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Microbial Corrosion
Microbial corrosion, also known as microbiologically influenced corrosion (MIC), microbially induced corrosion (MIC) or biocorrosion, occurs when microbes affect the electrochemical environment of the surface on which they are fixed. This usually involves the formation of a biofilm, which can either increase the corrosion of the surface or, in a process called microbial corrosion inhibition, protect the surface from corrosion. As every surface exposed to the environment is in some way also exposed to microbes, microbial corrosion causes trillions of dollars in damage around the globe annually. Microbes can locally create hypoxic conditions at the metal surface under a biofilm and contribute to the formation of anodic (oxidation) and cathodic ( reduction) sites initiating electrochemical potential differences and electrochemical corrosion. They can also act by either releasing byproducts from their cellular metabolism that corrode metals, or preventing normal corrosion inhibito ...
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Microbe
A microorganism, or microbe, is an organism of microscopic size, which may exist in its single-celled form or as a colony of cells. The possible existence of unseen microbial life was suspected from antiquity, with an early attestation in Jain literature authored in 6th-century BC India. The scientific study of microorganisms began with their observation under the microscope in the 1670s by Anton van Leeuwenhoek. In the 1850s, Louis Pasteur found that microorganisms caused food spoilage, debunking the theory of spontaneous generation. In the 1880s, Robert Koch discovered that microorganisms caused the diseases tuberculosis, cholera, diphtheria, and anthrax. Microorganisms are extremely diverse, representing most unicellular organisms in all three domains of life: two of the three domains, Archaea and Bacteria, only contain microorganisms. The third domain, Eukaryota, includes all multicellular organisms as well as many unicellular protists and protozoans that are ...
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Concentration Cell
In battery technology, a concentration cell is a limited form of a galvanic cell that has two equivalent half-cells of the same composition differing only in concentrations. One can calculate the potential developed by such a cell using the Nernst equation.Almost any textbook on physical chemistry, e.g. by I. N. Levine or P. W. Atkins, and also many general chemistry texts. A concentration cell produces a small voltage as it attempts to reach chemical equilibrium, which occurs when the concentration of reactant in both half-cells are equal. Because an order of magnitude concentration difference produces less than 60 millivolts at room temperature, concentration cells are not typically used for energy storage. A concentration cell generates electricity from the reduction in the thermodynamic free energy of the electrochemical system as the difference in the chemical concentrations in the two half-cells is reduced. The same reaction occurs in the half-cells but in opposite dir ...
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Hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the chemical formula, formula , called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas (dihydrogen) and in molecular forms, such as in water and organic compounds. The most common isotope of hydrogen (H) consists of one proton, one electron, and no neutrons. Hydrogen gas was first produced artificially in the 17th century by the reaction of acids with metals. Henry Cavendish, in 1766–1781, identified hydrogen gas as a distinct substance and discovere ...
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Sodium Chloride
Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and curing (food preservation), food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further Chemical synthesis, chemical syntheses. Another major application of sodium chloride is deicing of roadways in sub-freezing weather. Uses In addition to the many familiar domestic uses of salt, more dominant applications of the approximately 250 million tonnes per year production (2008 data) include chemicals and de-icing.Westphal, Gisbert ''et al.'' (2002) "Sodium Chloride" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim . Chem ...
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Anaerobic Organism
An anaerobic organism or anaerobe is any organism that does not require oxygen, molecular oxygen for growth. It may react negatively or even die if free oxygen is present. In contrast, an aerobic organism (aerobe) is an organism that requires an oxygenated environment. Anaerobes may be unicellular (e.g. protozoans, bacteria) or multicellular. Most fungi are obligate aerobes, requiring oxygen to survive. However, some species, such as the Chytridiomycota that reside in the rumen of cattle, are obligate anaerobes; for these species, anaerobic respiration is used because oxygen will disrupt their metabolism or kill them. The sea floor is possibly one of the largest accumulation of anaerobic organisms on Earth, where microbes are primarily concentrated around Hydrothermal_vent, hydrothermal vents. These microbes produce energy in absence of sunlight or oxygen through a process called chemosynthesis, whereby inorganic compounds such as hydrogen gas, hydrogen sulfide or ferrous ions are ...
