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Quantum Statistical Mechanics
Quantum statistical mechanics is statistical mechanics applied to quantum mechanical systems. In quantum mechanics a statistical ensemble (probability distribution over possible quantum states) is described by a density operator ''S'', which is a non-negative, self-adjoint, trace-class operator of trace 1 on the Hilbert space ''H'' describing the quantum system. This can be shown under various mathematical formalisms for quantum mechanics. One such formalism is provided by quantum logic. Expectation From classical probability theory, we know that the expectation of a random variable ''X'' is defined by its distribution D''X'' by : \mathbb(X) = \int_\mathbb \lambda \, d \, \operatorname_X(\lambda) assuming, of course, that the random variable is integrable or that the random variable is non-negative. Similarly, let ''A'' be an observable of a quantum mechanical system. ''A'' is given by a densely defined self-adjoint operator on ''H''. The spectral measure of ''A'' defi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Borel Functional Calculus
In functional analysis, a branch of mathematics, the Borel functional calculus is a ''functional calculus'' (that is, an assignment of operators from commutative algebras to functions defined on their spectra), which has particularly broad scope. Thus for instance if ''T'' is an operator, applying the squaring function ''s'' → ''s''2 to ''T'' yields the operator ''T''2. Using the functional calculus for larger classes of functions, we can for example define rigorously the "square root" of the (negative) Laplacian operator or the exponential e^. The 'scope' here means the kind of ''function of an operator'' which is allowed. The Borel functional calculus is more general than the continuous functional calculus, and its focus is different than the holomorphic functional calculus one. More precisely, the Borel functional calculus allows for applying an arbitrary Borel function to a self-adjoint operator, in a way that generalizes applying a polynomial function. Motivation If ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary ( macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Princeton University Press
Princeton University Press is an independent Academic publishing, publisher with close connections to Princeton University. Its mission is to disseminate scholarship within academia and society at large. The press was founded by Whitney Darrow, with the financial support of Charles Scribner II, Charles Scribner, as a printing press to serve the Princeton community in 1905. Its distinctive building was constructed in 1911 on William Street in Princeton. Its first book was a new 1912 edition of John Witherspoon's ''Lectures on Moral Philosophy.'' History Princeton University Press was founded in 1905 by a recent Princeton graduate, Whitney Darrow, with financial support from another Princetonian, Charles Scribner II. Darrow and Scribner purchased the equipment and assumed the operations of two already existing local publishers, that of the ''Princeton Alumni Weekly'' and the Princeton Press. The new press printed both local newspapers, university documents, ''The Daily Princetonian ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Thermal Quantum Field Theory
In theoretical physics, thermal quantum field theory (thermal field theory for short) or finite temperature field theory is a set of methods to calculate expectation values of physical observables of a quantum field theory at finite temperature. In the Matsubara formalism, the basic idea (due to Felix Bloch) is that the expectation values of operators in a canonical ensemble : \langle A\rangle=\frac may be written as expectation values in ordinary quantum field theory where the configuration is evolved by an imaginary time \tau = i t(0\leq\tau\leq\beta). One can therefore switch to a spacetime with Euclidean signature, where the above trace (Tr) leads to the requirement that all bosonic and fermionic fields be periodic and antiperiodic, respectively, with respect to the Euclidean time direction with periodicity \beta = 1/(kT) (we are assuming natural units \hbar = 1). This allows one to perform calculations with the same tools as in ordinary quantum field theory, such as func ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Quantum Thermodynamics
Quantum thermodynamics is the study of the relations between two independent physical theories: thermodynamics and quantum mechanics. The two independent theories address the physical phenomena of light and matter. In 1905, Albert Einstein argued that the requirement of consistency between thermodynamics and electromagnetism leads to the conclusion that light is quantized obtaining the relation E= h \nu . This paper is the dawn of quantum theory. In a few decades quantum theory became established with an independent set of rules. Currently quantum thermodynamics addresses the emergence of thermodynamic laws from quantum mechanics. It differs from quantum statistical mechanics in the emphasis on dynamical processes out of equilibrium. In addition, there is a quest for the theory to be relevant for a single individual quantum system. Dynamical view There is an intimate connection of quantum thermodynamics with the theory of open quantum systems. Quantum mechanics inserts dyn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Grand Canonical Ensemble
