Diamond Nanothread
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Diamond Nanothread
A carbon nanothread (also called diamond nanothread) is a sp3-bonded, one-dimensional carbon crystalline nanomaterial. The tetrahedral sp3-bonding of its carbon is similar to that of diamond. Nanothreads are only a few atoms across, more than 20,000 times thinner than a human hair. They consist of a stiff, strong carbon core surrounded by hydrogen atoms. Carbon nanotubes, although also one-dimensional nanomaterials, in contrast have sp2-carbon bonding as is found in graphite. The smallest carbon nanothread has a diameter of only 0.2 nanometer, much smaller than the diameter of a single-wall carbon nanotube. Synthesis Nanothreads are synthesized by compressing liquid benzene to extreme pressure of 20 GPa (around 200,000 times the air pressure at the surface of the Earth), and then slowly relieving that pressure. The mechanochemical synthesis reaction can be considered a form of organic solid state chemistry. The benzene chains form extremely thin, tight rings of carbon that ...
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Orbital Hybridisation
In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new ''hybrid orbitals'' (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory. For example, in a carbon atom which forms four single bonds the valence-shell s orbital combines with three valence-shell p orbitals to form four equivalent sp3 mixtures in a tetrahedral arrangement around the carbon to bond to four different atoms. Hybrid orbitals are useful in the explanation of molecular geometry and atomic bonding properties and are symmetrically disposed in space. Usually hybrid orbitals are formed by mixing atomic orbitals of comparable energies. History and uses Chemist Linus Pauling first developed the hybridisation theory in 1931 to explain the structure of simple molecules such as methane (CH4) using atomic orbitals. Pauling pointed out that a carbon atom forms fou ...
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Hexagonal Crystal Family
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhombohedral. Each lattice system consists of one Bravais l ...
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Orbital Hybridisation
In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new ''hybrid orbitals'' (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory. For example, in a carbon atom which forms four single bonds the valence-shell s orbital combines with three valence-shell p orbitals to form four equivalent sp3 mixtures in a tetrahedral arrangement around the carbon to bond to four different atoms. Hybrid orbitals are useful in the explanation of molecular geometry and atomic bonding properties and are symmetrically disposed in space. Usually hybrid orbitals are formed by mixing atomic orbitals of comparable energies. History and uses Chemist Linus Pauling first developed the hybridisation theory in 1931 to explain the structure of simple molecules such as methane (CH4) using atomic orbitals. Pauling pointed out that a carbon atom forms fou ...
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Nature Materials
''Nature Materials'', is a peer-reviewed scientific journal published by Nature Publishing Group. It was launched in September 2002. Vincent Dusastre is the launching and current chief editor. Aims and scope ''Nature Materials'' is focused on all topics within the combined disciplines of '' materials science'' and ''engineering''. Topics published in the journal are presented from the view of the impact that materials research has on other scientific disciplines such as (for example) physics, chemistry, and biology. Coverage in this journal encompasses fundamental research and applications from synthesis to processing, and from structure to composition. Coverage also includes basic research and applications of properties and performance of materials. Materials are specifically described as "substances in the condensed states (liquid, solid, colloidal)", and which are "designed or manipulated for technological ends." Furthermore, ''Nature Materials'' functions as a forum for th ...
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Carnegie Institution For Science
The Carnegie Institution of Washington (the organization's legal name), known also for public purposes as the Carnegie Institution for Science (CIS), is an organization in the United States established to fund and perform scientific research. The institution is headquartered in Washington, D.C. , the Institution's endowment was valued at $926.9 million. In 2018 the expenses for scientific programs and administration were $96.6 million.Eric Isaacs is president of the institution. Name More than 20 independent organizations were established through the philanthropy of Andrew Carnegie and now feature his surname. They perform work involving topics as diverse as art, education, international affairs, world peace, and scientific research. In 2007, the Carnegie Institution of Washington adopted the public name "Carnegie Institution for Science" to distinguish itself from other organizations established by and named for Andrew Carnegie. The Institution remains officially and leg ...
