Ionization
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Ionization
Ionization or ionisation is the process by which an atom or a molecule acquires a negative or positive Electric charge, charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule is called an ion. Ionization can result from the loss of an electron after collisions with subatomic particles, collisions with other atoms, molecules, electrons, positrons, protons, antiprotons, and ions, or through the interaction with electromagnetic radiation. Heterolytic bond cleavage and heterolytic substitution reactions can result in the formation of ion pairs. Ionization can occur through radioactive decay by the internal conversion process, in which an excited nucleus transfers its energy to one of the inner-shell electrons causing it to be ejected. Uses Everyday examples of gas ionization occur within a fluorescent lamp or other electrical discharge lamps. It is also used in radiation detectors such as the Geiger- ...
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Ionization Energy
In physics and chemistry, ionization energy (IE) is the minimum energy required to remove the most loosely bound electron of an isolated gaseous atom, Ion, positive ion, or molecule. The first ionization energy is quantitatively expressed as :X(g) + energy ⟶ X+(g) + e− where X is any atom or molecule, X+ is the resultant ion when the original atom was stripped of a single electron, and e− is the removed electron. Ionization energy is positive for neutral atoms, meaning that the ionization is an endothermic process. Roughly speaking, the closer the outermost electrons are to the atomic nucleus, nucleus of the atom, the higher the atom's ionization energy. In physics, ionization energy (IE) is usually expressed in electronvolts (eV) or joules (J). In chemistry, it is expressed as the energy to ionize a Mole (unit), mole of atoms or molecules, usually as Joule per mole, kilojoules per mole (kJ/mol) or Kilocalorie per mole, kilocalories per mole (kcal/mol). Comparison of ion ...
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Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionization, ionized, for example by bombarding it with a Electron ionization, beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragmen ...
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Electron Capture Ionization
Electron capture ionization is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A^-. The reaction is :A + e^- -> ^- where the M over the arrow denotes that to conserve energy and momentum a third body is required (the molecularity of the reaction is three). Electron capture can be used in conjunction with chemical ionization. Electron-capture mass spectrometry Electron-capture mass spectrometry (EC-MS) is a type of mass spectrometry that uses electron capture ionization to form negative ions from chemical compounds with positive electron affinities. The approach is particularly effective for electrophiles. In contrast to electron ionization, EC-MS uses low energy electrons in a gas discharge. EC-MS will cause less fragmentation of molecules compared to electron ionization. Negative ion formation Resonance electron capture Resonance electron capture is also known as nondissociative EC. The compound captures an electron ...
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Ionization Chamber
The ionization chamber is the simplest type of gaseous ionisation detector, and is widely used for the detection and measurement of many types of ionizing radiation, including X-rays, gamma rays, alpha particles and beta particles. Conventionally, the term "ionization chamber" refers exclusively to those detectors which collect all the charges created by ''direct ionization'' within the gas through the application of an electric field. It uses the discrete charges created by each interaction between the incident radiation and the gas to produce an output in the form of a small direct current. This means individual ionising events cannot be measured, so the energy of different types of radiation cannot be differentiated, but it gives a very good measurement of overall ionising effect. It has a good uniform response to radiation over a wide range of energies and is the preferred means of measuring high levels of gamma radiation, such as in a hot cell, radiation hot cell as they ca ...
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Geiger-Müller Counter
A Geiger counter (, ; also known as a Geiger–Müller counter or G-M counter) is an electronic instrument for detecting and measuring ionizing radiation with the use of a Geiger–Müller tube. It is widely used in applications such as radiation dosimetry, radiological protection, experimental physics and the nuclear industry. "Geiger counter" is often used generically to refer to any form of dosimeter (or, ''radiation-measuring device''), but scientifically, a Geiger counter is only one specific type of dosimeter. It detects ionizing radiation such as alpha particles, beta particles, and gamma rays using the ionization effect produced in a Geiger–Müller tube, which gives its name to the instrument. In wide and prominent use as a hand-held radiation survey instrument, it is perhaps one of the world's best-known radiation detection instruments. The original detection principle was realized in 1908 at the University of Manchester, but it was not until the development o ...
