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Laws Of Thermodynamics
The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion. In addition to their use in thermodynamics, they are important fundamental laws of physics in general, and are applicable in other natural sciences. Traditionally, thermodynamics has recognized three fundamental laws, simply named by an ordinal identification, the first law, the second law, and the third law.Guggenheim, E.A. (1985). ''Thermodynamics. An Advanced Treatment for Chemists and Physicists'', seventh edition, North Holland, Amsterdam, .Kittel, C. Kroemer, H. (1980). ''Thermal Physics'', second edi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scientific Law
Scientific laws or laws of science are statements, based on repeated experiments or observations, that describe or predict a range of natural phenomena. The term ''law'' has diverse usage in many cases (approximate, accurate, broad, or narrow) across all fields of natural science (physics, chemistry, astronomy, geoscience, biology). Laws are developed from data and can be further developed through mathematics; in all cases they are directly or indirectly based on empirical evidence. It is generally understood that they implicitly reflect, though they do not explicitly assert, causal relationships fundamental to reality, and are discovered rather than invented. Scientific laws summarize the results of experiments or observations, usually within a certain range of application. In general, the accuracy of a law does not change when a new theory of the relevant phenomenon is worked out, but rather the scope of the law's application, since the mathematics or statement representing ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
First Law Of Thermodynamics
The first law of thermodynamics is a formulation of the law of conservation of energy, adapted for thermodynamic processes. It distinguishes in principle two forms of energy transfer, heat and thermodynamic work for a system of a constant amount of matter. The law also defines the internal energy of a system, an extensive property for taking account of the balance of energies in the system. The law of conservation of energy states that the total energy of any isolated system, which cannot exchange energy or matter, is constant. Energy can be transformed from one form to another, but can be neither created nor destroyed. The first law for a thermodynamic process is often formulated asThe sign convention (Q is heat supplied ''to'' the system but W is work done ''by'' the system) is that of Rudolf Clausius (Equation IIa on page 384 of Clausius, R. (1850)), and it is followed below. :\Delta U = Q - W, where \Delta U denotes the change in the internal energy of a closed syst ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reflections On The Motive Power Of Fire
''Reflections on the Motive Power of Fire and on Machines Fitted to Develop that Power'' is a book published in 1824 by French physicist Sadi Carnot.full text of 1897 ed. ( Full text of 1897 edition on Wikisource ) The 118-page book's French title was ''Réflexions sur la puissance motrice du feu et sur les machines propres à développer cette puissance''. It is a significant publication in the history of thermodynamics about a generalized theory of heat engines. Overview The book is considered the founding work of thermodynamics. It contains the preliminary outline of the second law of thermodynamics. Carnot stated that motive power is due to the fall of caloric (heat) from a hot to a cold body. The work was unnoticed until 1834 when French mining engineer Émile Clapeyron put it on a graphical footing in his ''Memoir on the Motive Power of Heat''. Through Clapeyron's paper, German physicist Rudolf Clausius learned of Carnot's theory of heat and through a modification of Ca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nicolas Léonard Sadi Carnot
''Sous-lieutenant'' Nicolas Léonard Sadi Carnot (; 1 June 1796 – 24 August 1832) was a French mechanical engineer in the French Army, military scientist and physicist, and often described as the "father of thermodynamics". He published only one book, the '' Reflections on the Motive Power of Fire'' (Paris, 1824), in which he expressed the first successful theory of the maximum efficiency of heat engines and laid the foundations of the new discipline: thermodynamics. Carnot's work attracted little attention during his lifetime, but it was later used by Rudolf Clausius and Lord Kelvin to formalize the second law of thermodynamics and define the concept of entropy. Based on purely technical concerns, such as improving the performance of the steam engine, Sadi Carnot's intellect laid the groundwork for modern science technological designs, such as the automobile or jet engine. His father Lazare Carnot was an eminent mathematician, military engineer, and leader of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
History Of Chemistry
The history of chemistry represents a time span from ancient history to the present. By 1000 BC, civilizations used technologies that would eventually form the basis of the various branches of chemistry. Examples include the discovery of fire, extracting metals from ores, making pottery and glazes, fermenting beer and wine, extracting chemicals from plants for medicine and perfume, rendering fat into soap, making glass, and making alloys like bronze. The protoscience of chemistry, alchemy, was unsuccessful in explaining the nature of matter and its transformations. However, by performing experiments and recording the results, alchemists set the stage for modern chemistry. While both alchemy and chemistry are concerned with matter and its transformations, chemists are seen as applying scientific method to their work. The history of chemistry is intertwined with the history of thermodynamics, especially through the work of Willard Gibbs. Ancient history Early humans A 100,00 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
History Of Physics
