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Exergy
In thermodynamics, the exergy of a system is the maximum useful work possible during a process that brings the system into equilibrium with a heat reservoir, reaching maximum entropy. When the surroundings are the reservoir, exergy is the potential of a system to cause a change as it achieves equilibrium with its environment. Exergy is the energy that is available to be used. After the system and surroundings reach equilibrium, the exergy is zero. Determining exergy was also the first goal of thermodynamics. The term "exergy" was coined in 1956 by Zoran Rant (1904–1972) by using the Greek '' ex'' and '' ergon'' meaning "from work", but the concept had been earlier developed by J Willard Gibbs (the namesake of Gibbs free energy) in 1873. Energy is neither created nor destroyed during a process. Energy changes from one form to another (''see First Law of Thermodynamics''). In contrast, exergy is always destroyed when a process is irreversible, for example loss of heat to the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Second Law Of Thermodynamics
The second law of thermodynamics is a physical law based on universal experience concerning heat and Energy transformation, energy interconversions. One simple statement of the law is that heat always moves from hotter objects to colder objects (or "downhill"), unless energy in some form is supplied to reverse the direction of heat flow. Another definition is: "Not all heat energy can be converted into Work (thermodynamics), work in a cyclic process."Young, H. D; Freedman, R. A. (2004). ''University Physics'', 11th edition. Pearson. p. 764. The second law of thermodynamics in other versions establishes the concept of entropy as a physical property of a thermodynamic system. It can be used to predict whether processes are forbidden despite obeying the requirement of conservation of energy as expressed in the first law of thermodynamics and provides necessary criteria for spontaneous processes. The second law may be formulated by the observation that the entropy of isolated systems ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Entropy Production
Entropy production (or generation) is the amount of entropy which is produced in any irreversible processes such as heat and mass transfer processes including motion of bodies, heat exchange, fluid flow, substances expanding or mixing, anelastic deformation of solids, and any irreversible thermodynamic cycle, including thermal machines such as power plants, heat engines, refrigerators, heat pumps, and air conditioners. In the dual representation entropy–exergy for accounting the second law of thermodynamics it can be expressed in equivalent terms of exergy disruption. Short history Entropy is produced in irreversible processes. The importance of avoiding irreversible processes (hence reducing the entropy production) was recognized as early as 1824 by Carnot. In 1865 Rudolf Clausius expanded his previous work from 1854 on the concept of "unkompensierte Verwandlungen" (uncompensated transformations), which, in our modern nomenclature, would be called the entropy production. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Josiah Willard Gibbs
Josiah Willard Gibbs (; February 11, 1839 – April 28, 1903) was an American scientist who made significant theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynamics was instrumental in transforming physical chemistry into a rigorous inductive science. Together with James Clerk Maxwell and Ludwig Boltzmann, he created statistical mechanics (a term that he coined), explaining the laws of thermodynamics as consequences of the statistical properties of Statistical ensemble (mathematical physics), ensembles of the possible states of a physical system composed of many particles. Gibbs also worked on the application of Maxwell's equations to problems in physical optics. As a mathematician, he invented modern vector calculus (independently of the British scientist Oliver Heaviside, who carried out similar work during the same period). In 1863, Yale University, Yale awarded Gibbs the first American Doctor of Philosophy, doctorate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Work (thermodynamics)
In thermodynamics, work is one of the principal processes by which a thermodynamic system can interact with its surroundings and exchange energy. An exchange of energy is facilitated by a mechanism through which the system can spontaneously exert macroscopic forces on its surroundings, or vice versa. In the surroundings, this mechanical work can lift a weight, for example. The externally measured forces and external effects may be electromagnetic,Guggenheim, E.A. (1985). ''Thermodynamics. An Advanced Treatment for Chemists and Physicists'', seventh edition, North Holland, Amsterdam, .Jackson, J.D. (1975). ''Classical Electrodynamics'', second edition, John Wiley and Sons, New York, .Konopinski, E.J. (1981). ''Electromagnetic Fields and Relativistic Particles'', McGraw-Hill, New York, . gravitational,North, G.R., Erukhimova, T.L. (2009). ''Atmospheric Thermodynamics. Elementary Physics and Chemistry'', Cambridge University Press, Cambridge (UK), . or mechanical (such as pressure-v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Internal Energy
