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Quantum Tunnelling
In physics, quantum tunnelling, barrier penetration, or simply tunnelling is a quantum mechanical phenomenon in which an object such as an electron or atom passes through a potential energy barrier that, according to classical mechanics, should not be passable due to the object not having sufficient energy to pass or surmount the barrier. Tunneling is a consequence of the wave nature of matter, where the quantum wave function describes the state of a particle or other physical system, and wave equations such as the Schrödinger equation describe their behavior. The probability of transmission of a wave packet through a barrier decreases exponentially with the barrier height, the barrier width, and the tunneling particle's mass, so tunneling is seen most prominently in low-mass particles such as electrons or protons tunneling through microscopically narrow barriers. Tunneling is readily detectable with barriers of thickness about 1–3 nm or smaller for electrons, and abou ...
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Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ...
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Scanning Tunnelling Microscope
A scanning tunneling microscope (STM) is a type of scanning probe microscope used for imaging surfaces at the atomic level. Its development in 1981 earned its inventors, Gerd Binnig and Heinrich Rohrer, then at IBM Zürich, the Nobel Prize in Physics in 1986. STM senses the surface by using an extremely sharp conducting tip that can distinguish features smaller than 0.1  nm with a 0.01 nm (10  pm) depth resolution. This means that individual atoms can routinely be imaged and manipulated. Most scanning tunneling microscopes are built for use in ultra-high vacuum at temperatures approaching absolute zero, but variants exist for studies in air, water and other environments, and for temperatures over 1000 °C. STM is based on the concept of quantum tunneling. When the tip is brought very near to the surface to be examined, a bias voltage applied between the two allows electrons to tunnel through the vacuum separating them. The resulting ''tunneling current'' ...
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Molecular Spectra
The emission spectrum of a chemical element or chemical compound is the Spectrum (physical sciences), spectrum of frequencies of electromagnetic radiation emitted due to electrons making a atomic electron transition, transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances. Emission In physics, emission is the process by which a higher energy quantum mechanical state of a particle becomes converted to a lower one through the emis ...
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Double-well Potential
The so-called double-well potential is one of a number of quartic potentials of considerable interest in quantum mechanics, in quantum field theory and elsewhere for the exploration of various physical phenomena or mathematical properties since it permits in many cases explicit calculation without over-simplification. Thus the "symmetric double-well potential" served for many years as a model to illustrate the concept of instantons as a pseudo-classical configuration in a Euclideanised field theory. In the simpler quantum mechanical context this potential served as a model for the evaluation of Feynman path integrals. or the solution of the Schrödinger equation by various methods for the purpose of obtaining explicitly the energy eigenvalues. The "inverted symmetric double-well potential", on the other hand, served as a nontrivial potential in the Schrödinger equation for the calculation of decay rates and the exploration of the large order behavior of asymptotic expansions ...
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Friedrich Hund
Friedrich Hermann Hund (4 February 1896 – 31 March 1997) was a German physicist from Karlsruhe known for his work on atoms and molecules. He is known for the Hund's rules to predict the electron configuration of chemical elements. His work on Hund's cases and molecular orbital theory furthered the understanding of molecular structure. Scientific career Hund worked with such prestigious physicists as Erwin Schrödinger, Paul Dirac, Werner Heisenberg, Max Born, and Walther Bothe. At that time, he was Born's assistant, working with quantum interpretation of Spectral bands, band spectra of diatomic molecules. After his studies of mathematics, physics, and geography in Marburg and Göttingen, he worked as a private lecturer for theoretical physics in the University of Göttingen (1925), professor in the University of Rostock (1927), Leipzig University (1929), University of Jena (1946), Goethe University Frankfurt, University Frankfurt (1951) and from 1957 again in Göttingen. Addi ...
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WKB Approximation
In mathematical physics, the WKB approximation or WKB method is a technique for finding approximate solutions to Linear differential equation, linear differential equations with spatially varying coefficients. It is typically used for a Semiclassical physics, semiclassical calculation in quantum mechanics in which the wave function is recast as an exponential function, semiclassically expanded, and then either the amplitude or the phase is taken to be changing slowly. The name is an initialism for Wentzel–Kramers–Brillouin. It is also known as the LG or Liouville–Green method. Other often-used letter combinations include JWKB and WKBJ, where the "J" stands for Jeffreys. Brief history This method is named after physicists Gregor Wentzel, Hendrik Anthony Kramers, and Léon Brillouin, who all developed it in 1926. In 1923, mathematician Harold Jeffreys had developed a general method of approximating solutions to linear, second-order differential equations, a class that inc ...
