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Hydrogen-like Atom
A hydrogen-like atom (or hydrogenic atom) is any atom or ion with a single valence electron. These atoms are isoelectronic with hydrogen. Examples of hydrogen-like atoms include, but are not limited to, hydrogen itself, all alkali metals such as Rb and Cs, singly ionized alkaline earth metals such as Ca+ and Sr+ and other ions such as He+, Li2+, and Be3+ and isotopes of any of the above. A hydrogen-like atom includes a positively charged core consisting of the atomic nucleus and any core electrons as well as a single valence electron. Because helium is common in the universe, the spectroscopy of singly ionized helium is important in EUV astronomy, for example, of DO white dwarf stars. The non-relativistic Schrödinger equation and relativistic Dirac equation for the hydrogen atom can be solved analytically, owing to the simplicity of the two-particle physical system. The one-electron wave function solutions are referred to as ''hydrogen-like atomic orbitals''. Hydrogen-li ...
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Atom
Atoms are the basic particles of the chemical elements. An atom consists of a atomic nucleus, nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element. Atoms are extremely small, typically around 100 picometers across. A human hair is about a million carbon atoms wide. Atoms are smaller than the shortest wavelength of visible light, which means humans cannot see atoms with conventional microscopes. They are so small that accurately predicting their behavior using classical physics is not possible due to quantum mechanics, quantum effects. More than 99.94% of an atom's mass is in the nucleus. Protons hav ...
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Extreme Ultraviolet
Extreme ultraviolet radiation (EUV or XUV) or high-energy ultraviolet radiation is electromagnetic radiation in the part of the electromagnetic spectrum spanning wavelengths shorter than the hydrogen Lyman-alpha line from 121  nm down to the X-ray band of 10 nm. By the Planck–Einstein equation the EUV photons have energies from 10.26  eV up to 124.24 eV where we enter the X-ray energies. EUV is naturally generated by the solar corona and artificially by plasma, high harmonic generation sources and synchrotron light sources. Since UVC extends to 100 nm, there is some overlap in the terms. The main uses of extreme ultraviolet radiation are photoelectron spectroscopy, solar imaging, and lithography. In air, EUV is the most highly absorbed component of the electromagnetic spectrum, requiring high vacuum for transmission. EUV generation Neutral atoms or condensed matter do not have large enough energy transitions to emit EUV radiation. Ionizatio ...
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Principal Quantum Number
In quantum mechanics, the principal quantum number (''n'') of an electron in an atom indicates which electron shell or energy level it is in. Its values are natural numbers (1, 2, 3, ...). Hydrogen and Helium, at their lowest energies, have just one electron shell. Lithium through Neon (see periodic table) have two shells: two electrons in the first shell, and up to 8 in the second shell. Larger atoms have more shells. The principal quantum number is one of four quantum numbers assigned to each electron in an atom to describe the quantum state of the electron. The other quantum numbers for bound electrons are the total angular momentum of the orbit ''ℓ'', the angular momentum in the z direction ''ℓz'', and the spin of the electron ''s''. Overview and history As ''n'' increases, the electron is also at a higher energy and is, therefore, less tightly bound to the nucleus. For higher ''n'', the electron is farther from the nucleus, on average. For each value of ''n'', th ...
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Eigenfunction
In mathematics, an eigenfunction of a linear operator ''D'' defined on some function space is any non-zero function f in that space that, when acted upon by ''D'', is only multiplied by some scaling factor called an eigenvalue. As an equation, this condition can be written as Df = \lambda f for some scalar eigenvalue \lambda. The solutions to this equation may also be subject to boundary conditions that limit the allowable eigenvalues and eigenfunctions. An eigenfunction is a type of eigenvector. Eigenfunctions In general, an eigenvector of a linear operator ''D'' defined on some vector space is a nonzero vector in the domain of ''D'' that, when ''D'' acts upon it, is simply scaled by some scalar value called an eigenvalue. In the special case where ''D'' is defined on a function space, the eigenvectors are referred to as eigenfunctions. That is, a function ''f'' is an eigenfunction of ''D'' if it satisfies the equation where λ is a scalar. The solutions to Equation may also ...
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Point Charge
A point particle, ideal particle or point-like particle (often spelled pointlike particle) is an idealization of particles heavily used in physics. Its defining feature is that it lacks spatial extension; being dimensionless, it does not take up space. A point particle is an appropriate representation of any object whenever its size, shape, and structure are irrelevant in a given context. For example, from far enough away, any finite-size object will look and behave as a point-like object. Point masses and point charges, discussed below, are two common cases. When a point particle has an additive property, such as mass or charge, it is often represented mathematically by a Dirac delta function. In classical mechanics there is usually no concept of rotation of point particles about their "center". In quantum mechanics, the concept of a point particle is complicated by the Heisenberg uncertainty principle, because even an elementary particle, with no internal structure, occupies ...
