Ion Cyclotron Resonance
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Ion Cyclotron Resonance
Ion cyclotron resonance is a phenomenon related to the movement of ions in a magnetic field. It is used for accelerating ions in a cyclotron, and for measuring the masses of an ionized analyte in mass spectrometry, particularly with Fourier transform ion cyclotron resonance mass spectrometers. It can also be used to follow the kinetics of chemical reactions in a dilute gas mixture, provided these involve charged species. Definition of the resonant frequency An ion in a static and uniform magnetic field will move in a circle due to the Lorentz force. The angular frequency of this ''cyclotron motion'' for a given magnetic field strength ''B'' is given by :\omega = 2\pi f = \frac, where ''z'' is the number of positive or negative charges of the ion, ''e'' is the elementary charge and ''m'' is the mass of the ion. An electric excitation signal having a frequency ''f'' will therefore resonate with ions having a mass-to-charge ratio ''m/z'' given by :\frac = \frac. The circular motio ...
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Ions
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron an ...
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Cycloid
In geometry, a cycloid is the curve traced by a point on a circle as it rolls along a straight line without slipping. A cycloid is a specific form of trochoid and is an example of a roulette, a curve generated by a curve rolling on another curve. The cycloid, with the cusps pointing upward, is the curve of fastest descent under uniform gravity (the brachistochrone curve). It is also the form of a curve for which the period of an object in simple harmonic motion (rolling up and down repetitively) along the curve does not depend on the object's starting position (the tautochrone curve). History The cycloid has been called "The Helen of Geometers" as it caused frequent quarrels among 17th-century mathematicians. Historians of mathematics have proposed several candidates for the discoverer of the cycloid. Mathematical historian Paul Tannery cited similar work by the Syrian philosopher Iamblichus as evidence that the curve was known in antiquity. English mathematician ...
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Ion Source
An ion source is a device that creates atomic and molecular ions. Ion sources are used to form ions for mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters and ion engines. Electron ionization Electron ionization is widely used in mass spectrometry, particularly for organic molecules. The gas phase reaction producing electron ionization is :M + e^- -> M^ + 2e^- where M is the atom or molecule being ionized, e^- is the electron, and M^ is the resulting ion. The electrons may be created by an arc discharge between a cathode and an anode. An electron beam ion source (EBIS) is used in atomic physics to produce highly charged ions by bombarding atoms with a powerful electron beam. Its principle of operation is shared by the electron beam ion trap. Electron capture ionization Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A−•. The reacti ...
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Electric And Magnetic Fields In Matter
Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwell's equations. Various common phenomena are related to electricity, including lightning, static electricity, electric heating, electric discharges and many others. The presence of an electric charge, which can be either positive or negative, produces an electric field. The movement of electric charges is an electric current and produces a magnetic field. When a charge is placed in a location with a non-zero electric field, a force will act on it. The magnitude of this force is given by Coulomb's law. If the charge moves, the electric field would be doing work on the electric charge. Thus we can speak of electric potential at a certain point in space, which is equal to the work done by an external agent in carrying a unit of p ...
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Condensed Matter Physics
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with "condensed" phases of matter: systems of many constituents with strong interactions between them. More exotic condensed phases include the superconducting phase exhibited by certain materials at low temperature, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other theories to develop mathematical models. The diversity of systems and phenomena available for study makes condensed matte ...
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Electron Cyclotron Resonance
Electron cyclotron resonance (ECR) is a phenomenon observed in plasma physics, condensed matter physics, and accelerator physics. It happens when the frequency of incident radiation coincides with the natural frequency of rotation of electrons in magnetic fields. A free electron in a static and uniform magnetic field will move in a circle due to the Lorentz force. The circular motion may be superimposed with a uniform axial motion, resulting in a helix, or with a uniform motion perpendicular to the field (e.g., in the presence of an electrical or gravitational field) resulting in a cycloid. The angular frequency (ω = 2π ''f'' ) of this ''cyclotron'' motion for a given magnetic field strength ''B'' is given (in SI units) by :\omega_\text = \frac. where e is the elementary charge and m is the mass of the electron. For the commonly used microwave frequency 2.45 GHz and the bare electron charge and mass, the resonance condition is met when ''B'' = 875 G = 0.0875 T. For ...
