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Extended Irreversible Thermodynamics
Extended irreversible thermodynamics is a branch of non-equilibrium thermodynamics that goes beyond the local equilibrium hypothesis of classical irreversible thermodynamics. The space of state variables is enlarged by including the fluxes of mass, momentum and energy and eventually higher order fluxes. The formalism is well-suited for describing high-frequency processes and small-length scales materials. Overview Over the last decades, many efforts have been displayed to generalize the classical laws of Fourier (heat conduction), Fick (matter diffusion), Newton (viscous flows) and Ohm (electrical transport). Indeed, modern technology strives towards miniaturized devices, high frequency and strongly non-linear processes requiring for a new conceptual approach. Several classes of theories have been developed with this objective and one of them, known under the heading of ''Extended Irreversible Thermodynamics'' (EIT) has raised a particular growing interest. The paternity of EIT can ...
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Non-equilibrium Thermodynamics
Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions. Almost all systems found in nature are not in thermodynamic equilibrium, for they are changing or can be triggered to change over time, and are continuously and discontinuously subject to flux of matter and energy to and from other systems and to chemical reactions. Some systems and processes are, however, in a useful sense, near enough to thermodynamic equilibrium to allow description with useful accuracy by currently known non-equilibrium thermodynamics. Nevertheless, many natural systems and processes will always remain far beyond the scope o ...
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Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the firs ...
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Flux
Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport phenomena, flux is a vector quantity, describing the magnitude and direction of the flow of a substance or property. In vector calculus flux is a scalar quantity, defined as the surface integral of the perpendicular component of a vector field over a surface. Terminology The word ''flux'' comes from Latin: ''fluxus'' means "flow", and ''fluere'' is "to flow". As '' fluxion'', this term was introduced into differential calculus by Isaac Newton. The concept of heat flux was a key contribution of Joseph Fourier, in the analysis of heat transfer phenomena. His seminal treatise ''Théorie analytique de la chaleur'' (''The Analytical Theory of Heat''), defines ''fluxion'' as a central quantity and proceeds to derive the now well-known e ...
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Thermal Conduction
Conduction is the process by which heat is transferred from the hotter end to the colder end of an object. The ability of the object to conduct heat is known as its ''thermal conductivity'', and is denoted . Heat spontaneously flows along a temperature gradient (i.e. from a hotter body to a colder body). For example, heat is conducted from the hotplate of an electric stove to the bottom of a saucepan in contact with it. In the absence of an opposing external driving energy source, within a body or between bodies, temperature differences decay over time, and thermal equilibrium is approached, temperature becoming more uniform. In conduction, the heat flow is within and through the body itself. In contrast, in heat transfer by thermal radiation, the transfer is often between bodies, which may be separated spatially. Heat can also be transferred by a combination of conduction and radiation. In solids, conduction is mediated by the combination of vibrations and collisions of molec ...
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James Clerk Maxwell
James Clerk Maxwell (13 June 1831 – 5 November 1879) was a Scottish mathematician and scientist responsible for the classical theory of electromagnetic radiation, which was the first theory to describe electricity, magnetism and light as different manifestations of the same phenomenon. Maxwell's equations for electromagnetism have been called the " second great unification in physics" where the first one had been realised by Isaac Newton. With the publication of " A Dynamical Theory of the Electromagnetic Field" in 1865, Maxwell demonstrated that electric and magnetic fields travel through space as waves moving at the speed of light. He proposed that light is an undulation in the same medium that is the cause of electric and magnetic phenomena. (This article accompanied an 8 December 1864 presentation by Maxwell to the Royal Society. His statement that "light and magnetism are affections of the same substance" is at page 499.) The unification of light and elec ...
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Time Derivative
A time derivative is a derivative of a function with respect to time, usually interpreted as the rate of change of the value of the function. The variable denoting time is usually written as t. Notation A variety of notations are used to denote the time derivative. In addition to the normal ( Leibniz's) notation, :\frac A very common short-hand notation used, especially in physics, is the 'over-dot'. I.E. :\dot (This is called Newton's notation) Higher time derivatives are also used: the second derivative with respect to time is written as :\frac with the corresponding shorthand of \ddot. As a generalization, the time derivative of a vector, say: : \mathbf v = \left v_1,\ v_2,\ v_3, \ldots \right is defined as the vector whose components are the derivatives of the components of the original vector. That is, : \frac = \left \frac,\frac ,\frac , \ldots \right . Use in physics Time derivatives are a key concept in physics. For example, for a changing position x, its ...
