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Introduction To Eigenstates
Because of the uncertainty principle, statements about both the position and momentum of particles can only assign a probability that the position or momentum will have some numerical value. The uncertainty principle also says that eliminating uncertainty about position maximises uncertainty about momentum, and eliminating uncertainty about momentum maximizes uncertainty about position. A probability distribution assigns probabilities to all possible values of position and momentum. Schrödinger's wave equation gives wavefunction solutions, the squares of which are probabilities of where the electron might be, just as Heisenberg's probability distribution does. In the everyday world, it is natural and intuitive to think of every object being in its own eigenstate. This is another way of saying that every object appears to have a definite position, a definite momentum, a definite measured value, and a definite time of occurrence. However, the uncertainty principle says that i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uncertainty Principle
In quantum mechanics, the uncertainty principle (also known as Heisenberg's uncertainty principle) is any of a variety of mathematical inequalities asserting a fundamental limit to the accuracy with which the values for certain pairs of physical quantities of a particle, such as position, ''x'', and momentum, ''p'', can be predicted from initial conditions. Such variable pairs are known as complementary variables or canonically conjugate variables; and, depending on interpretation, the uncertainty principle limits to what extent such conjugate properties maintain their approximate meaning, as the mathematical framework of quantum physics does not support the notion of simultaneously well-defined conjugate properties expressed by a single value. The uncertainty principle implies that it is in general not possible to predict the value of a quantity with arbitrary certainty, even if all initial conditions are specified. Introduced first in 1927 by the German physicist Werner H ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eigenstate
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in time exhausts all that can be predicted about the system's behavior. A mixture of quantum states is again a quantum state. Quantum states that cannot be written as a mixture of other states are called pure quantum states, while all other states are called mixed quantum states. A pure quantum state can be represented by a ray in a Hilbert space over the complex numbers, while mixed states are represented by density matrices, which are positive semidefinite operators that act on Hilbert spaces. Pure states are also known as state vectors or wave functions, the latter term applying particularly when they are represented as functions of position or momentum. For example, when dealing with the energy spectrum of the electron in a hydrogen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superposition Principle
The superposition principle, also known as superposition property, states that, for all linear systems, the net response caused by two or more stimuli is the sum of the responses that would have been caused by each stimulus individually. So that if input ''A'' produces response ''X'' and input ''B'' produces response ''Y'' then input (''A'' + ''B'') produces response (''X'' + ''Y''). A function F(x) that satisfies the superposition principle is called a linear function. Superposition can be defined by two simpler properties: additivity F(x_1+x_2)=F(x_1)+F(x_2) \, and homogeneity F(a x)=a F(x) \, for scalar . This principle has many applications in physics and engineering because many physical systems can be modeled as linear systems. For example, a beam can be modeled as a linear system where the input stimulus is the load on the beam and the output response is the deflection of the beam. The importance of linear systems is that they are easier to analyze mathematically ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Self-adjoint Operator
In mathematics, a self-adjoint operator on an infinite-dimensional complex vector space ''V'' with inner product \langle\cdot,\cdot\rangle (equivalently, a Hermitian operator in the finite-dimensional case) is a linear map ''A'' (from ''V'' to itself) that is its own adjoint. If ''V'' is finite-dimensional with a given orthonormal basis, this is equivalent to the condition that the matrix of ''A'' is a Hermitian matrix, i.e., equal to its conjugate transpose ''A''. By the finite-dimensional spectral theorem, ''V'' has an orthonormal basis such that the matrix of ''A'' relative to this basis is a diagonal matrix with entries in the real numbers. In this article, we consider generalizations of this concept to operators on Hilbert spaces of arbitrary dimension. Self-adjoint operators are used in functional analysis and quantum mechanics. In quantum mechanics their importance lies in the Dirac–von Neumann formulation of quantum mechanics, in which physical observables such as p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
David Hilbert
David Hilbert (; ; 23 January 1862 – 14 February 1943) was a German mathematician, one of the most influential mathematicians of the 19th and early 20th centuries. Hilbert discovered and developed a broad range of fundamental ideas in many areas, including invariant theory, the calculus of variations, commutative algebra, algebraic number theory, the foundations of geometry, spectral theory of operators and its application to integral equations, mathematical physics, and the foundations of mathematics (particularly proof theory). Hilbert adopted and defended Georg Cantor's set theory and transfinite numbers. In 1900, he presented a collection of problems that set the course for much of the mathematical research of the 20th century. Hilbert and his students contributed significantly to establishing rigor and developed important tools used in modern mathematical physics. Hilbert is known as one of the founders of proof theory and mathematical logic. Life Early life and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Square Matrices
