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Heavy Mineral Analysis
Heavy minerals (minerals with a density greater than 2.89 g/cm3) have highly variable stabilities with respect to transport/weathering but the combined effects of chemical weathering, transport and diagenesis (and overall maturity) tend to decrease their percentage in the whole rock. Therefore, the average heavy mineral yield in sandstones is about 1% Boggs, S., 2009. Petrology of sedimentary rocks, Second Edition but can be a lot lower in old/recycled sandstones. The individual properties of heavy minerals being very different from one another and their relative abundance being a direct proxy of the nature of the source terranes and transport/recycling mechanism, heavy minerals have been used since the 19th century as a provenance tool. History The first published provenance analysis is often considered to be the study of the Dutch-Coast sand dunes by J.W. Retgers who combined petrography and chemical analysis of opaque minerals to assess provenance patterns in the basin. This st ...
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Heavy Minerals
In geology, a heavy mineral is a mineral with a density that is greater than 2.9 g/cm3, most commonly referring to dense components of siliciclastic sediments. A heavy mineral suite is the relative percentages of heavy minerals in a stone. Heavy mineral suites are used to help determine the provenance and history of sedimentary rocks. As heavy minerals are a minor constituent of most sedimentary rock, they must be separated out to be studied. Heavy mineral separation generally uses a dense liquid in either a separatory funnel or centrifuge. Liquids used include bromoform Bromoform (CHBr3) is a brominated organic solvent, colorless liquid at room temperature, with a high refractive index, very high density, and sweet odor is similar to that of chloroform. It is one of the four haloforms, the others being fluoroform ..., tetrabromoethane, tribromoethane, methylene iodide, and polytungstate liquids. References Petrology Sedimentology {{petrology-stub ...
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Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. History In the early tenth century, the Persian physician and alchemist Abu Bakr al-Razi ( 865–925, Latin: Rhazes) conducted experiments with sal ammoniac ( ammonium chloride) and vitriol (hydrated sulfates of various metals), which he distilled together, thus producing the gas hydrogen chloride. In doing so, al-Razi may have stumbled upon a primitive method for producing hydrochloric acid, as perhaps manifested in the following recipe from his ("The Book of Secrets"): However, it appears that in most of his experiments al-Razi disregarded the gaseous products, concentrating instead on the color c ...
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Monazite
Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium-dominant member of the group. It occurs usually in small isolated crystals. It has a hardness of 5.0 to 5.5 on the Mohs scale of mineral hardness and is relatively dense, about 4.6 to 5.7 g/cm3. There are five different most common species of monazite, depending on the relative amounts of the rare earth elements in the mineral: * monazite-(Ce), ( Ce, La, Nd, Th) PO4 (the most common member), * monazite-(La), (La,Ce,Nd)PO4, * monazite-(Nd), (Nd,La,Ce)PO4, * monazite-(Sm), ( Sm, Gd,Ce,Th)PO4, * monazite-(Pr), ( Pr,Ce,Nd,Th)PO4. The elements in parentheses are listed in the order of their relative proportion within the mineral: lanthanum is the most common rare-earth element in monazite-(La), and so forth. Silica (SiO2) is present in ...
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Garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different species are pyrope, almandine, spessartine, grossular (varieties of which are hessonite or cinnamon-stone and tsavorite), uvarovite and andradite. The garnets make up two solid solution series: pyrope-almandine-spessartine (pyralspite), with the composition range ; and uvarovite-grossular-andradite (ugrandite), with the composition range . Etymology The word ''garnet'' comes from the 14th-century Middle English word ''gernet'', meaning 'dark red'. It is borrowed from Old French ''grenate'' from Latin ''granatus,'' from ''granum'' ('grain, seed'). This is possibly a reference to ''mela granatum'' or even ''pomum granatum'' (' pomegranate', ''Punica granatum''), a plant whose fruits contain abundant and vivid red seed covers ( arils), ...
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Rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visible wavelengths of any known crystal and also exhibits a particularly large birefringence and high dispersion. Owing to these properties, it is useful for the manufacture of certain optical elements, especially polarization optics, for longer visible and infrared wavelengths up to about 4.5 micrometres. Natural rutile may contain up to 10% iron and significant amounts of niobium and tantalum. Rutile derives its name from the Latin ('red'), in reference to the deep red color observed in some specimens when viewed by transmitted light. Rutile was first described in 1803 by Abraham Gottlob Werner. Occurrence Rutile is a common accessory mineral in high-temperature and high-pressure metamorphic rocks and in igneous rocks. Thermodynamically, ru ...