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Biogenic Sulfide Corrosion
Biogenic sulfide corrosion is a bacterially mediated process of forming hydrogen sulfide gas and the subsequent conversion to sulfuric acid that attacks concrete and steel within wastewater environments. The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid. The effect of sulfuric acid on concrete and steel surfaces exposed to severe wastewater environments can be devastating. In the USA alone, corrosion causes sewer asset losses estimated at $14 billion per year. This cost is expected to increase as the aging infrastructure continues to fail. Environment Corrosion may occur where stale sewage generates hydrogen sulfide gas into an atmosphere containing oxygen gas and high relative humidity. There must be an underlying anaerobic aquatic habitat containing sulfates and an overlying aerobic aquatic habitat separated by a gas phase containing both oxygen and hydrogen sulfide at concentrations in excess of 2 ppm.Sawyer&McCarty p.461&462 ...
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Aerobic Organism
An aerobic organism or aerobe is an organism that can survive and grow in an oxygenated environment. The ability to exhibit aerobic respiration may yield benefits to the aerobic organism, as aerobic respiration yields more energy than anaerobic respiration. Energy production of the cell involves the synthesis of ATP by an enzyme called ATP synthase. In aerobic respiration, ATP synthase is coupled with an electron transport chain in which oxygen acts as a terminal electron acceptor. In July 2020, marine biologists reported that aerobic microorganisms (mainly), in " quasi-suspended animation", were found in organically poor sediments, up to 101.5 million years old, 250 feet below the seafloor in the South Pacific Gyre (SPG) ("the deadest spot in the ocean"), and could be the longest-living life forms ever found. Types * Obligate aerobes need oxygen to grow. In a process known as cellular respiration, these organisms use oxygen to oxidize substrates (for example sugars and ...
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Ammonia
Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pungent smell. It is widely used in fertilizers, refrigerants, explosives, cleaning agents, and is a precursor for numeous chemicals. Biologically, it is a common nitrogenous waste, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers. Around 70% of ammonia produced industrially is used to make fertilisers in various forms and composition, such as urea and diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many chemicals. In many countries, it is classified as an List of extremely hazardous substances, extremely hazardous substance. Ammonia is toxic, cau ...
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Acid
An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid. The first category of acids are the proton donors, or Brønsted–Lowry acid–base theory, Brønsted–Lowry acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Acid–base reaction#Arrhenius theory, Arrhenius acids. Johannes Nicolaus Brønsted, Brønsted and Martin Lowry, Lowry generalized the Arrhenius theory to include non-aqueous solvents. A Brønsted–Lowry or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+. Aqueous Arrhenius acids have characteristic properties that provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and ...
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RMS Titanic
RMS ''Titanic'' was a British ocean liner that Sinking of the Titanic, sank in the early hours of 15 April 1912 as a result of striking Iceberg that struck the Titanic, an iceberg on her maiden voyage from Southampton, England, to New York City, United States. Of the Sinking of the Titanic#Casualties and survivors, estimated 2,224 passengers and crew aboard, approximately 1,500 died (estimates vary), making the incident one of List of accidents and disasters by death toll#Peacetime maritime, the deadliest peacetime sinkings of a single ship. ''Titanic'', operated by White Star Line, carried some of the wealthiest people in the world, as well as hundreds of emigrants from the British Isles, Scandinavia, and elsewhere in Europe who were seeking a new life in the United States and Canada. The disaster drew public attention, spurred major changes in maritime safety regulations, and inspired a Titanic in popular culture, lasting legacy in popular culture. It was the second time Whit ...
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Rusticle
A rusticle is a formation of rust similar to an icicle or stalactite in appearance that occurs deep underwater when iron-loving bacteria attack and redox, oxidize wrought iron and steel. They may be familiar from underwater photographs of shipwrecks, such as the wreck of the Titanic, RMS ''Titanic'' and the German battleship Bismarck#Wreckage, German battleship ''Bismarck''. They have also been found in the #3 8-inch gun turret on the stern of the USS Indianapolis (CA-35), USS ''Indianapolis''. The word ''rusticle'' is a blend word, portmanteau of the words ''rust'' and ''icicle'' and was coined by Robert Ballard, who first observed them on the wreck of the RMS Titanic, ''Titanic'' in 1986. Rusticles on the ''Titanic'' were first investigated in 1996 by Roy Cullimore, based at the University of Regina in Canada. A previously unknown species of bacteria living inside the ''Titanic''s rusticles called ''Halomonas titanicae'' was discovered in 2010 by Henrietta Mann. Rusticles can fo ...
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