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Kinematically Complete Experiment
In accelerator physics, a kinematically complete experiment is an experiment in which all kinematic parameters of all collision products are determined. If the final state of the collision involves n particles 3n momentum components (3 Cartesian coordinates for each particle) need to be determined. However, these components are linked to each other by momentum conservation in each direction (3 equations) and energy conservation (1 equation) so that only 3n-4 components are linearly independent. Therefore, the measurement of 3n-4 momentum components constitutes a kinematically complete experiment. If the final state involves only two particles (e.g. in the Rutherford experiment on elastic scattering) then only one particle needs to be detected. However, for processes leading to three collision products, like e.g. single ionization of the target atom, then two particles need to be momentum-analyzed (for one of them it is sufficient to measure two momentum components) and measur ...
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Atom
Atoms are the basic particles of the chemical elements. An atom consists of a atomic nucleus, nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element. Atoms are extremely small, typically around 100 picometers across. A human hair is about a million carbon atoms wide. Atoms are smaller than the shortest wavelength of visible light, which means humans cannot see atoms with conventional microscopes. They are so small that accurately predicting their behavior using classical physics is not possible due to quantum mechanics, quantum effects. More than 99.94% of an atom's mass is in the nucleus. Protons hav ...
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Townsend Discharge
In electromagnetism, the Townsend discharge or Townsend avalanche is an ionisation process for gases where free electrons are accelerated by an electric field, collide with gas molecules, and consequently free additional electrons. Those electrons are in turn accelerated and free additional electrons. The result is an avalanche multiplication that permits significantly increased electrical conduction through the gas. The discharge requires a source of free electrons and a significant electric field; without both, the phenomenon does not occur. The Townsend discharge is named after John Sealy Townsend, who discovered the fundamental ionisation mechanism by his work circa 1897 at the Cavendish Laboratory, Cambridge. General description The avalanche occurs in a gaseous medium that can be ionised (such as air). The electric field and the mean free path of the electron must allow free electrons to acquire an energy level (velocity) that can cause impact ionisation. If the ...
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Radiation Therapy
Radiation therapy or radiotherapy (RT, RTx, or XRT) is a therapy, treatment using ionizing radiation, generally provided as part of treatment of cancer, cancer therapy to either kill or control the growth of malignancy, malignant cell (biology), cells. It is normally delivered by a linear particle accelerator. Radiation therapy may be cure, curative in a number of types of cancer if they are localized to one area of the body, and have not metastasis, spread to other parts. It may also be used as part of adjuvant therapy, to prevent tumor recurrence after surgery to remove a primary malignant tumor (for example, early stages of breast cancer). Radiation therapy is synergistic with chemotherapy, and has been used before, during, and after chemotherapy in susceptible cancers. The subspecialty of oncology concerned with radiotherapy is called radiation oncology. A physician who practices in this subspecialty is a radiation oncologist. Radiation therapy is commonly applied to the canc ...
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Aurora In Abisko Near Torneträsk
An aurora ( aurorae or auroras), also commonly known as the northern lights (aurora borealis) or southern lights (aurora australis), is a natural light display in Earth's sky, predominantly observed in high-latitude regions (around the Arctic and Antarctic). Auroras display dynamic patterns of radiant lights that appear as curtains, rays, spirals or dynamic flickers covering the entire sky. Auroras are the result of disturbances in the Earth's magnetosphere caused by enhanced speeds of solar wind from coronal holes and coronal mass ejections. These disturbances alter the trajectories of charged particles in the magnetospheric plasma. These particles, mainly electrons and protons, precipitate into the upper atmosphere ( thermosphere/ exosphere). The resulting ionization and excitation of atmospheric constituents emit light of varying color and complexity. The form of the aurora, occurring within bands around both polar regions, is also dependent on the amount of acce ...
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Electron Avalanche
An electron avalanche is a process in which a number of free electrons in a transmission medium are subjected to strong acceleration by an electric field and subsequently collide with other atoms of the medium, thereby ionizing them ( impact ionization). This releases additional electrons which accelerate and collide with further atoms, releasing more electrons—a chain reaction. In a gas, this causes the affected region to become an electrically conductive plasma. The avalanche effect was discovered by John Sealy Townsend in his work between 1897 and 1901, and is also known as the Townsend discharge. Electron avalanches are essential to the dielectric breakdown process within gases. The process can culminate in corona discharges, streamers, leaders, or in a spark or continuous arc that completely bridges the gap between the electrical conductors that are applying the voltage. The process extends to huge sparks — streamers in lightning discharges propagate by forma ...
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Energy State
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized. In chemistry and atomic physics, an electron shell, or principal energy level, may be thought of as the orbit of one or more electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus. The shells correspond with the princi ...
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