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Rydberg Atom
A Rydberg atom is an excited atom with one or more electrons that have a very high principal quantum number, ''n''. The higher the value of ''n'', the farther the electron is from the nucleus, on average. Rydberg atoms have a number of peculiar properties including an exaggerated response to electric and magnetic fields, long decay periods and electron wavefunctions that approximate, under some conditions, classical orbits of electrons about the nuclei. The core electrons shield the outer electron from the electric field of the nucleus such that, from a distance, the electric potential looks identical to that experienced by the electron in a hydrogen atom. Formulation In spite of its shortcomings, the Bohr model of the atom is useful in explaining these properties. Classically, an electron in a circular orbit of radius ''r'', about a hydrogen nucleus of charge +'' e'', obeys Newton's second law: : \mathbf=m\mathbf \Rightarrow = where ''k'' = 1/(4π ε0). Orbital moment ...
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Exotic Atom
An exotic atom is an otherwise normal atom in which one or more sub-atomic particles have been replaced by other particles. For example, electrons may be replaced by other negatively charged particles such as muons (muonic atoms) or pions (pionic atoms). Because these substitute particles are usually unstable, exotic atoms typically have very short lifetimes and no exotic atom observed so far can persist under normal conditions. Muonic atoms In a ''muonic atom'' (previously called a ''mu-mesic'' atom, now known to be a misnomer as muons are not mesons), an electron is replaced by a muon, which, like the electron, is a lepton. Since leptons are only sensitive to weak, electromagnetic and gravitational forces, muonic atoms are governed to very high precision by the electromagnetic interaction. Since a muon is more massive than an electron, the Bohr orbits are closer to the nucleus in a muonic atom than in an ordinary atom, and corrections due to quantum electrodynamics are more ...
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Positron
The positron or antielectron is the particle with an electric charge of +1''elementary charge, e'', a Spin (physics), spin of 1/2 (the same as the electron), and the same Electron rest mass, mass as an electron. It is the antiparticle (antimatter counterpart) of the electron. When a positron collides with an electron, annihilation occurs. If this collision occurs at low energies, it results in the production of two or more photons. Positrons can be created by positron emission radioactive decay (through weak interactions), or by pair production from a sufficiently energetic photon which is interacting with an atom in a material. History Theory In 1928, Paul Dirac published a paper proposing that electrons can have both a positive and negative charge. This paper introduced the Dirac equation, a unification of quantum mechanics, special relativity, and the then-new concept of electron Spin (physics), spin to explain the Zeeman effect. The paper did not explicitly predict a ...
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Positronium
Positronium (Ps) is a system consisting of an electron and its antimatter, anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two particles annihilate each other to predominantly produce two or three gamma-rays, depending on the relative spin states. The energy levels of the two particles are similar to that of the hydrogen atom (which is a bound state of a proton and an electron). However, because of the reduced mass, the frequency, frequencies of the spectral lines are less than half of those for the corresponding hydrogen lines. States The mass of positronium is 1.022 MeV, which is twice the electron mass minus the binding energy of a few eV. The lowest energy orbital state of positronium is 1S, and like with hydrogen, it has a hyperfine structure arising from the relative orientations of the spins of the electron and the positron. The Singlet state, ''singlet ...
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Muon
A muon ( ; from the Greek letter mu (μ) used to represent it) is an elementary particle similar to the electron, with an electric charge of −1 '' e'' and a spin of  ''ħ'', but with a much greater mass. It is classified as a lepton. As with other leptons, the muon is not thought to be composed of any simpler particles. The muon is an unstable subatomic particle with a mean lifetime of , much longer than many other subatomic particles. As with the decay of the free neutron (with a lifetime around 15 minutes), muon decay is slow (by subatomic standards) because the decay is mediated only by the weak interaction (rather than the more powerful strong interaction or electromagnetic interaction), and because the mass difference between the muon and the set of its decay products is small, providing few kinetic degrees of freedom for decay. Muon decay almost always produces at least three particles, which must include an electron of the same charge as the muon and t ...
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Muonium
Muonium () is an exotic atom made up of an antimuon and an electron, which was discovered in 1960 by Vernon W. Hughes and is given the chemical symbol Mu. During the muon's lifetime, muonium can undergo chemical reactions. Description Because, like a proton, the antimuon's mass is vastly larger than that of the electron, muonium () is more similar to atomic hydrogen () than positronium (). Its Bohr radius and ionization energy are within 0.5% of hydrogen, deuterium, and tritium, and thus it can usefully be considered as an exotic light isotope of hydrogen. Properties Although muonium is short-lived, physical chemists study it using muon spin spectroscopy (μSR), a magnetic resonance technique analogous to nuclear magnetic resonance (NMR) or electron spin resonance (ESR) spectroscopy. Like ESR, μSR is useful for the analysis of chemical transformations and the structure of compounds with novel or potentially valuable electronic properties. Muonium is usually studied by ...
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Wave Function
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter), psi, respectively). Wave functions are complex number, complex-valued. For example, a wave function might assign a complex number to each point in a region of space. The Born rule provides the means to turn these complex probability amplitudes into actual probabilities. In one common form, it says that the squared modulus of a wave function that depends upon position is the probability density function, probability density of measurement in quantum mechanics, measuring a particle as being at a given place. The integral of a wavefunction's squared modulus over all the system's degrees of freedom must be equal to 1, a condition called ''normalization''. Since the wave function is complex-valued, only its relative phase and relative magnitud ...
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