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State Functions
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system (e.g. gas, liquid, solid, crystal, or emulsion), not the path which the system has taken to reach that state. A state function describes equilibrium states of a system, thus also describing the type of system. A state variable is typically a state function so the determination of other state variable values at an equilibrium state also determines the value of the state variable as the state function at that state. The ideal gas law is a good example. In this law, one state variable (e.g., pressure, volume, temperature, or the amount of substance in a gaseous equilibrium system) is a function of other state variables so is regarded as a state function. A state fu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formula ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Temperature
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called ''centigrade''), the Fahrenheit scale (°F), and the Kelvin scale (K), the latter being used predominantly for scientific purposes. The kelvin is one of the seven base units in the International System of Units (SI). Absolute zero, i.e., zero kelvin or −273.15 °C, is the lowest point in the thermodynamic temperature scale. Experimentally, it can be approached very closely but not actually reached, as recognized in the third law of thermodynamics. It would be impossible to extract energy as heat from a body at that temperature. Tem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Integral
In mathematics, an integral assigns numbers to functions in a way that describes displacement, area, volume, and other concepts that arise by combining infinitesimal data. The process of finding integrals is called integration. Along with differentiation, integration is a fundamental, essential operation of calculus,Integral calculus is a very well established mathematical discipline for which there are many sources. See and , for example. and serves as a tool to solve problems in mathematics and physics involving the area of an arbitrary shape, the length of a curve, and the volume of a solid, among others. The integrals enumerated here are those termed definite integrals, which can be interpreted as the signed area of the region in the plane that is bounded by the graph of a given function between two points in the real line. Conventionally, areas above the horizontal axis of the plane are positive while areas below are negative. Integrals also refer to the concept ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
State Postulate
The state postulate is a term used in thermodynamics that defines the given number of properties to a thermodynamic system in a state of equilibrium. It is also sometimes referred to as the state principle. The state postulate allows a finite number of properties to be specified in order to fully describe a state of thermodynamic equilibrium. Once the state postulate is given the other unspecified properties must assume certain values. The state postulate says: A more general statement of the state postulate says: ''the state of a simple system is completely specified by r+1 independent, intensive properties where r is the number of significant work interactions.'' A system is considered to be a simple compressible one in the absence of certain effects which are uncommon in many engineering applications. These are electromagnetic and gravitational fields, surface tension, and motion. For such a system, only two independent intensive variables are sufficient to derive all the ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Higher-dimensional Space
In physics and mathematics, the dimension of a mathematical space (or object) is informally defined as the minimum number of coordinates needed to specify any point within it. Thus, a line has a dimension of one (1D) because only one coordinate is needed to specify a point on itfor example, the point at 5 on a number line. A surface, such as the boundary of a cylinder or sphere, has a dimension of two (2D) because two coordinates are needed to specify a point on itfor example, both a latitude and longitude are required to locate a point on the surface of a sphere. A two-dimensional Euclidean space is a two-dimensional space on the plane. The inside of a cube, a cylinder or a sphere is three-dimensional (3D) because three coordinates are needed to locate a point within these spaces. In classical mechanics, space and time are different categories and refer to absolute space and time. That conception of the world is a four-dimensional space but not the one that was found ne ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monatomic Gas
In physics and chemistry, "monatomic" is a combination of the words "mono" and "atomic", and means "single atom". It is usually applied to gases: a monatomic gas is a gas in which atoms are not bound to each other. Examples at standard conditions of temperature and pressure include all the noble gases (helium, neon, argon, krypton, xenon, and radon), though all chemical elements will be monatomic in the gas phase at sufficiently high temperature (or very low pressure). The thermodynamic behavior of a monatomic gas is much simpler when compared to polyatomic gases because it is free of any rotational or vibrational energy. Noble gases The only chemical elements that are stable single atoms (so they are not molecules) at standard temperature and pressure (STP) are the noble gases. These are helium, neon, argon, krypton, xenon, and radon. Noble gases have a full outer valence shell making them rather non-reactive species. While these elements have been described historically as compl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
State Space