The internal energy of a thermodynamic system is the total energy contained within it. It is the energy necessary to create or prepare the system in its given internal state, and includes the contributions of potential energy and internal kinetic energy. It keeps account of the gains and losses of energy of the system that are due to changes in its internal state. It does not include the kinetic energy of motion of the system as a whole, or any external energies from surrounding force fields. The internal energy of an isolated system is constant, which is expressed as the law of conservation of energy, a foundation of the first law of thermodynamics. The internal energy is an extensive property. The internal energy cannot be measured directly and knowledge of all its components is rarely interesting, such as the static rest mass energy of its constituent matter. Thermodynamics is chiefly concerned only with ''changes'' in the internal energy, not with its absolute value. Instea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Entropy
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication. The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names ''thermodynamic function'' and ''heat-potential''. In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of hea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carnot's Theorem (thermodynamics)
In thermodynamics, Carnot's theorem, developed in 1824 by Nicolas Léonard Sadi Carnot, also called Carnot's rule, is a principle that specifies limits on the maximum efficiency that any heat engine can obtain. Carnot's theorem states that all heat engines operating between the same two thermal or heat reservoirs can't have efficiencies greater than a reversible heat engine operating between the same reservoirs. A corollary of this theorem is that every reversible heat engine operating between a pair of heat reservoirs is equally efficient, regardless of the working substance employed or the operation details. Since a Carnot heat engine is also a reversible engine, the efficiency of all the reversible heat engines is determined as the efficiency of the Carnot heat engine that depends solely on the temperatures of its hot and cold reservoirs. The maximum efficiency (i.e., the Carnot heat engine efficiency) of a heat engine operating between cold and hot reservoirs, denoted as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
State Function
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system (e.g. gas, liquid, solid, crystal, or emulsion), not the path which the system has taken to reach that state. A state function describes equilibrium states of a system, thus also describing the type of system. A state variable is typically a state function so the determination of other state variable values at an equilibrium state also determines the value of the state variable as the state function at that state. The ideal gas law is a good example. In this law, one state variable (e.g., pressure, volume, temperature, or the amount of substance in a gaseous equilibrium system) is a function of other state variables so is regarded as a state function. A state fu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reversible Computing
Reversible computing is any model of computation where the computational process, to some extent, is time-reversible. In a model of computation that uses deterministic transitions from one state of the abstract machine to another, a necessary condition for reversibility is that the relation of the mapping from states to their successors must be one-to-one. Reversible computing is a form of unconventional computing. Due to the unitarity of quantum mechanics, quantum circuits are reversible, as long as they do not "collapse" the quantum states they operate on. Reversibility There are two major, closely related types of reversibility that are of particular interest for this purpose: physical reversibility and logical reversibility. A process is said to be ''physically reversible'' if it results in no increase in physical entropy; it is isentropic. There is a style of circuit design ideally exhibiting this property that is referred to as charge recovery logic, adiabatic circui ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Information Theory
Information theory is the scientific study of the quantification (science), quantification, computer data storage, storage, and telecommunication, communication of information. The field was originally established by the works of Harry Nyquist and Ralph Hartley, in the 1920s, and Claude Shannon in the 1940s. The field is at the intersection of probability theory, statistics, computer science, statistical mechanics, information engineering (field), information engineering, and electrical engineering. A key measure in information theory is information entropy, entropy. Entropy quantifies the amount of uncertainty involved in the value of a random variable or the outcome of a random process. For example, identifying the outcome of a fair coin flip (with two equally likely outcomes) provides less information (lower entropy) than specifying the outcome from a roll of a dice, die (with six equally likely outcomes). Some other important measures in information theory are mutual informat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Engine
In thermodynamics and engineering, a heat engine is a system that converts heat to mechanical energy, which can then be used to do mechanical work. It does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the higher temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a lower temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings and is not converted to work. Also, some energy is unusable because of friction and drag. In general, an engine is any machine that converts energy to mechanical work. Heat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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