial state and required degree of closeness. The result applies to isolated mechanical systems subject to some constraints, e.g., all particles must be bound to a finite volume. The theorem is commonly discussed in the context of ergodic theory, dynamical systems and statistical mechanics. Systems to which the Poincaré recurrence theorem applies are called conservative systems. The theorem is named after Henri Poincaré, who discussed it in 1890 and proved by Constantin Carathéodory using measure theory in 1919. Precise formulation Any dynamical s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Homogeneous Function
In mathematics, a homogeneous function is a function of several variables such that, if all its arguments are multiplied by a scalar, then its value is multiplied by some power of this scalar, called the degree of homogeneity, or simply the ''degree''; that is, if is an integer, a function of variables is homogeneous of degree if :f(sx_1,\ldots, sx_n)=s^k f(x_1,\ldots, x_n) for every x_1, \ldots, x_n, and s\ne 0. For example, a homogeneous polynomial of degree defines a homogeneous function of degree . The above definition extends to functions whose domain and codomain are vector spaces over a field : a function f : V \to W between two -vector spaces is ''homogeneous'' of degree k if for all nonzero s \in F and v \in V. This definition is often further generalized to functions whose domain is not , but a cone in , that is, a subset of such that \mathbf\in C implies s\mathbf\in C for every nonzero scalar . In the case of functions of several real variables and rea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
State Function
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system (e.g. gas, liquid, solid, crystal, or emulsion), not the path which the system has taken to reach that state. A state function describes equilibrium states of a system, thus also describing the type of system. A state variable is typically a state function so the determination of other state variable values at an equilibrium state also determines the value of the state variable as the state function at that state. The ideal gas law is a good example. In this law, one state variable (e.g., pressure, volume, temperature, or the amount of substance in a gaseous equilibrium system) is a function of other state variables so is regarded as a state function. A state fu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intensive And Extensive Properties
Physical properties of materials and systems can often be categorized as being either intensive or extensive, according to how the property changes when the size (or extent) of the system changes. According to IUPAC, an intensive quantity is one whose magnitude is independent of the size of the system, whereas an extensive quantity is one whose magnitude is additive for subsystems. The terms ''intensive and extensive quantities'' were introduced into physics by German writer Georg Helm in 1898, and by American physicist and chemist Richard C. Tolman in 1917. An intensive property does not depend on the system size or the amount of material in the system. It is not necessarily homogeneously distributed in space; it can vary from place to place in a body of matter and radiation. Examples of intensive properties include temperature, ''T''; refractive index, ''n''; density, ''ρ''; and hardness, ''η''. By contrast, extensive properties such as the mass, volume and entropy of syst ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Constantin Carathéodory
Constantin Carathéodory ( el, Κωνσταντίνος Καραθεοδωρή, Konstantinos Karatheodori; 13 September 1873 – 2 February 1950) was a Greek mathematician who spent most of his professional career in Germany. He made significant contributions to real and complex analysis, the calculus of variations, and measure theory. He also created an axiomatic formulation of thermodynamics. Carathéodory is considered one of the greatest mathematicians of his era and the most renowned Greek mathematician since antiquity. Origins Constantin Carathéodory was born in 1873 in Berlin to Greek parents and grew up in Brussels. His father Stephanos, a lawyer, served as the Ottoman ambassador to Belgium, St. Petersburg and Berlin. His mother, Despina, née Petrokokkinos, was from the island of Chios. The Carathéodory family, originally from Bosnochori or Vyssa, was well established and respected in Constantinople, and its members held many important governmental positions. Th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Refrigerator
A refrigerator, colloquially fridge, is a commercial and home appliance consisting of a thermally insulated compartment and a heat pump (mechanical, electronic or chemical) that transfers heat from its inside to its external environment so that its inside is cooled to a temperature below the room temperature. Refrigeration is an essential food storage technique around the world. The lower temperature lowers the reproduction rate of bacteria, so the refrigerator reduces the rate of spoilage. A refrigerator maintains a temperature a few degrees above the freezing point of water. The optimal temperature range for perishable food storage is .Keep your fridge-freezer clean and ice-free ''BBC''. 30 April 2008 A similar device that maintains a temperature below the freezing point of water is called a freezer. The refrigerator replaced the icebox, which had been a common household appliance for almost a century and a half. The United States Food and Drug Administration recommends t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Cycle
A thermodynamic cycle consists of a linked sequence of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. In the process of passing through a cycle, the working fluid (system) may convert heat from a warm source into useful work, and dispose of the remaining heat to a cold sink, thereby acting as a heat engine. Conversely, the cycle may be reversed and use work to move heat from a cold source and transfer it to a warm sink thereby acting as a heat pump. If at every point in the cycle the system is in thermodynamic equilibrium, the cycle is reversible. Whether carried out reversible or irreversibly, the net entropy change of the system is zero, as entropy is a state function. During a closed cycle, the system returns to its original thermodynamic state of temperature and pressure. Process quanti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
László Tisza
László Tisza (July 7, 1907 – April 15, 2009) was a Hungarian-born American physicist who was Professor of Physics Emeritus at MIT. He was a colleague of famed physicists Edward Teller, Lev Landau and Fritz London, and initiated the two-fluid theory of liquid helium. United States In 1941, Tisza immigrated to the United States and joined the faculty at the Massachusetts Institute of Technology. His research areas included theoretical physics and the history and philosophy of science, specifically on the foundation of thermodynamics and quantum mechanics. He taught at MIT until 1973. Publications Tisza was the author of the 1966 book, ''Generalized Thermodynamics''. The 1982 publication, ''Physics as Natural Philosophy: Essays in Honor of László Tisza'', was written by Tisza's colleagues and former students in honor of his 75th birthday. Affiliations He was a Fellow of The American Physical Society and American Academy of Arts and Sciences, a John Simon Guggenheim Fellow ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Max Planck
Max Karl Ernst Ludwig Planck (, ; 23 April 1858 – 4 October 1947) was a German theoretical physicist whose discovery of energy quanta won him the Nobel Prize in Physics in 1918. Planck made many substantial contributions to theoretical physics, but his fame as a physicist rests primarily on his role as the originator of quantum theory, which revolutionized human understanding of atomic and subatomic processes. In 1948, the German scientific institution Kaiser Wilhelm Society (of which Planck was twice president) was renamed Max Planck Society (MPG). The MPG now includes 83 institutions representing a wide range of scientific directions. Life and career Planck came from a traditional, intellectual family. His paternal great-grandfather and grandfather were both theology professors in Göttingen; his father was a law professor at the University of Kiel and Munich. One of his uncles was also a judge. Planck was born in 1858 in Kiel, Holstein, to Johann Julius Wilhelm Pl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
William Thomson, 1st Baron Kelvin
William Thomson, 1st Baron Kelvin, (26 June 182417 December 1907) was a British mathematician, Mathematical physics, mathematical physicist and engineer born in Belfast. Professor of Natural Philosophy (Glasgow), Professor of Natural Philosophy at the University of Glasgow for 53 years, he did important work in the mathematical analysis of electricity and formulation of the first and second laws of thermodynamics, and did much to unify the emerging discipline of physics in its contemporary form. He received the Royal Society's Copley Medal in 1883, was its President of the Royal Society, president 1890–1895, and in 1892 was the first British scientist to be elevated to the House of Lords. Absolute temperatures are stated in units of kelvin in his honour. While the existence of a coldest possible temperature (absolute zero) was known prior to his work, Kelvin is known for determining its correct value as approximately −273.15 degrees Celsius or −459.67 degrees Fahrenheit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