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Ideal Gas
An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics. The requirement of zero interaction can often be relaxed if, for example, the interaction is perfectly elastic or regarded as point-like collisions. Under various conditions of temperature and pressure, many real gases behave qualitatively like an ideal gas where the gas molecules (or atoms for monatomic gas) play the role of the ideal particles. Many gases such as nitrogen, oxygen, hydrogen, noble gases, some heavier gases like carbon dioxide and mixtures such as air, can be treated as ideal gases within reasonable tolerances over a considerable parameter range around standard temperature and pressure. Generally, a gas behaves more like an ideal gas at higher temperature and lower pressu ...
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Traffic Control
Traffic management is a key branch within logistics. It concerns the planning control and purchasing of transport services needed to physically move vehicles (for example aircraft, road vehicles, rolling stock and watercraft) and freight. Traffic management is implemented by people working with different job titles in different branches: * Within freight and cargo logistics: traffic manager, assessment of hazardous and awkward materials, carrier choice and fees, demurrage, documentation, expediting, freight consolidation, insurance, reconsignment and tracking * Within air traffic management: air traffic controller * Within rail traffic management: rail traffic controller, train dispatcher or signalman * Within road traffic management: traffic controller Traffic Control Management is the design, auditing and implementation of traffic control plans at worksites and civil infrastructure projects. Traffic Management can include: flagging, lane closures, detours, full freeway clos ...
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Economy
An economy is an area of the production, distribution and trade, as well as consumption of goods and services. In general, it is defined as a social domain that emphasize the practices, discourses, and material expressions associated with the production, use, and management of scarce resources'. A given economy is a set of processes that involves its culture, values, education, technological evolution, history, social organization, political structure, legal systems, and natural resources as main factors. These factors give context, content, and set the conditions and parameters in which an economy functions. In other words, the economic domain is a social domain of interrelated human practices and transactions that does not stand alone. Economic agents can be individuals, businesses, organizations, or governments. Economic transactions occur when two groups or parties agree to the value or price of the transacted good or service, commonly expressed in a certain curren ...
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World Wide Web
The World Wide Web (WWW), commonly known as the Web, is an information system enabling documents and other web resources to be accessed over the Internet. Documents and downloadable media are made available to the network through web servers and can be accessed by programs such as web browsers. Servers and resources on the World Wide Web are identified and located through character strings called uniform resource locators (URLs). The original and still very common document type is a web page formatted in Hypertext Markup Language (HTML). This markup language supports plain text, images, embedded video and audio contents, and scripts (short programs) that implement complex user interaction. The HTML language also supports hyperlinks (embedded URLs) which provide immediate access to other web resources. Web navigation, or web surfing, is the common practice of following such hyperlinks across multiple websites. Web applications are web pages that function as applicat ...
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Parabolic Partial Differential Equation
A parabolic partial differential equation is a type of partial differential equation (PDE). Parabolic PDEs are used to describe a wide variety of time-dependent phenomena, including heat conduction, particle diffusion, and pricing of derivative investment instruments. Definition To define the simplest kind of parabolic PDE, consider a real-valued function u(x, y) of two independent real variables, x and y. A second-order, linear, constant-coefficient PDE for u takes the form :Au_ + 2Bu_ + Cu_ + Du_x + Eu_y + F = 0, and this PDE is classified as being ''parabolic'' if the coefficients satisfy the condition :B^2 - AC = 0. Usually x represents one-dimensional position and y represents time, and the PDE is solved subject to prescribed initial and boundary conditions. The name "parabolic" is used because the assumption on the coefficients is the same as the condition for the analytic geometry equation A x^2 + 2B xy + C y^2 + D x + E y + F = 0 to define a planar parabola. ...
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Polymer
A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros' ...
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