A state space is the set of all possible configurations of a system. It is a useful abstraction for reasoning about the behavior of a given system and is widely used in the fields of artificial intelligence and game theory. For instance, the toy problem Vacuum World has a discrete finite state space in which there are a limited set of configurations that the vacuum and dirt can be in. A "counter" system, where states are the natural numbers starting at 1 and are incremented over time has an infinite discrete state space. The angular position of an undamped pendulum is a continuous (and therefore infinite) state space. Definition In the theory of dynamical systems, the state space of a discrete system defined by a function ''ƒ'' can be modeled as a directed graph where each possible state of the dynamical system is represented by a vertex with a directed edge from ''a'' to ''b'' if and only if ''ƒ''(''a'') = ''b''. This is known as a state diagram. For a co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and even by industry. Further, both spellings are often used ''within'' a particular industry or country. Industries in British English-speaking countries typically use the "gauge" spelling. is the pressure relative to the ambient pressure. Various #Units, units are used to express pressure. Some of these derive from a unit of force divided by a unit of area; the International System of Units, SI unit of pressure, the Pascal (unit), pascal (Pa), for example, is one newton (unit), newton per square metre (N/m2); similarly, the Pound (force), pound-force per square inch (Pounds per square inch, psi) is the traditional unit of pressure in the imperial units, imperial and United States customary units, U.S. customary systems. Pressure may also be e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Volume (thermodynamics)
In thermodynamics, the volume of a system is an important extensive parameter for describing its thermodynamic state. The specific volume, an intensive property, is the system's volume per unit of mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature. For example, volume is related to the pressure and temperature of an ideal gas by the ideal gas law. The physical volume of a system may or may not coincide with a control volume used to analyze the system. Overview The volume of a thermodynamic system typically refers to the volume of the working fluid, such as, for example, the fluid within a piston. Changes to this volume may be made through an application of work, or may be used to produce work. An isochoric process however operates at a constant-volume, thus no work can be produced. Many other thermodynamic processes will result in a change in volume. A polytropic process, in particular, causes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Willard Gibbs
Josiah Willard Gibbs (; February 11, 1839 – April 28, 1903) was an American scientist who made significant theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynamics was instrumental in transforming physical chemistry into a rigorous inductive science. Together with James Clerk Maxwell and Ludwig Boltzmann, he created statistical mechanics (a term that he coined), explaining the laws of thermodynamics as consequences of the statistical properties of ensembles of the possible states of a physical system composed of many particles. Gibbs also worked on the application of Maxwell's equations to problems in physical optics. As a mathematician, he invented modern vector calculus (independently of the British scientist Oliver Heaviside, who carried out similar work during the same period). In 1863, Yale awarded Gibbs the first American doctorate in engineering. After a three-year sojourn in Europe, Gibbs spent the rest of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
William Thomson, 1st Baron Kelvin
William Thomson, 1st Baron Kelvin, (26 June 182417 December 1907) was a British mathematician, Mathematical physics, mathematical physicist and engineer born in Belfast. Professor of Natural Philosophy (Glasgow), Professor of Natural Philosophy at the University of Glasgow for 53 years, he did important work in the mathematical analysis of electricity and formulation of the first and second laws of thermodynamics, and did much to unify the emerging discipline of physics in its contemporary form. He received the Royal Society's Copley Medal in 1883, was its President of the Royal Society, president 1890–1895, and in 1892 was the first British scientist to be elevated to the House of Lords. Absolute temperatures are stated in units of kelvin in his honour. While the existence of a coldest possible temperature (absolute zero) was known prior to his work, Kelvin is known for determining its correct value as approximately −273.15 degrees Celsius or −459.67 degrees Fahrenheit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peter Tait (physicist)
Peter Guthrie Tait FRSE (28 April 1831 – 4 July 1901) was a Scottish mathematical physicist and early pioneer in thermodynamics. He is best known for the mathematical physics textbook '' Treatise on Natural Philosophy'', which he co-wrote with Lord Kelvin, and his early investigations into knot theory. His work on knot theory contributed to the eventual formation of topology as a mathematical discipline. His name is known in graph theory mainly for Tait's conjecture. He is also one of the namesakes of the Tait–Kneser theorem on osculating circles. Early life Tait was born in Dalkeith on 28 April 1831 the only son of Mary Ronaldson and John Tait, secretary to the 5th Duke of Buccleuch. He was educated at Dalkeith Grammar School then Edinburgh Academy. He studied Mathematics and Physics at the University of Edinburgh, and then went to Peterhouse, Cambridge, graduating as senior wrangler and first Smith's prizeman in 1852. As a fellow and lecturer of his college he r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