In statistical mechanics, the grand canonical ensemble (also known as the macrocanonical ensemble) is the statistical ensemble that is used to represent the possible states of a mechanical system of particles that are in thermodynamic equilibrium (thermal and chemical) with a reservoir. The system is said to be open in the sense that the system can exchange energy and particles with a reservoir, so that various possible states of the system can differ in both their total energy and total number of particles. The system's volume, shape, and other external coordinates are kept the same in all possible states of the system. The thermodynamic variables of the grand canonical ensemble are chemical potential (symbol: ) and absolute temperature (symbol: . The ensemble is also dependent on mechanical variables such as volume (symbol: which influence the nature of the system's internal states. This ensemble is therefore sometimes called the ensemble, as each of these three quantitie ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Canonical Partition Function
The adjective canonical is applied in many contexts to mean "according to the canon" the standard, rule or primary source that is accepted as authoritative for the body of knowledge or literature in that context. In mathematics, "canonical example" is often used to mean "archetype". Science and technology * Canonical form, a natural unique representation of an object, or a preferred notation for some object Mathematics * * Canonical coordinates, sets of coordinates that can be used to describe a physical system at any given point in time * Canonical map, a morphism that is uniquely defined by its main property * Canonical polyhedron, a polyhedron whose edges are all tangent to a common sphere, whose center is the average of its vertices * Canonical ring, a graded ring associated to an algebraic variety * Canonical injection, in set theory * Canonical representative, in set theory a standard member of each element of a set partition Differential geometry * Canonical one-form ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Partition Function (mathematics)
The partition function or configuration integral, as used in probability theory, information theory and dynamical systems, is a generalization of the definition of a partition function in statistical mechanics. It is a special case of a normalizing constant in probability theory, for the Boltzmann distribution. The partition function occurs in many problems of probability theory because, in situations where there is a natural symmetry, its associated probability measure, the Gibbs measure, has the Markov property. This means that the partition function occurs not only in physical systems with translation symmetry, but also in such varied settings as neural networks (the Hopfield network), and applications such as genomics, corpus linguistics and artificial intelligence, which employ Markov networks, and Markov logic networks. The Gibbs measure is also the unique measure that has the property of maximizing the entropy for a fixed expectation value of the energy; this underlies the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Gibbs Canonical Ensemble
In statistical mechanics, a canonical ensemble is the statistical ensemble that represents the possible states of a mechanical system in thermal equilibrium with a heat bath at a fixed temperature. The system can exchange energy with the heat bath, so that the states of the system will differ in total energy. The principal thermodynamic variable of the canonical ensemble, determining the probability distribution of states, is the absolute temperature (symbol: ). The ensemble typically also depends on mechanical variables such as the number of particles in the system (symbol: ) and the system's volume (symbol: ), each of which influence the nature of the system's internal states. An ensemble with these three parameters is sometimes called the ensemble. The canonical ensemble assigns a probability to each distinct microstate given by the following exponential: :P = e^, where is the total energy of the microstate, and is the Boltzmann constant. The number is the free en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Quantum Entanglement
Quantum entanglement is the phenomenon that occurs when a group of particles are generated, interact, or share spatial proximity in a way such that the quantum state of each particle of the group cannot be described independently of the state of the others, including when the particles are separated by a large distance. The topic of quantum entanglement is at the heart of the disparity between classical and quantum physics: entanglement is a primary feature of quantum mechanics not present in classical mechanics. Measurements of physical properties such as position, momentum, spin, and polarization performed on entangled particles can, in some cases, be found to be perfectly correlated. For example, if a pair of entangled particles is generated such that their total spin is known to be zero, and one particle is found to have clockwise spin on a first axis, then the spin of the other particle, measured on the same axis, is found to be anticlockwise. However, this behavior gives ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Shannon Entropy
Shannon may refer to: People * Shannon (given name) * Shannon (surname) * Shannon (American singer), stage name of singer Shannon Brenda Greene (born 1958) * Shannon (South Korean singer), British-South Korean singer and actress Shannon Arrum Williams (born 1998) * Shannon, intermittent stage name of English singer-songwriter Marty Wilde (born 1939) * Claude Shannon (1916-2001) was American mathematician, electrical engineer, and cryptographer known as a "father of information theory" Places Australia * Shannon, Tasmania, a locality * Hundred of Shannon, a cadastral unit in South Australia * Shannon, a former name for the area named Calomba, South Australia since 1916 * Shannon River (Western Australia) Canada * Shannon, New Brunswick, a community * Shannon, Quebec, a city * Shannon Bay, former name of Darrell Bay, British Columbia * Shannon Falls, a waterfall in British Columbia Ireland * River Shannon, the longest river in Ireland ** Shannon Cave, a subterranean section ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |