Liquid Phase Exfoliation
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Liquid Phase Exfoliation
First demonstrated in 2008, Liquid-phase exfoliation (LPE) is a solution-processing method which is used to convert layered crystals into 2-dimensional nanosheets in large quantities. It is currently one of the pillar methods for producing 2D nanosheets. According to IDTechEx, the family of exfoliation techniques which are directly or indirectly descended from LPE now make up over 60% of global graphene production capacity. This method involves adding powdered layered crystals, for example of graphite, to appropriate solvents and inserting energy, often by ultrasonication, although high-shear mixing is often commonly used. The addition of energy causes a combination of fragmentation and exfoliation resulting in the removal of small nanosheets from the layered crystals. In this way graphite can be converted into large quantities of graphene nanosheets. In general, these nanosheets tend to be a few monolayers thick and of lateral sizes ranging from tens of nanometers to many micron ...
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Nanosheet
A nanosheet is a two-dimensional nanostructure with thickness in a scale ranging from 1 to 100 nm. A typical example of a nanosheet is graphene, the thinnest two-dimensional material (0.34 nm) in the world. It consists of a single layer of carbon atoms with hexagonal lattices. Examples and applications , Silicon nanosheets are being used to prototype future generations of small (5 nm) transistors. Carbon nanosheets (from hemp) may be an alternative to graphene as electrodes in supercapacitors. Synthesis The most commonly used nanosheet synthesis methods use a bottom-up approach, e.g., pre-organization and polymerization at interfaces like Langmuir–Blodgett films, solution phase synthesis and chemical vapor deposition (CVD). For example, CdTe (cadmium telluride) nanosheets could be synthesized by precipitating and aging CdTe nanoparticles in deionized water. The formation of free-floating CdTe nanosheets was due to directional hydrophobic attraction and an ...
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Inkjet Printing
Inkjet printing is a type of computer printing that recreates a digital image by propelling droplets of ink onto paper and plastic substrates. Inkjet printers were the most commonly used type of printer in 2008, and range from small inexpensive consumer models to expensive professional machines. By 2019, laser printers outsold inkjet printers by nearly a 2:1 ratio, 9.6% vs 5.1% of all computer peripherals. The concept of inkjet printing originated in the 20th century, and the technology was first extensively developed in the early 1950s. While working at Canon in Japan, Ichiro Endo suggested the idea for a "Bubble jet" printer, while around the same time Jon Vaught at HP was developing a similar idea. In the late 1970s, inkjet printers that could reproduce digital images generated by computers were developed, mainly by Epson, Hewlett-Packard (HP) and Canon. In the worldwide consumer market, four manufacturers account for the majority of inkjet printer sales: Canon, HP, ...
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Early TEM Image Of LPE Graphene Dublin
Early may refer to: History * The beginning or oldest part of a defined historical period, as opposed to middle or late periods, e.g.: ** Early Christianity ** Early modern Europe Places in the United States * Early, Iowa * Early, Texas * Early Branch, a stream in Missouri * Early County, Georgia Other uses * ''Early'' (Scritti Politti album), 2005 * ''Early'' (A Certain Ratio album), 2002 * Early (name) * Early effect, an effect in transistor physics * Early Records, a record label * the early part of the morning See also * Earley (other) Earley is a town in England. Earley may also refer to: * Earley (surname), a list of people with the surname Earley * Earley (given name), a variant of the given name Earlene * Earley Lake, a lake in Minnesota *Earley parser, an algorithm *Earley ...
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Graphene Oxide
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 (called a passivation layer) that protects the foil from further corrosion.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Stoichiometry (the measurable relationship between reactants and chemical equations of a equation or reaction) Oxides are extraordinarily diverse in terms of stoichiometries and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistr ...
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Jet Mill
A jet mill grinds materials by using a high speed jet of compressed air or inert gas to impact particles into each other. Jet mills can be designed to output particles below a certain size while continuing to mill particles above that size, resulting in a narrow size distribution of the resulting product. Particles leaving the mill can be separated from the gas stream by cyclonic separation. Particle size A jet mill consists of a short cylinder, meaning the cylinder's height is less than its diameter. Compressed gas is forced into the mill through nozzles tangent to the cylinder wall, creating a vortex. The gas leaves the mill through a tube along the axis of the cylinder. Solid particles in the mill are subject to two competing forces: # Centrifugal force created by the particles traveling in circles # Centripetal force created by the drag from the gas as it flows from the nozzles along the wall to the outlet in the center of the mill The drag on small particles is less ...