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Semiclassical Physics
In physics, semiclassical refers to a theory in which one part of a system is described quantum mechanically, whereas the other is treated classically. For example, external fields will be constant, or when changing will be classically described. In general, it incorporates a development in powers of the Planck constant, resulting in the classical physics of power 0, and the first nontrivial approximation to the power of (−1). In this case, there is a clear link between the quantum-mechanical system and the associated semi-classical and classical approximations, as it is similar in appearance to the transition from physical optics to geometric optics. History Max Planck was the first to introduce the idea of quanta of energy in 1900 while studying black-body radiation. In 1906, he was also the first to write that quantum theory should replicate classical mechanics at some limit, particularly if the Planck constant ''h'' were infinitesimal. With this idea he showed tha ...
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Rectangular Potential Barrier
In quantum mechanics, the rectangular (or, at times, square) potential barrier is a standard one-dimensional problem that demonstrates the phenomena of wave-mechanical tunneling (also called "quantum tunneling") and wave-mechanical reflection. The problem consists of solving the one-dimensional time-independent Schrödinger equation for a particle encountering a rectangular potential energy barrier. It is usually assumed, as here, that a free particle impinges on the barrier from the left. Although classically a particle behaving as a point mass would be reflected if its energy is less than a particle actually behaving as a matter wave has a non-zero probability of penetrating the barrier and continuing its travel as a wave on the other side. In classical wave-physics, this effect is known as evanescent wave coupling. The likelihood that the particle will pass through the barrier is given by the transmission coefficient, whereas the likelihood that it is reflected is give ...
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Absolute Value
In mathematics, the absolute value or modulus of a real number x, is the non-negative value without regard to its sign. Namely, , x, =x if x is a positive number, and , x, =-x if x is negative (in which case negating x makes -x positive), and For example, the absolute value of 3 and the absolute value of −3 is The absolute value of a number may be thought of as its distance from zero. Generalisations of the absolute value for real numbers occur in a wide variety of mathematical settings. For example, an absolute value is also defined for the complex numbers, the quaternions, ordered rings, fields and vector spaces. The absolute value is closely related to the notions of magnitude, distance, and norm in various mathematical and physical contexts. Terminology and notation In 1806, Jean-Robert Argand introduced the term ''module'', meaning ''unit of measure'' in French, specifically for the ''complex'' absolute value,Oxford English Dictionary, Draft Revision, Ju ...
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Wave–particle Duality
Wave–particle duality is the concept in quantum mechanics that fundamental entities of the universe, like photons and electrons, exhibit particle or wave (physics), wave properties according to the experimental circumstances. It expresses the inability of the Classical physics, classical concepts such as particle or wave to fully describe the behavior of quantum objects. During the 19th and early 20th centuries, light was found to behave as a wave then later was discovered to have a particle-like behavior, whereas electrons behaved like particles in early experiments then were later discovered to have wave-like behavior. The concept of duality arose to name these seeming contradictions. History Wave-particle duality of light In the late 17th century, Sir Isaac Newton had advocated that light was Corpuscular theory of light, corpuscular (particulate), but Christiaan Huygens took an opposing wave description. While Newton had favored a particle approach, he was the first to at ...
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Phenomenon
A phenomenon ( phenomena), sometimes spelled phaenomenon, is an observable Event (philosophy), event. The term came into its modern Philosophy, philosophical usage through Immanuel Kant, who contrasted it with the noumenon, which ''cannot'' be directly observed. Kant was heavily influenced by Gottfried Wilhelm Leibniz in this part of his philosophy, in which phenomenon and noumenon serve as interrelated technical terms. Far predating this, the Ancient Greek Philosophy, ancient Greek Pyrrhonism, Pyrrhonist philosopher Sextus Empiricus also used ''phenomenon'' and ''noumenon'' as interrelated technical terms. Common usage In popular usage, a ''phenomenon'' often refers to an extraordinary, unusual or notable event. According to the ''Dictionary of Visual Discourse'':In ordinary language 'phenomenon/phenomena' refer to any occurrence worthy of note and investigation, typically an untoward or unusual event, person or fact that is of special significance or otherwise notable. ...
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