Physics is a branch of science whose primary objects of study are matter and energy. Discoveries of physics find applications throughout the natural sciences and in technology. Physics today may be divided loosely into classical physics and modern physics. Ancient history Elements of what became physics were drawn primarily from the fields of astronomy, optics, and mechanics, which were methodologically united through the study of geometry. These mathematical disciplines began in antiquity with the Babylonians and with Hellenistic writers such as Archimedes and Ptolemy. Ancient philosophy, meanwhile, included what was called "Physics". ''Greek concept'' The move towards a rational understanding of nature began at least since the Archaic period in Greece (650–480 BCE) with the Pre-Socratic philosophers. The philosopher Thales of Miletus (7th and 6th centuries BCE), dubbed "the Father of Science" for refusing to accept various supernatural, religious or mythological explan ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perpetual Motion Machine Of The Second Kind
Perpetual motion is the motion of bodies that continues forever in an unperturbed system. A perpetual motion machine is a hypothetical machine that can do work infinitely without an external energy source. This kind of machine is impossible, as it would violate either the first or second law of thermodynamics or both. These laws of thermodynamics apply regardless of the size of the system. For example, the motions and rotations of celestial bodies such as planets may appear perpetual, but are actually subject to many processes that slowly dissipate their kinetic energy, such as solar wind, interstellar medium resistance, gravitational radiation and thermal radiation, so they will not keep moving forever. Thus, machines that extract energy from finite sources will not operate indefinitely, because they are driven by the energy stored in the source, which will eventually be exhausted. A common example is devices powered by ocean currents, whose energy is ultimately derived fro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perpetual Motion Machine Of The First Kind
Perpetual motion is the motion of bodies that continues forever in an unperturbed system. A perpetual motion machine is a hypothetical machine that can do work infinitely without an external energy source. This kind of machine is impossible, as it would violate either the first or second law of thermodynamics or both. These laws of thermodynamics apply regardless of the size of the system. For example, the motions and rotations of celestial bodies such as planets may appear perpetual, but are actually subject to many processes that slowly dissipate their kinetic energy, such as solar wind, interstellar medium resistance, gravitational radiation and thermal radiation, so they will not keep moving forever. Thus, machines that extract energy from finite sources will not operate indefinitely, because they are driven by the energy stored in the source, which will eventually be exhausted. A common example is devices powered by ocean currents, whose energy is ultimately derived fro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Glass
Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling ( quenching) of the molten form; some glasses such as volcanic glass are naturally occurring. The most familiar, and historically the oldest, types of manufactured glass are "silicate glasses" based on the chemical compound silica (silicon dioxide, or quartz), the primary constituent of sand. Soda–lime glass, containing around 70% silica, accounts for around 90% of manufactured glass. The term ''glass'', in popular usage, is often used to refer only to this type of material, although silica-free glasses often have desirable properties for applications in modern communications technology. Some objects, such as drinking glasses and eyeglasses, are so commonly made of silicate-based glass that they are simply called by the name of the material. D ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absolute Zero
Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical, zero-point energy-induced particle motion. The theoretical temperature is determined by extrapolating the ideal gas law; by international agreement, absolute zero is taken as −273.15 degrees on the Celsius scale ( International System of Units), Note: The triple point of water is 0.01 °C, not 0 °C; thus 0 K is −2890.15 °C, not −273.16 °C. which equals −459.67 degrees on the Fahrenheit scale (United States customary units or Imperial units). The corresponding Kelvin and Rankine temperature scales set their zero points at absolute zero by definition. It is commonly thought of as the lowest temperature possible, but it is not the lowest ''enthalpy'' state ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Third Law Of Thermodynamics
The third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: This constant value cannot depend on any other parameters characterizing the closed system, such as pressure or applied magnetic field. At absolute zero (zero kelvins) the system must be in a state with the minimum possible energy. Entropy is related to the number of accessible microstates, and there is typically one unique state (called the ground state) with minimum energy. In such a case, the entropy at absolute zero will be exactly zero. If the system does not have a well-defined order (if its order is glassy, for example), then there may remain some finite entropy as the system is brought to very low temperatures, either because the system becomes locked into a configuration with non-minimal energy or because the minimum energy state is non-unique. The constant value is called the residual entropy of the system. The entropy is essentially a state-function meaning t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Second Law Of Thermodynamics
The second law of thermodynamics is a physical law based on universal experience concerning heat and energy interconversions. One simple statement of the law is that heat always moves from hotter objects to colder objects (or "downhill"), unless energy in some form is supplied to reverse the direction of heat flow. Another definition is: "Not all heat energy can be converted into work in a cyclic process."Young, H. D; Freedman, R. A. (2004). ''University Physics'', 11th edition. Pearson. p. 764. The second law of thermodynamics in other versions establishes the concept of entropy as a physical property of a thermodynamic system. It can be used to predict whether processes are forbidden despite obeying the requirement of conservation of energy as expressed in the first law of thermodynamics and provides necessary criteria for spontaneous processes. The second law may be formulated by the observation that the entropy of isolated systems left to spontaneous evolution cannot decr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