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Oak Ridge National Laboratory
Oak Ridge National Laboratory (ORNL) is a U.S. multiprogram science and technology national laboratory sponsored by the U.S. Department of Energy (DOE) and administered, managed, and operated by UT–Battelle as a federally funded research and development center (FFRDC) under a contract with the DOE, located in Oak Ridge, Tennessee. Established in 1943, ORNL is the largest science and energy national laboratory in the Department of Energy system (by size) and third largest by annual budget. It is located in the Roane County section of Oak Ridge, Tennessee. Its scientific programs focus on materials, nuclear science, neutron science, energy, high-performance computing, systems biology and national security, sometimes in partnership with the state of Tennessee, universities and other industries. ORNL has several of the world's top supercomputers, including Frontier, ranked by the TOP500 as the world's most powerful. The lab is a leading neutron and nuclear power resear ...
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Penn State University
The Pennsylvania State University (Penn State or PSU) is a Public university, public Commonwealth System of Higher Education, state-related Land-grant university, land-grant research university with campuses and facilities throughout Pennsylvania. Founded in 1855 as the Farmers' High School of Pennsylvania, Penn State became the state's only Land-grant university, land-grant university in 1863. Today, Penn State is a major research university which conducts teaching, research, and public service. Its instructional mission includes undergraduate, graduate, professional and continuing education offered through resident instruction and online delivery. The University Park campus has been labeled one of the "Public Ivy, Public Ivies", a publicly funded university considered as providing a quality of education comparable to those of the Ivy League. In addition to its land-grant designation, it also participates in the sea-grant, space-grant, and sun-grant research consortia; it is on ...
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Pennsylvania State University
The Pennsylvania State University (Penn State or PSU) is a public state-related land-grant research university with campuses and facilities throughout Pennsylvania. Founded in 1855 as the Farmers' High School of Pennsylvania, Penn State became the state's only land-grant university in 1863. Today, Penn State is a major research university which conducts teaching, research, and public service. Its instructional mission includes undergraduate, graduate, professional and continuing education offered through resident instruction and online delivery. The University Park campus has been labeled one of the "Public Ivies", a publicly funded university considered as providing a quality of education comparable to those of the Ivy League. In addition to its land-grant designation, it also participates in the sea-grant, space-grant, and sun-grant research consortia; it is one of only four such universities (along with Cornell University, Oregon State University, and University of Haw ...
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The Fountains Of Paradise
''The Fountains of Paradise'' is a 1979 science fiction novel by British writer Arthur C. Clarke. Set in the 22nd century, it describes the construction of a space elevator. This "orbital tower" is a giant structure rising from the ground and linking with a satellite in geostationary orbit at the height of approximately 36,000 kilometers (approx. 22,300 miles). Such a structure would be used to raise payloads to orbit without the expense of using rockets. The novel won both the Hugo and Nebula Awards for Best Novel. Plot Summary The novel focuses primarily on a project known as the Orbital Tower proposed by the main character, Vannevar Morgan. The tower is to stretch from the Earth's equator to a satellite that is in geostationary orbit. Such a structure would greatly reduce the cost of sending people and supplies into space. The main story is framed by two other stories. The first one tells of King Kalidasa, living thousands of years before Morgan is born, who is constru ...
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Polydiacetylenes
Polydiacetylenes (PDAs) are a family of conducting polymers closely related to polyacetylene. They are created by the 1,4 topochemical polymerization of diacetylenes. They have multiple applications from the development of organic films to immobilization of other molecules. History The first polydiacetylene to be discovered was Poly(1,6-bishydroxy hexa-2,4-diacetylene) by Gerhard Wegner in 1969. This was achieved by exposing crystals of 1,6-bishydroxy hexa-2,4-diyne to UV light. Polymerization was assumed to occur because of the spatial arrangement of diynes in the crystal, but this was not confirmed until 1972 when Raymond H. Baughman coined the term "topochemical polymerization" to describe polymerization due to spatial arrangement and put forth the spatial requirements needed for a polymerization of this sort. Synthesis Synthesis of polydiacetylenes occurs through topochemical polymerization of 1,3-diynes. Typically, this must occur in the solid state, because many diynes unde ...
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