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Microfluid
Microfluidics refers to the behavior, precise control, and manipulation of fluids that are geometrically constrained to a small scale (typically sub-millimeter) at which surface forces dominate volumetric forces. It is a multidisciplinary field that involves engineering, physics, chemistry, biochemistry, nanotechnology, and biotechnology. It has practical applications in the design of systems that process low volumes of fluids to achieve multiplexing, automation, and high-throughput screening. Microfluidics emerged in the beginning of the 1980s and is used in the development of inkjet printheads, DNA chips, lab-on-a-chip technology, micro-propulsion, and micro-thermal technologies. Typically, micro means one of the following features: * Small volumes (μL, nL, pL, fL) * Small size * Low energy consumption * Microdomain effects Typically microfluidic systems transport, mix, separate, or otherwise process fluids. Various applications rely on passive fluid control using capillary ...
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Ball Mill
A ball mill is a type of grinder used to grind or blend materials for use in mineral dressing processes, paints, pyrotechnics, ceramics, and selective laser sintering. It works on the principle of impact and attrition: size reduction is done by impact as the balls drop from near the top of the shell. A ball mill consists of a hollow cylindrical shell rotating about its axis. The axis of the shell may be either horizontal or at a small angle to the horizontal. It is partially filled with balls. The grinding media are the balls, which may be made of steel (chrome steel), stainless steel, ceramic, or rubber. The inner surface of the cylindrical shell is usually lined with an abrasion-resistant material such as manganese steel or rubber lining. Less wear takes place in rubber lined mills. The length of the mill is approximately equal to its diameter. The general idea behind the ball mill is an ancient one, but it was not until the industrial revolution and the invention of ...
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Nanocomposite
Nanocomposite is a multiphase solid material where one of the phases has one, two or three dimensions of less than 100 nanometers (nm) or structures having nano-scale repeat distances between the different phases that make up the material. The idea behind Nanocomposite is to use building blocks with dimensions in nanometre range to design and create new materials with unprecedented flexibility and improvement in their physical properties. In the broadest sense this definition can include porous media, colloids, gels and copolymers, but is more usually taken to mean the solid combination of a bulk matrix and nano-dimensional phase(s) differing in properties due to dissimilarities in structure and chemistry. The mechanical, electrical, thermal, optical, electrochemical, catalytic properties of the nanocomposite will differ markedly from that of the component materials. Size limits for these effects have been proposed: in Kelly, A, ''Concise encyclopedia of composites materials'', El ...
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Black Phosphorus
Elemental phosphorus can exist in several allotropes, the most common of which are white and red solids. Solid violet and black allotropes are also known. Gaseous phosphorus exists as diphosphorus and atomic phosphorus. White phosphorus White phosphorus, yellow phosphorus or simply tetraphosphorus () exists as molecules made up of four atoms in a tetrahedral structure. The tetrahedral arrangement results in ring strain and instability. The molecule is described as consisting of six single P–P bonds. Two crystalline forms are known. The α form is defined as the standard state of the element, but is actually metastable under standard conditions. It has a body-centered cubic crystal structure, and transforms reversibly into the β form at 195.2 K. The β form is believed to have a hexagonal crystal structure. White phosphorus is a translucent waxy solid that quickly becomes yellow when exposed to light. For this reason it is also called yellow phosphorus. It glows greeni ...
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Solvent
A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for polar molecules and the most common solvent used by living things; all the ions and proteins in a cell are dissolved in water within the cell. The quantity of solute that can dissolve in a specific volume of solvent varies with temperature. Major uses of solvents are in paints, paint removers, inks, and dry cleaning. Specific uses for organic solvents are in dry cleaning (e.g. tetrachloroethylene); as paint thinners ( toluene, turpentine); as nail polish removers and solvents of glue (acetone, methyl acetate, ethyl acetate); in spot removers ( hexane, petrol ether); in detergents ( citrus terpenes); and in perfumes (ethanol). Solvents find various applications in chemical, pharmaceutical, oil, and gas industries, including in chemic ...
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Germanium Monosulfide
Germanium monosulfide or Germanium(II) sulfide is the chemical compound with the formula Ge S. It is a chalcogenide glass and a semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. .... Germanium sulfide is described as a red-brown powder or black crystals. Germanium(II) sulfide when dry is stable in air, hydrolyzes slowly in moist air but rapidly reacts in water forming Ge(OH)2 and then GeO.E. G. Rochow, E. W. Abel ,1973, The Chemistry of Germanium Tin and Lead, Pergamon Press, It is one of a few sulfides that can be sublimed under vacuum without decomposition. Preparation First made by Winkler by reducing GeS2 with Ge. Other methods include reduction in a stream of H2 gas, or with an excess of H3PO2 followed by vacuum sublimation. Structure It has a layer structur ...
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