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Cyclotron Resonance
Cyclotron resonance describes the interaction of external forces with charged particles experiencing a magnetic field, thus already moving on a circular path. It is named after the cyclotron, a cyclic particle accelerator that utilizes an oscillating electric field tuned to this resonance to add kinetic energy to charged particles. Cyclotron resonance frequency The cyclotron frequency or gyrofrequency is the frequency of a charged particle moving perpendicular to the direction of a uniform magnetic field ''B'' (constant magnitude and direction). Since that motion is always circular,Physics by M. Alonso & E. Finn, Addison Wesley 1996. the cyclotron frequency is given by equality of centripetal force and magnetic Lorentz force :\frac = qBv with the particle mass ''m'', its charge ''q'', velocity ''v'', and the circular path radius ''r'', also called gyroradius. The angular speed of the rotation is then: :\omega = \frac = \frac. Giving the rotational frequency (being the cyclotron ...
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Solar Wind
The solar wind is a stream of charged particles released from the upper atmosphere of the Sun, called the corona. This plasma mostly consists of electrons, protons and alpha particles with kinetic energy between . The composition of the solar wind plasma also includes a mixture of materials found in the solar plasma: trace amounts of heavy ions and atomic nuclei such as C, N, O, Ne, Mg, Si, S, and Fe. There are also rarer traces of some other nuclei and isotopes such as P, Ti, Cr, 54Fe and 56Fe, and 58Ni, 60Ni, and 62Ni. Superposed with the solar-wind plasma is the interplanetary magnetic field. The solar wind varies in density, temperature and speed over time and over solar latitude and longitude. Its particles can escape the Sun's gravity because of their high energy resulting from the high temperature of the corona, which in turn is a result of the coronal magnetic field. The boundary separating the corona from the solar wind is called the Alfvén surface. At a distance ...
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Tokamak
A tokamak (; russian: токамáк; otk, 𐱃𐰸𐰢𐰴, Toḳamaḳ) is a device which uses a powerful magnetic field to confine plasma in the shape of a torus. The tokamak is one of several types of magnetic confinement devices being developed to produce controlled thermonuclear fusion power. , it was the leading candidate for a practical fusion reactor. Tokamaks were initially conceptualized in the 1950s by Soviet physicists Igor Tamm and Andrei Sakharov, inspired by a letter by Oleg Lavrentiev. The first working tokamak was attributed to the work of Natan Yavlinsky on the T-1 in 1958. It had been demonstrated that a stable plasma equilibrium requires magnetic field lines that wind around the torus in a helix. Devices like the z-pinch and stellarator had attempted this, but demonstrated serious instabilities. It was the development of the concept now known as the safety factor (labelled ''q'' in mathematical notation) that guided tokamak development; by arrang ...
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Kinetic Energy
In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acceleration, the body maintains this kinetic energy unless its speed changes. The same amount of work is done by the body when decelerating from its current speed to a state of rest. Formally, a kinetic energy is any term in a system's Lagrangian which includes a derivative with respect to time. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2. In relativistic mechanics, this is a good approximation only when ''v'' is much less than the speed of light. The standard unit of kinetic energy is the joule, while the English unit of kinetic energy is the foot-pound. History and etymology The adjective ''kinetic'' has its roots in the Greek word κίνησις ''kines ...
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Plasma (physics)
Plasma ()πλάσμα
, Henry George Liddell, Robert Scott, ''A Greek English Lexicon'', on Perseus
is one of the four fundamental states of matter. It contains a significant portion of charged particles – ions and/or s. The presence of these charged particles is what primarily sets plasma apart from the other fundamental states of matter. It is the most abundant form of ordi ...
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Electromagnetic Radiation
In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible) light, ultraviolet, X-rays, and gamma rays. All of these waves form part of the electromagnetic spectrum. Classically, electromagnetic radiation consists of electromagnetic waves, which are synchronized oscillations of electric and magnetic fields. Depending on the frequency of oscillation, different wavelengths of electromagnetic spectrum are produced. In a vacuum, electromagnetic waves travel at the speed of light, commonly denoted ''c''. In homogeneous, isotropic media, the oscillations of the two fields are perpendicular to each other and perpendicular to the direction of energy and wave propagation, forming a transverse wave. The position of an electromagnetic wave within the electromagnetic spectrum can be characterized by either i ...
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