In mathematics, a square matrix is a matrix with the same number of rows and columns. An ''n''-by-''n'' matrix is known as a square matrix of order Any two square matrices of the same order can be added and multiplied. Square matrices are often used to represent simple linear transformations, such as shearing or rotation. For example, if R is a square matrix representing a rotation (rotation matrix) and \mathbf is a column vector describing the position of a point in space, the product R\mathbf yields another column vector describing the position of that point after that rotation. If \mathbf is a row vector, the same transformation can be obtained using where R^ is the transpose of Main diagonal The entries a_ (''i'' = 1, …, ''n'') form the main diagonal of a square matrix. They lie on the imaginary line which runs from the top left corner to the bottom right corner of the matrix. For instance, the main diagonal of the 4×4 matrix above contains the elements , , , . The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Observable
In physics, an observable is a physical quantity that can be measured. Examples include position and momentum. In systems governed by classical mechanics, it is a real-valued "function" on the set of all possible system states. In quantum physics, it is an operator, or gauge, where the property of the quantum state can be determined by some sequence of operations. For example, these operations might involve submitting the system to various electromagnetic fields and eventually reading a value. Physically meaningful observables must also satisfy transformation laws that relate observations performed by different observers in different frames of reference. These transformation laws are automorphisms of the state space, that is bijective transformations that preserve certain mathematical properties of the space in question. Quantum mechanics In quantum physics, observables manifest as linear operators on a Hilbert space representing the state space of quantum states ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eigenvalue
In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted by \lambda, is the factor by which the eigenvector is scaled. Geometrically, an eigenvector, corresponding to a real nonzero eigenvalue, points in a direction in which it is stretched by the transformation and the eigenvalue is the factor by which it is stretched. If the eigenvalue is negative, the direction is reversed. Loosely speaking, in a multidimensional vector space, the eigenvector is not rotated. Formal definition If is a linear transformation from a vector space over a field into itself and is a nonzero vector in , then is an eigenvector of if is a scalar multiple of . This can be written as T(\mathbf) = \lambda \mathbf, where is a scalar in , known as the eigenvalue, characteristic value, or characteristic root a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Cloud
In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus. The term ''atomic orbital'' may also refer to the physical region or space where the electron can be calculated to be present, as predicted by the particular mathematical form of the orbital. Each orbital in an atom is characterized by a set of values of the three quantum numbers , , and , which respectively correspond to the electron's energy, angular momentum, and an angular momentum vector component ( magnetic quantum number). Alternative to the magnetic quantum number, the orbitals are often labeled by the associated harmonic polynomials (e.g., ''xy'', ). Each such orbital can be occupied by a maximum of two electrons, each with its own projection of spin m_s. The simple names s orbital, p or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Probability
Probability is the branch of mathematics concerning numerical descriptions of how likely an event is to occur, or how likely it is that a proposition is true. The probability of an event is a number between 0 and 1, where, roughly speaking, 0 indicates impossibility of the event and 1 indicates certainty."Kendall's Advanced Theory of Statistics, Volume 1: Distribution Theory", Alan Stuart and Keith Ord, 6th Ed, (2009), .William Feller, ''An Introduction to Probability Theory and Its Applications'', (Vol 1), 3rd Ed, (1968), Wiley, . The higher the probability of an event, the more likely it is that the event will occur. A simple example is the tossing of a fair (unbiased) coin. Since the coin is fair, the two outcomes ("heads" and "tails") are both equally probable; the probability of "heads" equals the probability of "tails"; and since no other outcomes are possible, the probability of either "heads" or "tails" is 1/2 (which could also be written as 0.5 or 50%). These con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no known components or substructure. The electron's mass is approximately 1/1836 that of the proton. Quantum mechanical properties of the electron include an intrinsic angular momentum ( spin) of a half-integer value, expressed in units of the reduced Planck constant, . Being fermions, no two electrons can occupy the same quantum state, in accordance with the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Werner Heisenberg
Werner Karl Heisenberg () (5 December 1901 – 1 February 1976) was a German theoretical physicist and one of the main pioneers of the theory of quantum mechanics. He published his work in 1925 in a breakthrough paper. In the subsequent series of papers with Max Born and Pascual Jordan, during the same year, his matrix formulation of quantum mechanics was substantially elaborated. He is known for the uncertainty principle, which he published in 1927. Heisenberg was awarded the 1932 Nobel Prize in Physics "for the creation of quantum mechanics". Heisenberg also made contributions to the theories of the hydrodynamics of turbulent flows, the atomic nucleus, ferromagnetism, cosmic rays, and subatomic particles. He was a principal scientist in the German nuclear weapons program during World War II. He was also instrumental in planning the first West German nuclear reactor at Karlsruhe, together with a research reactor in Munich, in 1957. Following World War II, he was app ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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