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Intrinsic Low-dimensional Manifold
In chemical kinetics, an intrinsic low-dimensional manifold is a technique to simplify the study of reaction mechanisms using dynamical systems, first proposed in 1992. The ILDM approach fixes a low dimensional surface which describes well the slow dynamics and assumes that after a short time the fast dynamics are less important and the system can be described in the lower-dimensional space. See also *Intrinsic dimension References Chemical kinetics {{physical-chemistry-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History In 1864, Peter Waage and Cato Guldberg pioneered the development of chemical kinetics by formulating the law of mass action, which states that the speed of a chemical reaction is proportional to the quantity of the reacting substances.C.M. Guldberg and P. Waage,"Studies Concerning Affinity" ''Forhandlinger i Videnskabs-Selskabet i Christiania'' (1864), 3 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dynamical System
In mathematics, a dynamical system is a system in which a function describes the time dependence of a point in an ambient space. Examples include the mathematical models that describe the swinging of a clock pendulum, the flow of water in a pipe, the random motion of particles in the air, and the number of fish each springtime in a lake. The most general definition unifies several concepts in mathematics such as ordinary differential equations and ergodic theory by allowing different choices of the space and how time is measured. Time can be measured by integers, by real or complex numbers or can be a more general algebraic object, losing the memory of its physical origin, and the space may be a manifold or simply a set, without the need of a smooth space-time structure defined on it. At any given time, a dynamical system has a state representing a point in an appropriate state space. This state is often given by a tuple of real numbers or by a vector in a geome ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intrinsic Dimension
The intrinsic dimension for a data set can be thought of as the number of variables needed in a minimal representation of the data. Similarly, in signal processing of multidimensional signals, the intrinsic dimension of the signal describes how many variables are needed to generate a good approximation of the signal. When estimating intrinsic dimension, however, a slightly broader definition based on manifold dimension is often used, where a representation in the intrinsic dimension does only need to exist locally. Such intrinsic dimension estimation methods can thus handle data sets with different intrinsic dimensions in different parts of the data set. This is often referred to as local intrinsic dimensionality. The intrinsic dimension can be used as a lower bound of what dimension it is possible to compress a data set into through dimension reduction, but it can also be used as a measure of the complexity of the data set or signal. For a data set or signal of ''N'' variables, it ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