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Tourmaline
Tourmaline ( ) is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety of colors. The term is derived from the Sinhalese "tōramalli", which refers to the carnelian gemstones. History Brightly colored Ceylonese gem tourmalines were brought to Europe in great quantities by the Dutch East India Company to satisfy a demand for curiosities and gems. Tourmaline was sometimes called the "Ceylonese Magnet" because it could attract and then repel hot ashes due to its pyroelectric properties. Tourmalines were used by chemists in the 19th century to polarize light by shining rays onto a cut and polished surface of the gem. Species and varieties Commonly encountered species and varieties: Schorl species: : Brownish black to black—''schorl'', Dravite species: from the Drave district of Carinthia : Dark yellow to brownis ...
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Zircon
Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green. The name derives from the Persian ''zargun'', meaning "gold-hued". This word is corrupted into " jargoon", a term applied to light-colored zircons. The English word "zircon" is derived from ''Zirkon'', which is the German adaptation of this word. Yellow, orange, and red zircon is also known as " hya ...
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Magnetic Separator
Magnetic separation is the process of separating components of mixtures by using a magnet to attract magnetic substances. The process that is used for magnetic separation separates non-magnetic substances from those which are magnetic. This technique is useful for the select few minerals which are ferromagnetic (iron-, nickel-, and cobalt-containing minerals) and paramagnetic. Most metals, including gold, silver and aluminum, are nonmagnetic. A large diversity of mechanical means are used to separate magnetic materials. During magnetic separation, magnets are situated inside two separator drums which bear liquids. Due to the magnets, magnetic particles are being drifted by the movement of the drums. This can create a magnetic concentrate (e.g. an ore concentrate). History Michael Faraday discovered that when a substance is put in a magnetic environment, the intensity of the environment is modified by it. With this information, he discovered that different materials can be separa ...
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Sodium Polytungstate
Sodium metatungstate is the inorganic compound with the formula Na6 2W12O40 sometimes written 3Na2WO4·9WO3·H2O. It also called as sodium polytungstate (SPT). This salt has been used in the manufacture of dense aqueous solutions. Sodium metatungstate exists as white solid. The anion is the polyoxotungstate 6-">2W12O40/nowiki>6-, which features six-coordinated tungsten(VI) centers interconnected with doubly- and triply bridging oxo ligands. Due to its very high solubility in water (max. density 3.1 g/cm3), SPT is widely used as to produce "heavy liquid" for gravity separation (sink /float analysis) and density gradient centrifugation. It has significant advantages when compared to zinc chloride Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2 and its hydrates. Zinc chlorides, of which nine crystalline forms are known, are colorless or white, and are highly soluble in water. This salt is hygroscopic and e ... solution or the toxic halogenate ...
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Tetrabromoethane
Tetrabromoethane (TBE) is a halogenated hydrocarbon, chemical formula C2H2Br4. Although three bromine atoms may bind to one of the carbon atoms creating 1,1,1,2-tetrabromoethane this is not thermodynamically favorable, so in practice tetrabromoethane is equal to 1,1,2,2-tetrabromoethane, where each carbon atom binds two bromine atoms. Uses It has an unusually high density for an organic compound, near 3 g/mL, due largely to the four bromine atoms.Organic based heavy liquids
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TBE is a at , and is used to separate



Bromoform
Bromoform (CHBr3) is a brominated organic solvent, colorless liquid at room temperature, with a high refractive index, very high density, and sweet odor is similar to that of chloroform. It is one of the four haloforms, the others being fluoroform, chloroform, and iodoform. Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide. Currently its main use is as a laboratory reagent. Structure The molecule adopts tetrahedral molecular geometry with C3v symmetry. Uses Only small quantities of bromoform are currently produced industrially in the United States. In the past, it was used as a solvent, sedative and flame retardant, but now it is mainly used as a laboratory reagent, for example as an extraction solvent. Bromoform also has medical uses; injections of bromoform are sometimes used instead of epinephrine to treat severe asthma cases. B ...
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